专利号:US-2024424490-A1 优先权日:2021-01-25 标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles 发明人:WNUK PAWEL; LEWERA ADAM; JURCZAKOWSKI RAFAL; POWALA FILIP; KOLODZIEJCZYK JAN 权利人:UNIV WARSZAWSKI 摘要:The presented invention relates to a method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles, which comprises the following steps:n adsorbing on carbon support complexes of a platinum group metal with a urea complexing agent selected from a group comprising urea, urea derivative, a mixture of urea with at least one urea derivative, and a mixture of at least two urea derivatives; and reducing the complexes adsorbed on the carbon support to metal nanoparticles, forming a product of carbon-supported metal nanoparticles. nn The invention also provides the use of the carbon-supported platinum group metal or metal alloy nanoparticles obtained by the method of the invention as catalyst. n The present invention further relates to a method of adsorption of precursors of platinum group metals on the surface of a carbon support and use of complexes of platinum group metals with urea complexing agent for adsorption of platinum group metal precursors on carbon support.
专利号:US-10280189-B2 优先权日:2012-07-17 标题:Method for the synthesis of aminoalkylenephosphonic acid 发明人:BURCK SEBASTIAN; LECLERCQ CEDRIC NICOLAS; NOTTE PATRICK 权利人:MONSANTO TECHNOLOGY LLC 摘要:A method for the synthesis of an aminoalkylenephosphonic acid or its phosphonate esters including the following steps: a) forming, in the presence of an aldehyde or ketone and an acid catalyst, a reaction mixture by mixing a compound having at least one HNR 1 R 2 moiety or a salt thereof, with a compound having one or more P—O—P anhydride moieties, the moieties having one P atom at the oxidation state (+III) and one P atom at the oxidation state (+III) or (+V), wherein the ratio of moles of aldehyde or ketone to N—H moieties is 1 or more and wherein the ratio of N—H moieties to P—O—P anhydride moieties is 0.3 or more, and b) recovering the resulting aminoalkylenephosphonic acid having compound or its phosphonate esters.
专利号:US-4209466-A 优先权日:1973-07-10 标题 :Manufacture of formaldehyde 发明人:DIEM HANS; GRABOWSKY OTTO; MATTHIAS GUENTHER; WOLF DIETER 权利人:BASF AG 摘要:Manufacture of formaldehyde by oxidative dehydrogenation of methanol in the presence of a silver catalyst using methanol obtained from a condensate derived from the evaporation of aqueous reaction mixtures in the synthesis of urea resins and then treated with caustic soda solution under specific conditions of temperature, pressure, residence time and initial formaldehyde concentration. The formaldehyde obtained is a disinfectant, tanning agent, reducing agent and starting material for the manufacture of synthetic resins, adhesives and plastics.
专利号:US-3850978-A 优先权日:1973-11-28 标 题 :Synthesis of n,n-bis(2-fluoro-2,2-dinitroethyl)carbamates 发明人:GILLIGAN W; KAMLET M 权利人:US NAVY 摘要:1. A COMPOUND OF THE FORMULA (O2N-C(-R1)(-R2)-(CH2)M)2-N-CO-Z-(CH2)N-C(-R3)(-R4)-NO2 WHEREIN R1, R2, R3 AND R4 VARY INDEPENDENTLY AND ARE SELECTED FROM THE GROUP CONSISTING OF F AND NO2, Z IS SELECTED FROM THE GROUP CONSISTING OF O AND NH, AND M AND N VARY INDEPENDENTLY AND ARE INTEGERS OF FROM 1 TO 2.
专利号:US-4547590-A 优先权日:1984-07-06 标题 :Carbon monoxide process for the production of alpha amino acids 发明人:LOVE RICHARD A; ZEHNER LEE R 权利人:GRACE W R & CO 摘要:A process is disclosed for the synthesis of alpha-amino acid by first contacting the condensation product of an aldehyde or ketone and an amine or amide with a protic or Lewis acid solvent and carbon monoxide to form an intermediate reaction product, and then hydrolyzing the intermediate to yield a product comprising the alpha-amino acid. The reaction rate and product yield can be increased by the addition of a Group 1B metal oxide catalyst in the first step.
专利号:WO-2022158990-A1 优先权日:2021-01-25 标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles
参考标题: Method For The Synthesis Of Aminoalkylenephosphonic Acid Procédé De Synthèse D'Acide Aminoalkylènephosphonique 摘要:The Present Invention Is Related To A Method For The Synthesis Of An Aminoalkylenephosphonic Acid Or Its Phosphonate Esters Comprising The Following Steps: A) Forming, In The Presence Of An Aldehyde Or Ketone And An Acid Catalyst, A Reaction Mixture By Mixing A Compound Comprising At Least One Hnr1R2 Moiety Or A Salt Thereof, With A Compound Having One Or More P-O-P Anhydride Moieties, Said Moieties Comprising One P Atom At The Oxidation State (+iii) And One P Atom At The Oxidation State (+iii) Or (+v), Wherein The Ratio Of Moles Of Aldehyde Or Ketone To N-H Moieties Is 1 Or More And Wherein The Ratio Of N-H Moieties To P-O-P Anhydride Moieties Is 0.3 Or More And, B) Recovering The Resulting Aminoalkylenephosphonic Acid Comprising Compound Or Its Phosphonate Esters.
合成参考文献
摘要:Compound: Urea, N,N′-bis(hydroxymethyl)-, homopolymer 摘要:Kanerva - Rustemeyer L, Elsner P, John SM, Maibach HI (eds). Kanerva's Occupational Dermatology, 2nd Ed. Berlin: Springer-Verlag, 2012., p. 397-408 摘要:Kanerva - Rustemeyer L, Elsner P, John SM, Maibach HI (eds). Kanerva's Occupational Dermatology, 2nd Ed. Berlin: Springer-Verlag, 2012., p. 405