CAS: 24772-63-2; 1,8-Diiodooctane

该化合物是一种有机化合物,其特点是其直线烷结构,其两个碘原子附着于一个辛醇链的第一个和第八个碳原子,其分子式为C8H16I2,表明存在八个碳原子,十六个氢原子和两个碘亚原子,该化合物在室内温度下一般没有色,不会粉黄黄色液体,其密度和粘度高于非碘碳氢化合物.1.8-二iodooctane在有机溶剂中是溶解的,但由于缺水碳烷骨骼,其水溶性有限.碘原子的存在具有独特的特性,例如分子重量增加,有机合成中的潜在应用,特别是在药用化学和材料科学领域.此外,该混合物由于存在碘亚体,可能表现出有趣的再活动性,因为碘亚组体可以参与各种化学反应,包括核糖替代.在处理该化合物时,应当采取安全防范措施,因为在某些浓度中,碘可能具有危险性.

结构式图片

相似化合物

16355-92-3 629-09-4 628-77-3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

1,8-°Ctanediol 1,8-dibromo°Ctane 1,8-diphenoxy°Ctane hydrogen iodide 1,12-dodecanedioic acid 1,8-bis(phenylthio)°Ctane 1,N8-diphenyl°Ctane-1,8-diamineN1,N8-diphenyl°Ctane-1,8-diamine 1,8-dimethoxy°Ctane

合成工艺路线路线简述

    1,8-二溴辛烷置于sodium Iodide体系中,用 丙酮 用作溶剂,化学反应 24.0H,以95%的收率获得1,8-二碘辛烷
    参考文献:限于动态超分子主体的二卤化物的高度选择性自由基单还原.
    标题:限于动态超分子主体的二卤化物的高度选择性自由基单还原.
    摘要:(的烷基二卤化物客人减少2-5和7)三烷基硅烷与(r 3在水溶性宿主进行的sih)1来调查快速自由基反应限制效应(ķ >=10 3 米-1 小号-1).在温和条件下,对初级和次级二卤化物客人观测到单还原产物的高选择性(> 95%).结果突出了主客体络合速率对调节自由基反应中产物选择性的重要性.
    Doi:10.1002/chem.202004953

    专利信息


    专利号:US-7557099-B2
    优先权日:2004-03-01
    标题 :Pyrrolobenzodiazepines as key intermediates in the synthesis of dimeric cytotoxic pyrrolobenzodiazepines
    发明人:HOWARD PHILIP WILSON; KANG GYOUNG-DONG
    权利人:SPIROGEN LTD
    摘要:Compounds and a method of synthesis of compounds of formula (Ia) or (Ib): and salts, solvates, and chemically protected forms thereof, wherein the dotted lines indicate the optional presence of a double bond between C1 and C2 or C2 and C3; R 2 and R 3 are independently selected from —H, â•?O, â•?CH 2 , —CN, —R, OR, halo, â•?CH—R, O—SO 2 —R, CO 2 R and COR; R 10 is a carbamate-based nitrogen protecting group; and R 11 is an oxygen protecting group.

    专利号:US-9783634-B2
    优先权日:2012-02-15
    标题 :Synthesis of photovoltaic conjugated polymers
    发明人:WANG SHUANGXI; SHI CHENJUN; CHEN RUBY; ZHANG JUNLIAN; WANG WEI; WU YUE; HUANG HUI; PALKAR AMIT; HE TING
    权利人:PHILLIPS 66 CO; SOLARMER ENERGY INC
    摘要:A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.

    专利号:US-10236457-B2
    优先权日:2016-06-29
    标题 :Synthesis of porphyrin materials for highly efficient organic photovoltaics
    发明人:ZHU XUNJIN; CHEN SONG; WONG WAI YEUNG; WONG WAI KWOK
    权利人:UNIV HONG KONG BAPTIST UNIV
    摘要:The present disclosure relates to porphyrin small molecules that can be represented by, e.g., a compound of Formula IV designed and synthesized for bulk heterojunction (BHJ) organic solar cells (OSCs). Provided are synthesized materials with strong and ordered self-assembly property, leading to form bi-continuous, interpenetrating networks which are required for efficient charge separation and transport in organic solar cells. The power conversion efficiency (PCE) of the solar cells devices based on the embodiments of the present disclosure have the highest PCE among the solution-processed BHJ solar cell based on porphyrin small molecules to date.

    专利号:US-10787537-B2
    优先权日:2018-01-29
    标 题:Synthesis of polymers for organic photovoltaics
    发明人:BULLOCK JOE; WORFOLK BRIAN; EARMME TAESHIK; PAN HUALONG; WOODY KATHY
    权利人:PHILLIPS 66 CO
    摘要:A method of coupling n nand 5,5-Y-3,3′-difluoro-2,2′-bithiophene to producen n n n n n n n n n n n n wherein X can be any known compound capable of coupling with the Y-difluorothiophene and Y is selected from the group consisting of Br, a stannyl group, a boronic ester and a H.

    专利号:US-9595676-B2
    优先权日:2013-08-27
    标 题:Synthesis of water soluble doped conjugated polyelectrolytes for applications in organic electronics
    发明人:BAZAN GUILLERMO C; MAI CHENG-KANG
    权利人:UNIV CALIFORNIA
    摘要:A method of fabricating a composition of matter, including fabricating one or more conjugated polyelectrolytes each comprising a donor-acceptor copolymer backbone and one or more anionic side groups, wherein the one or more conjugated polyelectrolytes are self doped. The doped conjugated polyelectrolytes can be used in a hole transport layer in a solar cell.

    专利号:US-9735365-B2
    优先权日:2014-07-21
    标题:Low band gap polymer compound, synthesis of thereof, and organic photovoltaic cell containing the same
    发明人:KIM BONG SOO; LEE HYO SANG; KIM HONG GON; KO MIN JAE; LEE DOH-KWON; KIM JIN YOUNG; SON HAE JUNG
    权利人:KOREA INST SCI & TECH
    摘要:The present disclosure relates to a novel polymer compound and a method for preparing the same. More particularly, the present disclosure relates to a novel conductive low band gap electron donor polymer compound having high photon absorptivity and improved hole mobility, a method for preparing the same and an organic photovoltaic cell containing the same. Since the conductive polymer compound as a low band gap electron donor exhibits high photon absorptivity and superior hole mobility, it can be usefully used as a material for an organic optoelectronic device such as an organic photodiode (OPD), an organic thin-film transistor (OTFT), an organic light-emitting diode (OLED), an organic photovoltaic cell, etc. as well as in the development of a n-type material.
    铜陵立事达化学科技有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.lishidachem.cn
    企业联系电话:18606623089;19064063435👤
    📞铜陵立事达化学科技有限公司 ⚠️参考联系方式
    联系人:瞿先生;刘经理
    电话:18606623089;19064063435
    手机:18606623089;19064063435

    邮箱:350737036@qq.com
    通信地址: 安徽省铜陵市郊区陈瑶湖镇其凤村向东路192号
    邮编: 244061
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:安徽省铜陵市郊区陈瑶湖镇其凤村向东路192号
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页
    现货

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Jiyun Song, Et Al. Nanostructured Electron-Selective Interlayer For Efficient Inverted Organic Solar Cells. Acs Appl Mater Interfaces. 2015 Aug 26;7(33):18460-6.
    [参考文献]: Qian Liu, Et Al. 9-Arylidene-9H-Fluorene-Containing Polymers For High Efficiency Polymer Solar Cells. Acs Appl Mater Interfaces. 2014 Feb 12;6(3):1601-7.
    [参考文献]: Xing Fan, Et Al. 1,8-Diiodooctane As The Processing Additive To Improve The Efficiency Of P3Ht:Pc61Bm Solar Cells. J Nanosci Nanotechnol. 2014 May;14(5):3592-6.

    合成参考文献


    摘要:Bao, Z.; Wang, J., Science of Synthesis: Knowledge Updates, (2023) 2, 34.
    参考文献:10.1038/srep05071
    摘要:Zhang L, Xing X, Zheng L, Chen Z, Xiao L, Qu B, Gong Q. Vertical phase separation in bulk heterojunction solar cells formed by in situ polymerization of fulleride. Scientific Reports. 2014 May 27;4(1):5071. doi: 10.1038/srep05071.
    参考文献:10.1038/ncomms9547
    摘要:Kim T, Kim J, Kang TE, Lee C, Kang H, Shin M, Wang C, Ma B, Jeong U, Kim T, Kim BJ. Flexible, highly efficient all-polymer solar cells. Nature Communications. 2015 Oct 09;6(1):8547. doi: 10.1038/ncomms9547.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知