CAS: 13462-90-3; Nickel Iodide (Nii2)

该化合物是一种无机化合物,其特点是其深绿色和黑晶状外观,由镍和碘组成,镍在+2氧化状态下,该化合物通常通过镍盐与碘的反作用或元素的直接结合形成.镍碘化物以其在水和酒精等极地溶剂中的较高溶性而著称,它也可以作为镍离子的来源用于各种化学反应.就其物理特性而言,NiI2具有高度的熔点和表现出的血缘特征,这意味着它可以吸收空气中的湿度.重要的是要小心地处理碘化镍,因为镍化合物可能有毒,并可能对接触产生健康风险.此外,NiI2在有机合成中具有应用作用,在某些化学反应中也具有催化剂作用,突出其在工业和实验室环境中的重要性.

结构式图片

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求食品接触材料-禁用CMR物质化妆品禁用物质清单C&L通报ECHA物质REACH预注册废弃物危险特性清单

上下游产品

iodine nickel tetracarbonyl nickel nickel dichloride2(Tri-p-tolyl-phosphin)2NiI2(Tri-p-tolyl-phosphin)2 (1-)triiodide(1-) 2(phenylcyanide)4NiI2(phenylcyanide)4 2(CH3C6H4NH2)4}{NiI2(CH3C6H4NH2)4}

合成工艺路线路线简述

    碘化铵 反应生成碘化亚镍
    参考文献:Tanno Kazuo; Komani Yumiko; Kurosawa Fumio; Saito Shiro,Inform. Mater. Energy Theory Life,54,(1986) N 6,490-497
    标题:Tanno Kazuo; Komani Yumiko; Kurosawa Fumio; Saito Shiro,Inform. Mater. Energy Theory Life,54,(1986) N 6,490-497

    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-11247977-B2
    优先权日:2018-06-22
    标题 :Compound and use thereof in synthesis of brivaracetam intermediate and crude drug
    发明人:FENG YAN; WANG RUYONG; YE YIZHANG; ZHANG FENGSEN; GONG XUAN; WANG ZHONGHONG; KANG XINSHAN
    权利人:FUJIAN HAIXI PHARMACEUTICALS CO LTD
    摘要:The present application provides a compound in formula III, and further provides a use of the compound in the synthesis of a Brivaracetam intermediate and a crude drug, and a synthesis method. A raw material involved in the method of the present application is low in costs and easily available; (R)-4-propyl-dihydrofuran-2-ketone having high optical purity can be prepared; complicated separation and purification steps are avoided; costs are reduced, and the method is more applicable to industrial production.

    专利号:US-8283476-B2
    优先权日:2007-06-26
    标 题:Transition metal catalyzed synthesis of 2H-indazoles
    发明人:HALLAND NIS; NAZARE MARC; LINDENSCHMIDT ANDREAS; ALONSO JORGE; RKYEK OMAR; URMANN MATTHIAS
    权利人:HALLAND NIS; NAZARE MARC; LINDENSCHMIDT ANDREAS; ALONSO JORGE; RKYEK OMAR; URMANN MATTHIAS; SANOFI SA
    摘要:The present invention relates to a process for the regioselective synthesis of compounds of the formula I, n nwherein R0; R1; R2; R3; R4; R5; A1; A2; A3; A4, Q and J have the meanings indicated in the claims. The present invention provides a direct transition metal catalyzed process to a wide variety of multifunctional 2H-indazoles or 2H-azaindazoles of the formula (I) from 2-halo-phenylacetylenes or (2-sulfonato)phenylacetylenes and monosubstituted hydrazines.

    专利号:US-7951961-B2
    优先权日:2006-07-07
    标题:Enantioselective synthesis of pyrrolidines substituted with flavones, and intermediates thereof
    发明人:SIVAKUMAR MEENAKSHI; SHUKLA MANOJ; JADHAV PRAMOD KUMAR; BORHADE AJIT
    权利人:PIRAMAL LIFE SCIENCES LTD
    摘要:The present invention relates to an enantioselective synthesis of (+)-trans enantiomer of pyrrolidines substituted with flavones, represented by Formula 1 or salts thereof, which are inhibitors of cyclin dependant kinases and can be used for treatment of proliferative disorders such as cancer n nwherein Ar has the meaning as indicated in the claims.

    专利号:US-8026375-B2
    优先权日:2007-04-13
    标题:Transition metal catalyzed synthesis of N-aminoindoles
    发明人:HALLAND NIS; NAZARE MARC; LINDENSCHMIDT ANDREAS; RKYEK OMAR; URMANN MATTHIAS; ALONSO JORGE
    权利人:SANOFI AVENTIS
    摘要:The present invention relates to a process for the regioselective synthesis of compounds of the formula I, n nwherein R0; R1; R2; R3; R4; R5; R6; A1; A2; A3; A4, Q, T and J have the meanings indicated in the claims. The present invention provides a direct transition metal catalyzed process to a wide variety of multifunctional N-aminoindole or N-amino-azaindoles of the formula I from 2-halo-phenylacetylenes or (2-sulfonato)phenyl-acetylenes and N,N-disubstituted hydrazines, useful for the production of pharmaceuticals, diagnostic agents, liquid crystals, polymers, herbicides, fungicidals, nematicidals, parasiticides, insecticides, acaricides and arthropodicides.
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    合成参考文献


    摘要:USEPA/Office of Water; Federal-State Toxicology and Risk Analysis Committee (FSTRAC). Summary of State and Federal Drinking Water Standards and Guidelines (11/93) To Present
    摘要:Lide, D.R. (ed.). CRC Handbook of Chemistry and Physics. 79th ed. Boca Raton, FL: CRC Press Inc., 1998-1999., p. 4-73
    摘要:Lewis, R.J., Sr (Ed.). Hawley's Condensed Chemical Dictionary. 13th ed. New York, NY: John Wiley & Sons, Inc. 1997., p. 787
    摘要:Mackison, F. W., R. S. Stricoff, and L. J. Partridge, Jr. (eds.). NIOSH/OSHA - Occupational Health Guidelines for Chemical Hazards. DHHS(NIOSH) Publication No. 81-123 (3 VOLS). Washington, DC: U.S. Government Printing Office, Jan. 1981., p. 3
    摘要:L41: ATSDR - Agency for Toxic Substances and Disease Registry (2005). Toxicological profile for nickel. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA). http://www.atsdr.cdc.gov/toxprofiles/tp15.html
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