CAS: 14592-56-4; Bis(Acetonitrile)Palladium(Ii) Dichloride

上下游产品

bis(triphenylphosphine)platinum(II) dichloride acetonitrile dichloro(cyclo°Cta-1,5-diene)palladium (II) 2(tri(methylallyl)arsine)2]cis-[PdCl2(tri(methylallyl)arsine)2]palladium(II) tetraphenylporphyrin [5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato]palladium(II) [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride methyl (α-chloromethyl)acrylate

Palladium Dichloride 以 乙腈 用作溶剂,化学反应生成双(乙腈)氯化钯(II)
参考文献:Structure,Dynamics And Catalytic Activity Of Palladium(II) Complexes With Imidazole Ligands
标题:Structure,Dynamics And Catalytic Activity Of Palladium(II) Complexes With Imidazole Ligands
摘要:Several Palladium Complexes Of The Type [pd(Im)(2)Cl-2],[pd(Im)(3)Cl]Cl,And [pd(Im)(4)]Cl-2 (Im = Imidazole 1,1-Methylimidazole 2,1,2-Dimethylimidazole 3,1-Butylimidazole 4,4A,1-Phenylimidazole 6,1-Phenylimidazoline 7,And 1-Methylimidazoline 8) Were Prepared And Structurally Characterized. The Square Planar Structure Of Two New Complexes With The Composition [pd(Im)(4)]Cl-2 (2B,4B) Was Confirmed By X-Ray Analysis. In Solution,Exchange Of Imidazole Ligands Leading To Heteroleptic Products Was Evidenced By Esi-Ms Studies. Two Bis-Ligated Complexes,Bearing 1-Methylimidazole (2A) And 1-Propoxymethylimidazole (5) Ligands,Were Obtained In The Reaction Of Palladium With Imidazoles Formed By Deprotection Of One Nitrogen Atom In The Respective Imidazolium Halides. Catalytic Suzuki-Miyaura Reactions Were Carried Out Using The Obtained Palladium Complexes In Isopropanol-Water Solution. High Yields Of The Cross-Coupling Products Were Obtained At 40 And 60 Degrees C When 2-Bromotoluene,4-Bromotoluene,And 4-Bromoanizole Were Used As Substrates. (C) 2010 Elsevier B.V. All Rights Reserved.
Doi:10.1016/j.Ica.2010.08.037

专利信息

专利号:WO-2025119975-A1
优先权日:2023-12-04
标 题:A method for synthesis of harmine
发明人：HETT ROBERT; GRAB HANUSCH; LAGOUTTE ROMAN
权利人:RECONNECT LABS AG
摘要:The invention relates to a method of synthesis of a compound of formula (I), harmine, according to the method comprising a step of transforming the compound of formula (II), into the compound of formula (I). The invention further relates to a compound of formula (II), which is an intermediate in synthesis of harmine according to the present invention.

专利号:US-10918627-B2
优先权日:2016-05-11
标 题:Convergent and enantioselective total synthesis of Communesin analogs
发明人：MOVASSAGHI MOHAMMAD; LATHROP STEPHEN PAUL; POMPEO MATTHEW W; CHANG WEN-TAU TIMOTHY
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:A highly convergent biomimetic synthesis of a complex polycyclic scaffold has been successfully implemented. From these efforts, compounds having a structure of Formula (I): n nor a pharmaceutically acceptable salt, tautomer or stereoisomer thereof, wherein R 1 -R 8 and m, n, r, s, t, and u are as defined herein, is provided. Methods of making such compounds are also disclosed as are methods for the treatment of cancer, various infectious diseases, and abnormal cardiovascular function.

专利号:US-2011130567-A1
优先权日:2009-06-03
标题 :Steroselective synthesis of certain trifluoromethyl-substituted alcohols
发明人：FANDRICK DANIEL R; REEVES JONATHAN T; SONG JINHUA J; TAN ZHULIN; QU BO; YEE NATHAN K; RODRIGUEZ SONIA
权利人:BOEHRINGER INGELHEIM INT
摘要:A process for stereoselective synthesis of a compound of Formula (X) n n n n n n n n n n wherein:n R 1 is an aryl group substituted with one to three substituent groups,n wherein each substituent group of R 1 is independently C 1 -C 5 alkyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, halogen, carboxy, cyano, or trifluoromethyl,n wherein each substituent group of R 1 is optionally independently substituted with one to three substituents selected from C 1 -C 3 alkyl, C 1 -C 3 alkoxy, phenyl, and alkoxyphenyl; n n R 2 and R 3 are each independently C 1 -C 5 alkyl; R 4 is C 1 -C 5 alkyl optionally independently substituted with one to three substituent groups,n wherein each substituent group of R 4 is independently C 1 -C 3 alkyl, hydroxy, halogen, amino, or oxo; and n R 5 is a heteroaryl group substituted with one to three substituent groups,n wherein each substituent group of R 5 is independently C 1 -C 5 alkyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsulfonylamino, aminosulfonyl, C 1 -C 5 alkylaminosulfonyl, C 1 -C 5 dialkylaminosulfonyl, halogen, hydroxy, carboxy, cyano, trifluoromethyl, trifluoromethoxy, trifluoromethylthio, or C 1 -C 5 alkylthio wherein the sulfur atom is optionally oxidized to a sulfoxide or sulfone.

专利号:US-7429658-B2
优先权日:2003-09-11
标题 :Synthesis of protected pyrrolobenzodiazepines
发明人：HOWARD PHILIP; MASTERSON LUKE
权利人:SPIROGEN LTD
摘要:A method of synthesis of a N-10 protected PBD compound of formula (I): n nvia an intermediate of formula (II) or formula (V):

专利号:WO-2024073221-A1
优先权日:2022-09-29
标题:Synthesis of palladium(0) phosphine complexes
发明人：MACQUEEN PRESTON; GHORAI SUBIR; COLACOT THOMAS
权利人:SIGMA ALDRICH CO LLC
摘要:Provided is an optimized process for the synthesis of palladium(O) phosphine complexes. The process described herein is characterized by a more efficient reaction control, high yield and purity, the use of readily available starting materials, and savings in reaction time and steps, thereby offering increased sustainability when compared to processes reported in the state of the art.

专利号:US-6700001-B2
优先权日:2001-10-05
标 题:Process for stereoselective synthesis of 2-hydroxymethyl chromans
发明人：GROSS JONATHAN L; STACK GARY P
权利人:WYETH CORP
摘要:A process for the stereoselective synthesis of 2-hydroxymethyl-chromans of formula (II) is providedwhere R, R<1>, R<2 >and R<3 >are as defined herein. The compound of formula (II) is prepared using an optically active benzene compound of formula (I)where R<0 >is as defined herein. The 2-hydroxymethyl-chroman compounds of formula (II) are useful as intermediates for preparing a variety of medicinal agents.