CAS: 198964-46-4; 9,9-Dioctyl-2,7-Dibromofluorene

上下游产品

CAS号111-83-1 1-溴代正辛烷 | CAS号16433-88-8 2,7-二溴芴 | CAS号123863-99-0 9,9-二正辛基芴 | CAS号86-73-7 芴 | CAS号317802-08-7 9,9-二辛基芴-2,7-二硼... | CAS号222159-97-9 [7-(hydroxymeth... | CAS号253870-90-5 (7-bromo-9,9-di... | CAS号123863-99-0 9,9-二正辛基芴 | CAS号302554-80-9 2-溴-9,9-二正辛基芴 | CAS号1059502-70-3 2-bromo-7-butyl... | CAS号196207-58-6 9,9-二正辛基芴-2,7-二... | CAS号258865-48-4 9,9-二辛基芴-2,7-二硼酸 | CAS号851042-10-9 2,7-二氨基-9,9-二正辛基芴 | CAS号428865-66-1 9,9-di°Ctylfluo...

芴置于iron(III) Chloride,N-溴代丁二酰亚胺(Nbs),四丁基碘化铵,Sodium Hydroxide体系中,用 水,N,N-二甲基甲酰胺,甲苯 用作溶剂,化学反应 22.0H,反应生成9,9-二辛基-2,7-二溴代芴
参考文献:通过改变基于棒状芴基-炔基的π-共轭低聚物及其双核金(i)炔基络合物的供体/受体单元来实现黄色发射†
标题:通过改变基于棒状芴基-炔基的π-共轭低聚物及其双核金(i)炔基络合物的供体/受体单元来实现黄色发射†
摘要:芴基的炔基的π共轭棒状低聚物轴承不同的中心芳族结构部分和官能化的二炔基的末端,如h--Fl--Fl--Fl--H(oh1),H--Fl--Btz--fl--h(oh2)和h--fl--btd--fl--h(oh3),其中fl = 9,9-二辛基芴,Btz = N-己基苯并三唑和btd =苯并噻二唑是通过pd(0)催化的stille偶联方案成功合成的.引入了吸电子至强至中性受体的苯并噻二唑和苯并三唑,以及与施主一样的芴,以调节施主-受体(d-A)的强度来微调带隙(e G)和发射波长.相应的digold(i)σ络合物(pph 3)au--fl--fl--fl--au(pph 3)(om1),(pph 3)au--fl--btz--fl--Au(pph 3)(om2)和(pph 3还通过au(pph 3)cl和甲醇naome在dcm中与相应的炔基官能化的低聚物反应制备了au-
Doi:10.1039/c7Dt00895C

专利信息

专利号:US-2014187716-A1
优先权日:2011-07-15
标 题:Process for the synthesis of conjugated polymers
发明人：JONES DAVID JOHN; WONG WING HO WALLACE; HOLMES ANDREW BRUCE; SEYLER HELGA
权利人:JONES DAVID JOHN; WONG WING HO WALLACE; HOLMES ANDREW BRUCE; SEYLER HELGA; UNIV MELBOURNE
摘要:Processes for the continuous production of conjugated polymers are disclosed. The processes provide excellent control over reaction parameters and are highly reproducible. The conjugated polymers find use in heterojunction devices.

专利号:US-12173212-B2
优先权日:2020-08-21
标题:Design, synthesis, and photophysical properties of a novel NIR II dye for biological imaging and optoelectronic devices
发明人：DELCAMP JARED; HAMMER NATHAN; SCOTT COLLEEN
权利人:UNIV MISSISSIPPI; UNIV MISSISSIPPI STATE
摘要:In one aspect, the disclosure relates to fluorescent dyes that absorb and emit in the near infrared II (NIR II) range of the electromagnetic spectrum, methods of making same, compositions comprising same and methods of using the compositions to perform imaging on biological samples, and optoelectronic devices using the dyes. The dyes are small organic molecules that are inexpensive and facile to produce, can be water-soluble, have tunable properties, and are biocompatible and/or possess low toxicity.

专利号:US-11186676-B2
优先权日:2016-12-09
标 题 :Polymer containing S,S-dioxide-dibenzothiophene in backbone chain with content-adjustable triarylamine end groups and preparation method and application thereof
发明人：GUO TING; PENG FENG; YING LEI; YANG WEI; PENG JUNBIAO; CAO YONG
权利人:UNIV SOUTH CHINA TECH
摘要:Provided are a polymer containing S,S-dioxide-dibenzothiophene in backbone chain with content-adjustable triarylamine end groups, and a preparation method and an application thereof. Triarylamines hole-transport small molecules are introduced into the polymer end group, and a content of the triarylamine end groups can be adjusted by controlling a polymer molecular weight, so that the polymer has better electron-transport and hole-transport capabilities, and charge carrier transport can be balanced, so that more exciton recombination takes place effectively, thus improving the luminous efficiency and stability of the polymer. The polymer is prepared by a Suzuki polymerization reaction and does not require synthesis of new monomers. The polymer material is used for preparing highly effective and stable monolayer devices, and is dissolved directly in an organic solvent, then spin-coated, ink-jet printed, or printed to form a film.

专利号:WO-0142331-A1
优先权日:1999-12-09
标题:Fluorene-perylene copolymers and uses thereof
发明人：BECKER STEFAN; FRIEND RICHARD; MUELLEN KLAUS; MACKENZIE DEVIN; MARSITZKY DIRK; SETAYESH SEPAS
权利人:CAMBRIDGE DISPLAY TECH LTD; MAX PLANCK INST FUER POLYMERFO; BECKER STEFAN; FRIEND RICHARD; MUELLEN KLAUS; MACKENZIE DEVIN; MARSITZKY DIRK; SETAYESH SEPAS
摘要:A statistical copolymer of formula (I) is provided wherein: A represents an end-capping unit; B is a moiety of formula (II) or (III), wherein each of R?1 and R2¿ is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl, aryl and aralkyl; C is a perylene-containing moiety of formula (IV), wherein each of a1, a2, a3 and a4 is 0 or 1, each of b3, b4, b5 and b6 is 0, 1 or 2, each of X?1, X2, X3 and X4¿ is a single bond or a linking unit, and each of R?3, R4, R5 and R6¿ is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl, aryl, aryloxy or aralkyl; and the ratio x:y is from 80:20 to 99.9:0.1. A kit for the synthesis of the copolymers of the invention and electroluminescent devices incorporating said copolymers are also provided.

专利号:WO-2012087243-A1
优先权日:2010-12-20
标 题:New p-type low bandgap polymers and their use
发明人：MA ZHUN; CHEN ZHIKUAN; LIM SIEW LAY; LI JUN
权利人:AGENCY SCIENCE TECH & RES; MA ZHUN; CHEN ZHIKUAN; LIM SIEW LAY; LI JUN
摘要:Synthesis of a benzothiadiazole/thiophene-based oligomer/polymer for bulk heteroj unction photovoltaic cells. The polymer/oligomer comprises electron donating units such as fluorene, dibenxothiophene, dibenzosilole dihydroindenofluorene etc and electron withdrawing units such as benzothiadiazole and is represented by formula (I).

专利号:WO-2013010209-A1
优先权日:2011-07-15
标 题:Process for the synthesis of conjugated polymers