CAS: 1623-05-8; Perfluoropropoxyethylene

相似化合物

6037-91-8 85737-06-0 69804-19-9

上下游产品

丙烷,1,1,1,2,2-五氟-3-[(三氟乙烯基)氧代]- 1,1-Dihydropentafluoropropyl Trifluorovinyl Ether 1682-32-2
2-全氟丙氧基全氟丙基三氟乙烯基醚 1,1,1,2,3,3-Hexafluoro-2-(Heptafluoropropoxy)-3-[(Trifluorovinyl)Oxy]Propane 1644-11-7

全氟丙基1,2-二氯三氟乙醚置于锌体系中,用 N,N-二甲基甲酰胺 用作溶剂,70.0 °C,100.0 Kpa 条件下,以70%的收率获得全氟正丙基乙烯基醚
参考文献:一种全氟正丙基乙烯基醚的合成方法
标题:一种全氟正丙基乙烯基醚的合成方法
摘要:本发明提供了一种全氟正丙基乙烯基醚的合成方法,包括如下步骤:(1)五氟丙酰氟在催化剂作用下与氟气反应得到1‑氟氧基七氟丙烷;(2)1‑氟氧基七氟丙烷与1,2‑二氟‑1,2‑二氯乙烯反应得到1,2‑二氯‑1,2,2‑三氟乙基七氟丙醚;(3)1,2‑二氯‑1,2,2‑三氟乙基七氟丙醚在有机溶剂中,还原剂,引发剂作用下脱氯反应得到全氟正丙基乙烯基醚.本发明方法工艺简单稳定,副产物少且环境友好,适于工业化大规模生产,具有很好的经济效益.

专利信息

专利号:US-11485804-B2
优先权日:2017-10-17
标题:Method for the synthesis of fluoropolymers
发明人：D'APRILE FIORENZA; KAPELYUSHKO VALERIY; KENT BRADLEY LANE; BRINATI GIULIO; PONTA LAURA
权利人:SOLVAY SPECIALTY POLYMERS IT
摘要:The present invention relates to a fluorosurfactant-free emulsion polymerization method for the synthesis of a fluoropolymer, more in particular of a VDF-based polymer.

专利号:US-12122875-B2
优先权日:2018-04-20
标题:Method of making mixture of polymers
发明人：FONTANA GIOVANNI; GALIMBERTI MARCO; TORTELLI VITO
权利人:SOLVAY SPECIALTY POLYMERS IT
摘要:The present invention relates to a process for the synthesis of partially and fully fluorinated polyether (PFPE) polymers, to PFPE polymers obtained therefrom and to the use of said PFPE polymers as intermediate compounds for the manufacture of additives for plastic and glass coating.

专利号:US-7271231-B2
优先权日:1995-01-24
标 题 :Polymerization of olefins
发明人：BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE
权利人:DU PONT
摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.

专利号:US-2005215741-A1
优先权日:1999-12-29
标题 :Fluorinated elastomers with low glass transition temperatures based on vinylidene fluoride and free of tetrafluoroethylene or siloxane group
发明人：AMEDURI BRUNO M; ARMAND MICHEL; BOUCHER MARIO; BOUTEVIN BERNARD L
权利人:HYDRO QUEBEC
摘要:The present invention describes synthesis of new fluorinated elastomers presenting very low glass transition temperatures, a good resistance to bases, petroleum and fuels and good properties for forming. These elastomers contain, by way of example, from 90 to 50 mole % of vinylidene fluoride (VDF) and from 10 to 50 molar % of perfluoromethyl vinyl ether (PMVE). In this precise case, they are prepared by radical copolymerisation of VDF and with PMVE in presence of various organic initiators such as for example the peroxides, the peresters or the diazo compounds.

专利号:US-4303593-A
优先权日:1979-06-16
标 题 :Process for the dimerization of hexafluoropropene oxide
发明人：KUEHNE GERHARD
权利人:HOECHST AG
摘要:In the dimerization of hexafluoropropene oxide to give oligomeric acid fluorides of the formula the ratio of the oligomeric constituents formed is directed, in an improved manner, towards the formation of the dimer (n=0) if the reaction is carried out in the presence of a catalyst system which consists of a mixture of a copper (I) compound and a copper (II) compound mixed with a complex-forming agent from the group of the nitriles, isocyanides, tertiary phosphines and cyclic hydrocarbons with 6 to 12 ring atoms and 2 to 3 double bonds in the ring, and an aprotic organic solvent. The dimer is an intermediate product in the synthesis of perfluoropropyl perfluorovinyl ether, the latter being employed as a comonomer in fluorine-containing copolymers.

专利号:EP-1252205-B1
优先权日:1999-12-29
标题:Fluorosulphonated elastomers with low glass transition based of vinylidene fluoride
发明人：AMEDURI BRUNO MICHEL; ARMAND MICHEL; BOUCHER MARIO; MANSERI ABDELLATIF
权利人:HYDRO QUEBEC
摘要:The present invention describes the synthesis of new sulforated fluorinated elastomers having very low glass transition temperatures (Tg), a good resistance to bases, oils and fuels and good properties of workability. These elastomers contain, by way of example, from 80 to 60 mole % of vinylidene fluoride (VDF) and 20 to 40 mole % of perfluoro(4-methyl-3,6-dioxaoct-7-ene) sulfonyl fluoride (PFSO2F). In this case, they are prepared by radical copolymerisation of VDF and PFSO2F in the presence of different organic initiators, for example, peroxides, peresters or diazo compounds.