十四醇置于盐酸,十六烷基三甲基溴化铵体系中,化学反应 16.0H,以93%的收率获得氯代十四烷 参考文献:Organic Synthesis In Micellar Media. Oxidation Of Alcohols And Their Conversion Into Alkyl Chlorides 标题:Organic Synthesis In Micellar Media. Oxidation Of Alcohols And Their Conversion Into Alkyl Chlorides 摘要:研究了微胶团在各种有机反应中的应用:在微胶团中用次氯酸钠氧化醇,使用十六烷基三甲基铵铬酸盐作为微胶团氧化醇,以及在微胶团存在下用氢氯酸水溶液将一醇转化为1-氯烷烃.在所有情况下,产物分离都很简单,并且得到了令人满意的收率. Doi:10.1055/s-1988-27732
专利号:US-5481040-A 优先权日:1994-03-31 标 题:Process for the preparation of phosphonium salts 发明人:FUKUMOTO TAKEHIKO; HIROKAWA KAZUSHI; OKADA KURAO 权利人:SHINETSU CHEMICAL CO 摘要:A process for the preparation of phosphonium salts by the use of chlorides, which is useful in the course of synthesis of olefin compounds by the Wittig reaction, and which comprises reacting a phosphine compound of the general formula R13P wherein R1 is a phenyl group or a straight-chain alkyl group having 2 to 8 carbon atoms, with a primary or secondary chloride of the general formula wherein R2 and R3 are hydrocarbon radicals, in a solvent selected from the group consisting of N,N-dimethylformamide, N,N-dimethylacetamide and N,N-1,3-dimethyl-2-imidazolidinone, and in the presence of an alkali metal salt of the general formula MBr or MI.
专利号:CN-109651192-A 优先权日:2018-12-24 标题 :A New Process for the Synthesis of Benzoyl Cyanide
专利号:US-4816559-A 优先权日:1986-07-08 标题 :Biologically active peptides TAN-866 发明人:HARADA SETSUO; ONO HIDEO; KATAYAMA NOZOMI 权利人:TAKEDA CHEMICAL INDUSTRIES LTD 摘要:The iron-containing biologically active peptide TAN-866 produced by microorganisms belonging to the genus Pseudomonas and its iron free compounds have antibacterial activity mainly against gram-negative bacteria. These peptides can be used as a therepeutic agent for bacterial infections in mammals, domestic fowl, etc., caused by Pseudomonas aeruginosa. Further, TAN-866 and its deacyl compounds are also promising as the starting materials and intermediates for the synthesis of novel products.
专利号:US-6512146-B2 优先权日:1998-04-28 标 题 :Process for preparing a dialkyl acetal of a C8 to C30 aldehyde 发明人:PAULEY EDWARD P; NEIGHBOR KATHERINE SUE 权利人:PENFORD CORP 摘要:Improved water resistant acetal sizing agents including 1,1-octadecoxyoctadecane are provided along with methods for their synthesis including methods in which C 8 to C 30 alkyl bromides are reacted with a polyol under basic conditions and those in which a C 8 to C 30 primary alcohol is reacted with an organic base in the presence of a suitable oxidizing agent under basic conditions.
专利号:CN-107473971-A 优先权日:2017-09-21 标 题:A new process for the synthesis of methyl benzoylformate from benzoyl cyanide
专利号:CN-1193992-C 优先权日:2000-02-04 标 题 :Synthesis of 3,6-dialkyl 5,6-dihydro-4-hydroxide-2H-pyran-2-ketone
[参考文献]: G Roshan Deen, Et Al. Phase Behavior And Kinetics Of Phase Separation Of A Nonionic Microemulsion Of C12E5/water/1-Chlorotetradecane Upon A Temperature Quench. J Phys Chem B. 2009 May 21;113(20):7138-46. [参考文献]: Renu Sharma, Et Al. Interactional Behavior Of The Polyelectrolyte Poly Sodium 4-Styrene Sulphonate (Napss) With Imidazolium Based Surface Active Ionic Liquids In An Aqueous Medium. Phys Chem Chem Phys. 2015 Sep 28;17(36):23582-94.
合成参考文献
摘要:Clark, K. F.; Dimitrova, D.; Murphy, J. A., Science of Synthesis, (2020) , 42. 摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198