4,5-二溴噻吩-2-甲酸置于mercury(II) Diacetate,溶剂黄146,Sodium Chloride体系中,化学反应生成2,3-二溴噻吩 参考文献:Steinkopf; Koehler,Justus Liebigs Annalen Der Chemie,1937,Vol. 532,P. 250,279 标题:Steinkopf; Koehler,Justus Liebigs Annalen Der Chemie,1937,Vol. 532,P. 250,279
专利信息
专利号:US-2014199585-A1 优先权日:2013-01-17 标 题 :Low Symmetry Molecules And Phosphonium Salts, Methods Of Making And Devices Formed There From 发明人:RUPERT BENJAMIN L; BEER LEANNE 权利人:ESIONIC ES INC 摘要:Synthesis of molecules and salts is disclosed having low average symmetry and their use in many applications, including but not limited to: as electrolytes in electronic devices such as memory devices including static, permanent and dynamic random access memory, as electrolytes in energy storage devices such as batteries, electrochemical double layer capacitors (EDLCs) or supercapacitors or ultracapacitors, electrolytic capacitors, as electrolytes in dye-sensitized solar cells (DSSCs), as electrolytes in fuel cells, as a heat transfer medium, high temperature reaction and/or extraction media, among other applications. In particular, synthesis methods and processes to form molecules and salts having low average symmetry using mixed Grignard reagents are disclosed.
专利号:US-9045462-B2 优先权日:2012-08-17 标 题 :Synthesis of an antiviral compound 发明人:EVANS JARED WAYNE; FUJIMORI SHINJI; HUYNH GRACE M; LIU QI; TERESK MARTIN GERALD 权利人:GILEAD SCIENCES INC 摘要:The present disclosure provides processes for the preparation of a compound of Formula I: n nwhich is useful as an antiviral agent. The disclosure also provides compounds that are synthetic intermediates to compounds of formula.
专利号:US-9701692-B1 优先权日:2016-03-11 标 题 :Synthesis of thienothiophenes 发明人:KOBILKA BRANDON M; KUCZYNSKI JOSEPH; WERTZ JASON T 权利人:IBM 摘要:In some embodiments, a method for synthesizing a compound of the structure: n nis provided wherein R is selected from the group consisting of alkyl, ester, aryl, vinyl, ketone, amide, and sulfone, includes mixing a 3-(methylthio)-4-alkynylthiophene with iodine and/or iodine monochloride. In some embodiments, a method for synthesizing a compound of the structure:n n nis provided wherein R is selected from the group consisting of alkyl, ester, aryl, vinyl, ketone, amide, and sulfone, includes mixing a 3-bromo-4-(methylthio)-thiophene, a terminal alkyne, and a palladium catalyst.
专利号:US-8927741-B2 优先权日:2012-08-17 标 题 :Synthesis of an antiviral compound 发明人:WATKINS WILLIAM JOHN; LIU QI 权利人:GILEAD SCIENCES INC 摘要:The present disclosure provides a processes for the preparation of a compound of Formula I: n nwhich is useful as an antiviral agent. The disclosure also provides compounds that are synthetic intermediates to compounds of Formula I.
专利号:US-2013059412-A1 优先权日:2010-05-04 标 题 :In-situ polymerization in bulk heterojunction organic devices 发明人:ADE HARALD W; SEOK JAEWOOK 权利人:ADE HARALD W; SEOK JAEWOOK; UNIV NORTH CAROLINA STATE 摘要:Fabrication of bulk heterojunction organic devices are disclosed that utilize in-situ polymerization of an active component of the device or an in-situ polymerization of an additive that controls the device morphology. According to an aspect, a method for the synthesis of a BHJ photovoltaic film may comprise preparing a homogeneous solution comprising 2,5-dibromothiophene and/or 2,5-diiodothiophene, P3HT and PCBM. The method may also comprise preparing a thin film of the homogeneous solution on the solid surface of a material or an assembly capable of acting as an anode. Oxygen may be excluded from the environment where the thin film will be exposed to photopolymerization by placing the thin film and anode assembly in an inert-gas environment. The method also comprises exposing the liquid film to UV light for a sufficient duration of time and at a sufficient temperature to cause photopolymerization to occur.
专利号:US-11476422-B2 优先权日:2018-03-15 标 题:Anthradithiophene derivatives, process for the preparation thereof and polymers that contain them 发明人:BIANCHI GABRIELE; PASINI DARIO; NITTI ANDREA 权利人:ENI SPA 摘要:An Anthradithiophene derivative having general formula (I): n ncan be advantageously used in the synthesis of electron donor polymers These polymers can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support or on a flexible support. Furthermore, these polymers can be advantageously used in the construction of Organic Thin Film Transistors (OTFTs), or Organic Field Effect Transistors (OFETs), or Organic Light-Emitting Diodes (OLEDs).