专利号:US-6770436-B1 优先权日:1996-11-14 标题:Chemical amplification for the synthesis of patterned arrays 发明人:BEECHER JODY E; GOLDBERG MARTIN J; MCGALL GLENN H 权利人:AFFYMETRIX INC 摘要:Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers. When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions. The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.
专利号:US-8815351-B2 优先权日:2005-09-15 标 题:Method for attachment of silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds 发明人:OWENS JEFFREY R 权利人:OWENS JEFFREY R; US AIR FORCE 摘要:A method for attaching silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds is described. Attaching silicon-containing compounds to a surface comprises providing a silicon-containing compound having two or more leaving groups, and a first functional compound comprising at least one nucleophilic group, contacting the silicon-containing compound and the functional compound with a surface of a substrate having nucleophilic sites and exposing the silicon-containing compound, the functional compound and the surface of the substrate to microwave radiation.
专利号:US-2004110133-A1 优先权日:2002-12-06 标 题 :Functionated photoacid generator for biological microarray synthesis 发明人:XU GUANGYU; GOLDBERG MARTIN 权利人:AFFYMETRIX INC 摘要:In some embodiment of the invention, methods are provided for the synthesis of polymer arrays. In one embodiment, a chemically amplified polymer matrix is used for the synthesis of polymer arrays.
专利号:US-7053198-B2 优先权日:2002-12-06 标题 :Functionated photoacid generator and functionated polymer system for biological microarray synthesis 发明人:GOLDBERG MARTIN; XU GUANGYU 权利人:AFFYMETRIX INC 摘要:In some embodiment of the invention, methods are provided for the synthesis of polymer arrays. In one embodiment, a reactive polymer and a photo acid generator is used for the photodirected polymer array synthesis.
专利号:WO-2013135701-A1 优先权日:2012-03-13 标题:Synthesis of polyphenol disulphides 发明人:FLECKENSTEIN CHRISTOPH; DENECKE HARTMUT; FUCHS SABINE; MUELLER MATTHIAS; DOERING MANFRED; CISIELSKI MICHAEL; WAGNER JOCHEN; DEGLMANN PETER; NALAWADE SAMEER; GUTMANN PETER; HAHN KLAUS; MASSONNE KLEMENS; KLEINKE ANDREAS; KRAEMER ROLAND HELMUT 权利人:BASF SE 摘要:The invention relates to a process for producing a polyphenol disulphide of formula (I) by reacting one or more mercaptophenols of formula (II) with one or more oxidizing agents, optionally in the presence of one or more bases, where the symbols R 1 , R 2 , R 3 , R 4 and n have the meanings given in the description.
专利号:WO-2020238440-A1 优先权日:2019-05-24 标 题:Semi-aromatic polyamide, method for synthesis thereof, and polyamide molding composition consisting thereof 发明人:HUANG XIANBO; ZHANG CHUANHUI; YE NANBIAO; CAO MIN; JIANG SUJUN; ZHOU ZHUXIN; YAN KUN; PENG ZHONGQUAN 权利人:KINGFA SCIENCE & TECHNOLOGY CO; ZUHAI VANTEQUE SPECIALTY ENG PLASTICS CO LTD 摘要:Provided is a semi-aromatic polyamide, comprising, on the basis of the molar content of all repeating units, the following repeating units: 46‑54 mol% of 10T unit derived from 1,10‑diaminodecane and terephthalic acid, 46-54 mol% derived from one or more monomers in diacid Y containing 4-36 carbon atoms, and XY unit consisting of one or more monomers in diamine X containing 4-36 carbon atoms; the 10T unit and XY unit in the semi-aromatic polyamide chain segment are arranged in an alternating order ... 10TXY10TXY10TXY 10TXY10TXY ...; the semi-aromatic polyamide at least contains three monomers. In the semi-aromatic polyamide prepared by means of the special preparation method, 10T and XY units are arranged alternately, and in comparison with ordinary random copolymerized semi-aromatic polyamides, it has higher crystallinity and a higher melting point, and the water absorption rate is low.