Potassium <13C>Cyanate置于硫酸氢铵,Ammonium Hydroxide体系中,化学反应 4.0H,以87%的收率获得产物尿素-13C
参考文献:Concomitant Oxygen‐18 Enrichment In Commercial Carbon‐13 Labelled Urea
标题:Concomitant Oxygen‐18 Enrichment In Commercial Carbon‐13 Labelled Urea
摘要:By Mass Spectroscopy,50-Fold Oxygen-18 Enrichment Over Natural Abundance Was Observed In Commercial C-13-Urea (99 Atom % C-13) Synthesized From C-13-Carbon Monoxide That Had Been C-13-Enriched By Cryogenic Distillation. In Contrast,C-13-Urea Synthesized From C-13-Potassium Cyanide (A C-13-Labelled Compound Having No Oxygen Atom) Showed The Natural Abundance Level Of Oxygen-18.
DOI:10.1002/(Sici)1099-1344(199612)38:12<1133::Aid-Jlcr935>3.0.Co;2-#