均三甲苯置于聚合甲醛,氢溴酸体系中,用 溶剂黄146 用作溶剂,以90%的收率获得2,4,6-三溴甲基三甲基苯 参考文献:A Bright Entry To Improve The Performance Of Dsscs With The Influence Of Novel Optoelectronic Acridinedione Based Macromolecules In I−/i3− Electrolytes 标题:A Bright Entry To Improve The Performance Of Dsscs With The Influence Of Novel Optoelectronic Acridinedione Based Macromolecules In I−/i3− Electrolytes 摘要:新合成的多价大分子含有性能优越的吖啶二酮单元和1,2,3-三氮唑单元,通过一种新型且便捷的铜催化的炔烃和叠氮化物的1,3-偶极环加成反应(cuaac)连接,被用于描述染料敏化纳米晶tio2太阳能电池(dsscs)的性能.这些独特的大分子已被证明非常适合利用在i-/i3-氧化还原电解质中的添加剂.在各种取代基中,具有富电子氮杂原子取代基的体系获得了最高的光电流转换效率约6.4%,开路电压为810 Mv. Doi:10.1039/c3Ta12221B
专利号:WO-2018056902-A1 优先权日:2016-09-20 标题:Imidazolium compounds, methods of synthesis and uses thereof 发明人:ZHANG YUGEN; YUAN YUAN 权利人:AGENCY SCIENCE TECH & RES 摘要:The present invention generally relates to a non-linear imidazolium compound of Formula (I), comprising a planar or stereo core structure. In addition, the present invention relates to the method of preparing the imidazolium compound as disclosed herein. Advantageously, the imidazolium compound of the present disclosure may demonstrate antimicrobial properties. The present invention also relates to the therapeutic and non-therapeutic use of the imidazolium compound as disclosed herein.
专利号:CN-109293636-B 优先权日:2018-10-22 标 题 :One-pot synthesis of capsule coordination compound containing Schiff base structural unit, preparation method and application
专利号:US-11535647-B2 优先权日:2018-09-14 标题 :Peptide purification method using sulfonate compound 发明人:MATSUYAMA KEISUKE; YAMAMOTO KENICHIRO; MURAKAMI SAYOKO 权利人:NAGASE & CO LTD 摘要:A method for purifying a target peptide may include mixing a peptide product obtained through a peptide synthesis with a solvent in the presence of a sulfonic acid compound to obtain a solid; and performing a solid-liquid separation to collect the solid.
专利号:CN-101717326-B 优先权日:2009-12-04 标题:Synthesis method of antioxidant 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene
参考文献:10.1107/s1600536810040730 摘要:Wang W, Gao Y, Ji M, Yao HG, Qiu H. 5,5',5''-Triphenyl-2,2',2''-[2,4,6-tri-methyl-benzene-1,3,5-triyltris(methyl-idene-sulfanedi-yl)]tris-(1,3,4-oxadiazole). Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):o2835.