CAS: 544-16-1; 1-Butyl Nitrite

上下游产品

CAS号71-36-3 正丁醇 | CAS号109-65-9 正溴丁烷 | CAS号542-69-8 碘代正丁烷 | CAS号2372-45-4 正丁醇钠 | CAS号142-96-1 正丁醚 | CAS号106-97-8 丁烷 | CAS号19062-98-7 1-λ1-oxidanylbutane | CAS号109-52-4 正戊酸 | CAS号56-23-5 四氯化碳 | CAS号107649-71-8 methyl 2-hydrox... | CAS号3279-07-0 邻硝基对叔丁基苯酚 | CAS号5891-68-9 1-TERT-BUTYL-4-... | CAS号3972-56-3 1-叔丁基-4-氯苯 | CAS号5921-80-2 丁醛二丁基乙缩醛 | CAS号7775-81-7 4,4′-di-tert-bu... | CAS号542-52-9 碳酸二正丁酯 | CAS号59-89-2 N-亚硝基吗啉 | CAS号71-36-3 正丁醇

Sodium Butanolate置于二氯甲烷,Dinitrogen Tetraoxide,正丁醇体系中,化学反应生成 亚硝酸丁酯
参考文献:The Nitrosation And Nitration Of Amines And Alcohols With Nitrogen Tetroxide
标题:The Nitrosation And Nitration Of Amines And Alcohols With Nitrogen Tetroxide
摘要:
DOI:10.1021/ja01578A074

专利信息

专利号:US-11040938-B2
优先权日:2016-07-27
标 题 :Continuous flow process for the synthesis of phenylhydrazine salts and substituted phenylhydrazine salts
发明人：MA BING; PAN SHUAI
权利人:SHANGHAI HYBRID—CHEM TECH; SHANGHAI HYBRID CHEM TECH
摘要:The present invention provided a continuous flow process for the synthesis of phenylhydrazine salts and substituted phenylhydrazine salts. Diazotization, reduction, acidic hydrolysis and salifying with acids are innovatively integrated together. Using acidic liquids of aniline or substituted aniline, diazotization reagents, reductants and acids as raw materials, phenylhydrazine derivative salts is obtained through the synthesis process, which is a three-step continuous tandem reaction including diazotization, reduction, acidic hydrolysis and salifying. The described synthesis process is a kind of integrated solutions, which is carried out in an integrated reactor. The feed inlets of the integrated reactor are continuously filled with raw materials. In the integrated reactor, diazotization, reduction, acidic hydrolysis and salifying are carried out continuously and orderly, and phenylhydrazine salts or substituted phenylhydrazine salts is obtained in the outlet of the integrated reactor without interruption. The total reaction time is no more than 20 min.

专利号:US-11639349-B2
优先权日:2020-05-28
标题:Stereoselective synthesis of intermediate for preparation of heterocyclic compound
发明人：CHEN WEN-CHANG; HSU HAN-PEI; CHOU SHAN-YEN; CHUANG SHIH-CHIEH; YEN CHI-FENG
权利人:TAI GEN BIOTECHNOLOGY CO LTD; TAIGEN BIOPHARMACEUTICALS CO BEIJING LTD; TAIGEN BIOTECHNOLOGY CO LTD
摘要:Provided is a stereoselective synthesis of an intermediate for the preparation of the heterocyclic derivative as a Cap-dependent endonuclease inhibitor. The synthesis process has the advantages of simple operation, higher yield and relatively controllable steroselectivity, such that it is suitable for large-scale production.

专利号:US-4379935-A
优先权日:1980-08-04
标 题 :Process for the synthesis of vincamine and related indole alkaloids
发明人：PARACCHINI SILVANO; MORA PAOLO C
权利人:CORVI MORA PAOLO
摘要:A process is taught for the synthesis of vincamine and related indole alkaloids, according to which, through only two steps and through a novel synthesis intermediate, namely the glycidic ester, having the formula ##STR1## wherein R' represents --COOCH 3 or --COOCH 2 CH 3 , 1-ethyl-1,2,3,4,5,6,7,12b-octahydroindole[2,3-a]quinolizine-1-carboxaldehyde is reacted with a haloester in the presence of a base and the glycidic ester is converted to vincamine or apovincamine or like esters by reaction with a Lewis acid or a mineral acid, the reaction products being subsequently separated by chromatography.

专利号:US-7452994-B2
优先权日:2001-09-12
标 题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings
发明人：MCEACHERN ERNEST J; BRIDGER GARY J; SKUPINSKA KRYSTYNA A; SKERLJ RENATO T; YANG WEN
权利人:ANORMED INC
摘要:This invention describes various processes for synthesis and resolution of racemic amino-substituted fused bicyclic ring systems. One process utilizes selective hydrogenation of an amino-substituted fused bicyclic aromatic ring system. An alternative process prepares the racemic amino-substituted fused bicyclic ring system via nitrosation. In addition, the present invention describes the enzymatic resolution of a racemic mixture to produce the (R)- and (S)-forms of amino-substituted fused bicyclic rings as well as a racemization process to recycle the unpreferred enantioner. Further provided by this invention is an asymmetric synthesis of the (R)- or (S)-enantiomer of primary amino-substituted fused bicyclic ring systems.

专利号:US-11292775-B2
优先权日:2017-12-21
标 题 :Efficient process for the synthesis of 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro-3H-1,2,4-triazole-3-thione(prothioconazole) and its intermediates
发明人：KADAM SUBHASH RAJARAM; JANI NILESH; SHINDE RAVINDRA; SHAH KENAL V; SHAH BHAVESH V; GUJRAL AJIT SINGH; BYREGOWDA GANGANARASAIAH; SIVAIAH GANADI; PAWAR JIVAN DHANRAJ; PATI HARI NARAYAN
权利人:GSP Crop Science Pvt Ltd
摘要:The present invention relates to an improved and efficient process for the synthesis of 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, compound of formula (I) (Prothioconazole). The present invention more particularly relates to an improved process for manufacturing of 2-(1-chloro-cycloprop-1-yl)-3-(2-chloro phenyl)-2-hydroxy propyl-1-hydrazine (compound of formula III) and 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2,4-triazolidine-3-thione (compound of formula II) which are mainly used for synthesis of Prothioconazole which is knows as an active compound with microbicidal fungicidal properties.

专利号:US-6951932-B2
优先权日:2001-10-25
标 题:Synthesis of 2-aralkoxyadenosines and 2-alkoxyadenosines
发明人：MOORMAN ALLAN R
权利人:KING PHARMACEUTICALS RES & DEV
摘要:The invention provides new methods for synthesis of 2-aralkyloxyadenosines and 2-alkoxyadenosines. The invention is particularly useful for synthesis of 2-[2-(4-chlorophenyl)ethoxy]adenosine. Preferred methods of the invention include activating a guanosine compound followed by hydrolysis; alkylating the hydrolyzed compound with subsequent animation to provide a 2-aralkyloxyadenosine or a 2-alkoxyadenosine compound.