CAS: 126801-58-9; Ethoxysulfuron

该化合物是一种广泛用于谷物和其他作物选择性除草控制的灭菌剂,其高纯度(~90%)确保了抑制乙醇actate合成酶(ALS)的一贯效力,乙醇-氨基酸合成(ALS)是环环链合成中的关键酶,导致有目标的除草.化合物的施用率较低,减少了环境影响,同时保持作物安全.乙氧硫磺对于大叶类杂草和某些草种特别有效,为长期保护提供了残留活动.其有利的溶液和稳定性使其适合各种农产品的配方.适当应用时间和坚持建议剂量对于最佳性能和尽量减少抗药性发育至关重要.

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上下游产品

2-ethoxyphenoxysulfonamide 2-is°Cyanato-4,6-dimethoxypyrimidine 4,6-dimethoxy-2-aminopyrimidine (2-ethoxy-phenoxy)-sulphonyl is°Cyanate

合成工艺路线路线简述

    (2-Ethoxy-Phenoxy)-Sulphonyl Isocyanate,2-氨基-4,6-二甲氧基嘧啶置于盐酸,水,乙醚体系中,用 二氯甲烷 用作溶剂,化学反应 16.0H,以145.0 G (91% Of Theory) Of 3-(4,6-Dimethoxypyrimidin-2-yl)-1-(2-Ethoxyphenoxysulfonyl)Urea Of Melting Point 145°-147oc. Are Obtained的收率获得乙氧嘧磺隆
    参考文献:Heterocyclic 2-Alkoxyphenoxysulfonylureas And The Use Thereof As
    标题:Heterocyclic 2-Alkoxyphenoxysulfonylureas And The Use Thereof As
    摘要:公式i的化合物或其盐,其中r1为乙基,丙基或异丙基,R2为卤素,No2,Cf3,Cn,烷基,烷氧基,烷硫基或烷氧羰基,N为0,1,2或3,Y为o或s,R3为氢,烷基,烯基,炔基或烷氧基; R4为以下式的杂环基##str2## E为ch或n; G为o或ch2,R5和r6为氢,卤素,或为烷基,烷氧基或烷硫基,可选择地被卤素,烷氧基或烷硫基取代,或为--Nr12R13,--ochr7--Co2R12,(C3-C6)环烷基,(C3-C5)烯基,(C2-C4)炔基,(C3-C5)烯氧基或(C3-C5)炔氧基; R7为氢或烷基,R8为烷基,--Chf2或--Ch2Cf3; R9和r10为氢,烷基,烷氧基或卤素; R11为氢,烷基,--Chf2或ch2Cf3; R12和r13彼此独立地为氢,烷基,烯基或炔基,具有出色的除草和植物生长调节性能.

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:WO-2021130756-A1
    优先权日:2019-12-25
    标题:Combinations of non-protein amino acids and acetolactate synthase enzyme inhibitors
    发明人:KLIPCAN LIRON; VAN-OSS PINHASI RUTH
    权利人:THE STATE OF ISRAEL MINISTRY OF AGRICULTURE & RURAL DEVELOPMENT AGRICULTURAL RES ORGANIZATION ARO VO
    摘要:The present invention provides compositions and methods for disrupting protein synthesis in plant cells.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
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    合成参考文献


    参考文献:10.1107/s1600536810024785
    摘要:Fun HK, Goh JH, Rai S, Isloor AM, Shetty P. Methyl 2,6-bis-[(5-chloro-4,6-dimeth-oxy-pyrimidin-2-yl)-oxy]benzoate. Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 30;66(Pt 7):o1869–70.
    参考文献:10.1107/s1600536810024724
    摘要:Fun HK, Goh JH, Rai S, Isloor AM, Shetty P. Methyl 2,6-bis-[(5-bromo-4,6-dimeth-oxy-pyrimidin-2-yl)-oxy]benzoate. Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 30;66(Pt 7):o1871.
    参考文献:10.1107/s1600536810025067
    摘要:Fun HK, Yeap CS, Rai S, Isloor AM, Shetty P. 4,6-Dimeth-oxy-2-(methyl-sulfon-yl)pyrimidine. Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 03;66(Pt 8):o1913.
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