CAS: 16292-95-8; 3-Methoxy-4-Nitrophenol

相似化合物

4920-84-7 14227-18-0 6665-97-0

上下游产品

CAS号448-19-1 5-氟-2-硝基苯甲醚 | CAS号394-41-2 3-氟-4-硝基苯酚 | CAS号124-41-4 甲醇钠 | CAS号67-56-1 甲醇 | CAS号91-23-6 2-硝基苯甲醚 | CAS号865-33-8 甲醇钾 | CAS号150-19-6 3-甲氧基苯酚 | CAS号446-36-6 5-氟-2-硝基苯酚 | CAS号6615-24-3 1-Ethynyl-4-(4-... | CAS号5446-02-6 4-甲氧基水杨酸甲酯 | CAS号61638-01-5 3-甲氧基-4-氨基苯酚

2-硝基苯甲醚置于过氧化氢异丙苯,Potassium Tert-Butylate体系中,用 氨 用作溶剂,化学反应 1.0H,以8%的收率获得3-甲氧基-4-硝基苯酚
参考文献:Hydroxylation Of Nitroarenes With Alkyl Hydroperoxide Anions Via Vicarious Nucleophilic Substitution Of Hydrogen
标题:Hydroxylation Of Nitroarenes With Alkyl Hydroperoxide Anions Via Vicarious Nucleophilic Substitution Of Hydrogen
摘要:Carbo--And Heterocyclic Nitroarenes React With Anions Of Tert-Butyl And Cumyl Hydroperoxides In The Presence Of Strong Bases To Form Substituted O-And P-Nitrophenols. The Reaction Usually Proceeds In High Yields And Is Of Practical Value As A Method Of Synthesis And Manufacturing Of Nitrophenols. Orientation Of The Hydroxylation Can Be Controlled To A Substantial Extent By Selection Of The Proper Conditions. Basic Mechanistic Features Of This Process Were Clarified.
Doi:10.1021/jo970726M

专利信息

专利号:RU-2119482-C1
优先权日:1991-01-11
标 题:Acridine derivatives, method of synthesis, pharmaceutical composition and a method of treatment of patients with malignant tumors