CAS: 372-16-7; 4-((Trifluoromethyl)Thio)Aniline

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CAS号403-66-7 4-三氟甲硫基硝基苯 | CAS号2314-97-8 三氟碘甲烷 | CAS号1193-02-8 4-氨基苯硫酚 | CAS号1314-15-4 无水氧化铂 | CAS号100-32-3 4,4'-二硝基二苯二硫醚 | CAS号701-57-5 4-硝基茴香硫醚 | CAS号713-66-6 1-nitro-4-(tric... | CAS号333-47-1 1-溴-4-(三氟甲基硫代)苯 | CAS号326-45-4 6-((三氟甲基)硫基)苯并[... | CAS号456-56-4 苯基三氟甲基硫醚 | CAS号24032-84-6 4-三氟甲基硫代苯基异氰酸酯 | CAS号88575-32-0 对三氟甲硫基苯甲酰肼 | CAS号99479-65-9 2,6-二氯-4-三氟甲基磺酰基苯胺 | CAS号51679-42-6 2-[4-(trifluoro...

4-硝基茴香硫醚置于偶氮二异丁腈,Palladium 10% On Activated Carbon,氢气,三氟化锑,氯体系中,用 二氯甲烷,氯仿 用作溶剂,20.0~60.0 °C,4.05 Mpa 条件下,反应 14.0H,反应生成对三氟甲硫基苯胺
参考文献:A Concise And Convenient Synthesis Of 4-(Trifluoromethylthio)Aniline
标题:A Concise And Convenient Synthesis Of 4-(Trifluoromethylthio)Aniline
摘要:4-(三氟甲硫基)苯胺是一种关键的农业中间体,可由 4-硝基溴苯合成.首先,在相转移催化剂存在下,通过 4-硝基溴苯与甲硫醇钠盐的甲硫基三嗪反应得到 4-硝基硫代苯甲醚,收率为 91.4%;然后,通过氯化反应和氟化反应分别得到 4-(三氟甲硫基)硝基苯,收率分别为 83.7%和 86.3%;最后,在 Pd/c 存在下进行氢化反应可以得到 4-(三氟甲硫基)苯胺,收率为 98%.
Doi:10.14233/ajchem.2017.20138

专利信息

专利号:RU-2030397-C1
优先权日:1990-02-14
标 题 :Method of synthesis of aminophenylperfluoroalkylsulfides

专利号:US-4411912-A
优先权日:1978-02-16
标 题 :Insecticidal isovaleric acid esters
发明人：HENRICK CLIVE A; GARCIA BARBARA A
权利人:ZOECON CORP
摘要:Esters and thiolesters of amino acids, intermediates therefor, synthesis thereof, and the use of said esters and thiolesters and compositions for the control of pests.

专利号:WO-2010139090-A1
优先权日:2009-06-02
标 题 :N-phenyl dichloroacetamide and their derivatives, preparation methods and uses theirof
发明人：CHENG CHANGMEI; YANG YONGCHONG; CHANG ZHIJIE; CHEN ZHESHENG; ZHANG FENG; WANG DONGCHUN; LU AIJUN
权利人:UNIV TSINGHUA; CHENG CHANGMEI; YANG YONGCHONG; CHANG ZHIJIE; CHEN ZHESHENG; ZHANG FENG; WANG DONGCHUN; LU AIJUN
摘要:N-Phenyl dichloroacetamide and their derivatives which belong to pharmaceutical chemistry and organic synthesis fields are provided. These compounds have the structures of general formula I, in which N-{3-chloro-4-[(trifluoromethyl)sulfonyl]phenyl}dichloroacetamide is preferred. The preparation methods of these compounds are also provided, which are easy to conduct. There is no need to use any catalyst in these methods. Additionally, the uses of these compounds in the preparation of anticancer drugs which have high-effective and low toxic anticancer activities are provided.

专利号:US-4338318-A
优先权日:1979-03-23
标 题 :Novel compositions and methods
发明人：HENRICK CLIVE A; LABOVITZ JEFFREY N; FOX ROLAND T V; RATHMELL WILLIAM G; SHEPHARD MARGARET C
权利人:ZOECON CORP
摘要:Novel 1-substituted uracils, synthesis and intermediates therefor, and compositions for the control of pests.

专利号:US-4297297-A
优先权日:1979-03-23
标题 :α-Cyano-β-(substituted-anilino)-N-ethoxycarbonylacrylamide intermediates
发明人：HENRICK CLIVE A; LABOVITZ JEFFREY N; FOX ROLAND T V; RATHMELL WILLIAM G; SHEPHARD MARGARET C
权利人:ZOECON CORP
摘要:Novel 1-substituted uracils, synthesis and intermediates therefor, and compositions for the control of pests.

专利号:US-4266056-A
优先权日:1978-04-07
标 题 :Phenyl uracils
发明人：HENRICK CLIVE A; LABOVITZ JEFFREY N; FOX ROLAND T V; RATHMELL WILLIAM G; SHEPHARD MARGARET C
权利人:ZOECON CORP
摘要:Phenyl uracils, synthesis and intermediates therefor, and compositions for the control of pests, especially fungi and bacteria.