CAS: 63488-10-8; 4-Tert-Butylphenylmagnesium Bromide

该化合物是一种在有机合成中常用的灰色试剂,用于引入4-之三-丁基苯基化合物,这种有机金属化合物具有高度反应性,能够在诸如核生殖器添加和交叉组合等反应中有效地形成碳-碳联结,通常作为二乙基乙基或四氟甲烷的一种溶液供应,确保在惰性条件下的稳定性和易于处理.二丁基亚基成分会增强消毒和电子效应,使其在包括制药和先进材料在内的复杂分子合成中具有价值.在无水和无氧条件下适当储存对保持其再活动至关重要.处理需要严格遵守安全协议,因为其交火性.

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1-bromo-4-tert-butylbenzene magnesium 1-methoxy-2-methyl-4-bromo-6-tert-butyl-indane sodium hydrogencarbonate 2-(4-tert-butylphenyl)ethanol (4-tert-butylphenyl)trimethylsilane 4-tert-Butyl-4',4''-dimethyltriphenylmethanol tert-butyl-phenyl)-dichloro-methyl-silane(4-tert-butyl-phenyl)-dichloro-methyl-silane

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    专利信息


    专利号:US-7635781-B2
    优先权日:2001-05-15
    标 题:Synthesis of cyclopentadiene derivatives
    发明人:NIFANT EV ILYA; KASHULIN IGOR; IVCHENKO PAVEL; KLUSENER PETER; KORNDORFFER FRANS; DE KLOE KEES; RIJSEMUS JOS
    权利人:BASELL POLYOLEFINE GMBH
    摘要:A compound of formula (X): n n n n n n n n n n n n wherein n R 1 , R 2 , equal to or different from each other are hydrogen or a linear or branched saturated or unsaturated C 1 -C 20 -alkyl, C 3 -C 20 -cycloalkyl, C 6 -C 20 -aryl, C 7 -C 20 -alkylaryl or C 7 -C 20 -arylalkyl radical, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or they can form a C 4 -C 7 ring optionally containing O, S, N, P or Si atoms that can bear substituents; n R 3 is hydrogen or a linear or branched saturated or unsaturated C 1 -C 20 -alkyl, C 3 -C 20 -cycloalkyl, C 6 -C 20 -aryl, C 7 -C 20 -alkylaryl or C 7 -C 20 -arylalkyl radical, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two adjacent R 3 groups can form a C 4 -C 7 ring optionally containing O, S, N, P or Si atoms, wherein said ring can bear substituents; n and at least one of R 1 , R 2 or R 3 is different from hydrogen.

    专利号:US-2008287692-A1
    优先权日:2001-05-15
    标 题:Synthesis of cyclopentadiene derivatives

    专利号:US-2004236115-A1
    优先权日:2001-05-15
    标题 :Synthesis of cyclopentadiene derivatives

    专利号:US-7253292-B2
    优先权日:2001-05-15
    标 题:Synthesis of cyclopentadiene derivatives

    专利号:US-11542346-B2
    优先权日:2018-03-19
    标 题 :Catalysts for olefin polymerization
    发明人:IZMER VYATCHESLAV V; KONONOVICH DMITRY S; VOSKOBOYNIKOV ALEXANDER Z; VIRKKUNEN VILLE; RESCONI LUIGI MARIA CRISTOFORO
    权利人:BOREALIS AG
    摘要:New bisindenyl ligand complexes and catalysts comprising those complexes. The invention is directed to improving the manufacturing of specific C1-symmetric bisindenyl complexes by modifying one of the indenyl ligands in order to improve the selectivity of the complex synthesis towards the desired anti-isomer, increase the yield and simplify the purification of the complex. The invention also relates to the use of the new bisindenyl metallocene catalysts for the production of polypropylene homopolymers or propylene copolymers.

    专利号:CN-113429358-B
    优先权日:2021-06-24
    标 题 :Synthesis method of a kind of molecular glass and its application as high frequency and low dielectric constant material
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    合成参考文献


    摘要:Kaposi, M.; Witt, J.; Cokoja, M.; Kühn, F. E., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 2, 298.
    摘要:Banerjee, S.; Ilies, L., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 361.
    摘要:Zeng, X., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 762.
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