CAS: 1345-04-6; Antimony(Iii) Sulfide

Tris[(4-Methylbenzoyl)Thio]Antimony置于piperidine体系中,用 二氯甲烷 用作溶剂,以98%的收率获得硫化锑
参考文献:[(硫代酰基)硫代]-和(酰基硒基)锑和-铋衍生物((rcss)x Mr和(rcose)x Mr的合成,结构和某些反应,M = Sb,Bi和x = 1-3)
标题:[(硫代酰基)硫代]-和(酰基硒基)锑和-铋衍生物((rcss)x Mr和(rcose)x Mr的合成,结构和某些反应,M = Sb,Bi和x = 1-3)
摘要:一系列[(硫代酰基)硫代]-和(酰基硒代)锑和[(硫代酰基)硫代]-和(酰基硒代)铋,即(rcss)x Mr和(rcose)x Mr(m = Sb,Bi,R 通过用锑和卤化铋处理哌啶鎓或碳二硫代硫酸钠和-硒酸酯,可以中等至非常好的收率合成1 =芳基,X = 1-3).(4-Mec 6 H 4 Css)2 Sb(4-Mec 6 H 4)(9B'),(4-Meoc 6 H 4 Cose)2 Sb(4-Mec 6 H 4)(12C')的晶体结构),(4-Meoc 6 H 4 Cos)2 Bi(4-Mec 6 H 4)(15C')和(4-Meoc 6 H 4 Css)2 Biph(18C)以及(4-Mec 6 H 4确定了cos)2 Sbph(6B)和(4-Mec 6 H 4 Cos)3 Sb(7B)(图1和2).这些化合物具有扭曲的方形锥体结构,其中中心sb-或bi原子上的芳基或碳硫基(=酰基硫
Doi:10.1002/hlca.200690070

专利信息

专利号:US-6077371-A
优先权日:1997-02-10
标 题 :Gas generants comprising transition metal nitrite complexes
发明人：LUNDSTROM NORMAN H; BEGIN LAURENCE C
权利人:AUTOMOTIVE SYSTEMS LAB
摘要:High nitrogen gas generant compositions, useful for inflating passenger restraint gas inflator bags, comprise a nitrogen rich coordination compound selected from coordination complexes comprised of anionic nitro and nitrito ligands coordinated with a transitional metal template, and nonmetallic or nonmetallic/metallic cations. The gas generant compositions generate relatively more gas and less solids, and are safer than known gas generant compositions. Certain gas generant compositions ignite at lower autoignition temperatures thereby facilitating the use of an aluminum or light weight metal pressure vessel. Other gas generants self-deflagrate eliminating the need for other constituents in the composition. Novel methods for the synthesis of nonmetal derivative coordination complexes, guanidine and hydrazine for example, are also presented.

专利号:US-6409990-B1
优先权日:1999-05-14
标 题:Macromolecular carrier for drug and diagnostic agent delivery
发明人：VERA DAVID R
权利人:UNIV CALIFORNIA
摘要:New macromolecular carriers for drugs and diagnostic agents are described that make use of the chemical attachment of new leashes to oligomeric backbone structures. The synthesis of these leashes and their facile creation, reaction and conjugation with chelators and ligands makes them ideal candidates for use in medicine, and especially diagnostics.

专利号:JP-2010201365-A
优先权日:2009-03-04
标题 :Method for producing catalyst for synthesis of unsaturated carboxylic acid

专利号:CN-107477120-B
优先权日:2017-09-29
标 题:A kind of yaw synthesis brake block and preparation method thereof