CAS: 67023-84-1; (2E,6E)-1-Chloro-3,7,11-Trimethyldodeca-2,6,10-Triene

英文名称(2E,6E)-1-Chloro-3,7,11-Trimethyldodeca-2,6,10-Triene
中文名称(2E,6E)-1-氯-3,7,11-三甲基十二烷-2,6,10-三烯
IUPAC名称(2E,6E)-1-chloro-3,7,11-trimethyldodeca-2,6,10-triene
其它别名Trans,Trans-Farnesyl Chloride ; Trans,Trans-1-Chloro-3,7,11-Trimethyl-2,6,10-Dodecatriene; Trans,Trans-Farnesyl Chloride; (2E,6E)-1-Chloro-3,7,11-Trimethyldodeca-2,6,10-Triene; 2,6,10-Dodecatriene, 1-Chloro-3,7,11-Trimethyl-, (2E,6E)-; Trans,Trans-Farnesyl Chloride
CAS编号67023-84-1
MFCD编号:MFCD00192172
EINECS号:806-285-5
分子式:C15H25Cl
分子量:240.82
产品CID: 1652244
产品分类有机原料→分子砌块→脂肪链类化合物

相似结构搜索
InChIKey: BJVUJIDTICYHLL-YFVJMOTDSA-N
InChI=1S/C15H25Cl/c1-13(2)7-5-8-14(3)9-6-10-15(4)11-12-16/h7,9,11H,5-6,8,10,12H2,1-4H3/b14-9+,15-11+…
计算化学: 氢键受体数*氢键供体数0可旋转键数7

相似化合物

5389-87-7 18794-84-8 28290-41-7

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P362+P364-P403+P233-P405-P501
UN编号UN 3334
危险品标志Xi
安全声明26-27-36/37/39
危险类别码36/37/38
WGK Germany3

欧盟法规

C&L通报

上下游产品

(E)-β-farnesene Farnesol 2(E),8(E)-Farnesyl mesylate 3,7,11-trimethyl-2ξ,6E,10-dodecatrien-1-ol6,10,14-trimethyl-5,9,13-pentadecatriene-2-on trans,trans-farnesyl-L-cysteine 2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene farnesyl pyrophosphate

合成工艺路线路线简述

金合欢醇置于吡啶,2,4,6-三甲基吡啶,氢氧化钾,甲基磺酰氯,Lithium Chloride体系中,用乙醇,水,N,N-二甲基甲酰胺作为反应溶剂,化学反应 12.0H,反应生成反,反-氯化法呢酯
参考文献:Cyclonerodiol Biosynthesis And The Enzymic Conversion Of Farnesyl To Nerolidyl Pyrophosphate
标题:Cyclonerodiol Biosynthesis And The Enzymic Conversion Of Farnesyl To Nerolidyl Pyrophosphate
摘要:
DOI:10.1021/ja00394A032

海关参考信息

2901210000-乙烯
2901220000-丙烯
2903110000-一氯甲烷及氯乙烷
2903291000-3-氯-1-丙烯
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-11912654-B2
优先权日:2021-09-03
标题:Process for stereospecific synthesis of vitamin K2 and its novel intermediates
发明人：MEHTA DILIP; SHASHTRI MAYANK; RAJU BNS; SHAH ASHWIN; VORA PARIN; MAHALE UMAKANT
权利人:SYNERGIA LIFE SCIENCES PVT LTD
摘要:The present disclosure relates to a novel process for the synthesis of stereospecific compounds of Vitamin K2 group in general and Vitamin K2-7. The present disclosure further discloses novel intermediates useful in the synthesis of stereospecific Vitamin K2-7. Compounds of the Vitamin K2 group obtained are crystalline and exhibit well defined melting points.

专利号:WO-2023031841-A1
优先权日:2021-09-03
标题:A process for the stereospecific synthesis of vitamin k2 and its intermediates
发明人：MEHTA DILIP; SHASHTRI MAYANK; RAJU BNS; VORA PARIN; MAHALE UMAKANT
权利人:SYNERGIA LIFE SCIENCES PVT LTD
摘要:The present disclosure relates to a novel process for the synthesis of stereospecific compounds of Vitamin K2 group in general and Vitamin K2-7, in particular. It also discloses novel intermediates useful in the synthesis of stereospecific Vitamin K2-7. Compounds of the Vitamin K2 group obtained are crystalline and exhibit well defined melting points.

专利号:US-2021114953-A1
优先权日:2018-06-08
标题:Synthesis of e,e-farnesol, farnesyl acetate and squalene from farnesene via farnesyl chloride
发明人：FISHER KARL JOSEPH; WOOLARD FRANK XAVIER
权利人:AMYRIS INC
摘要:The present disclosure provides methods for preparing polyunsaturated hydrocarbons, such as E,E-farnesol, farnesyl acetate and squalene, by base catalyzed addition of a dialkylamine to a 3-methylene-1-alkene, such as farnesene. The present disclosure also provides compositions including one more farnesene derivatives prepared using the disclosed methods.

专利号:BR-112020024702-A2
优先权日:2018-06-08
标题 :synthesis of e, e-farnesol, farnesyl acetate and squalene from farnesene via farnesyl chloride

专利号:KR-20210018903-A
优先权日:2018-06-08
标题:Synthesis of E,E-farnesol, farnesyl acetate and squalene via farnesyl chloride from farnesene

专利号:CA-3100362-A1
优先权日:2018-06-08
标题:Synthesis of e,e-farnesol, farnesyl acetate and squalene from farnesene via farnesyl chloride