CAS: 1676-63-7; 4'-Ethoxyacetophenone

该化合物是一种有机化合物,其特点是芳香结构和氯酮功能组,其特点是一种代用苯环,代之以与碳基化合物组相对位置的乙氧基组;该化合物一般是一种无色的,可粉黄的黄色液体,具有甜美的香味,使其在香味和口味产业中具有兴趣;其分子式反映碳,氢和氧原子的存在,促成其相对低极化;该化合物在乙醇和乙醇等有机溶剂中溶解,但水溶解性有限;必须谨慎处理该物质,因为若吸入或摄入,可能会对健康造成危害.此外,1-(4-乙氧基苯基)乙酮可以参与各种化学反应,包括弗里德-克利氏纤维的细胞化和核分裂替代,使其成为有机合成的有用中间体.

结构式图片

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ECHA物质C&L通报REACH预注册

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CAS号108-24-7 乙酸酐 | CAS号103-73-1 苯乙醚 | CAS号74-96-4 溴乙烷 | CAS号99-93-4 对羟基苯乙酮 | CAS号79887-14-2 乙氧基苯乙炔 | CAS号75-36-5 乙酰氯 | CAS号876-27-7 乙酸-4-氯苯酯 | CAS号116071-56-8 1-(4-ethoxyphen... | CAS号78-08-0 乙烯基三乙氧基硅烷 | CAS号99-90-1 4-溴苯乙酮 | CAS号55836-71-0 4-乙氧基苯甲酰胺 | CAS号40784-91-6 4'-ethoxyphenyl... | CAS号14333-52-9 Benzeneacetalde... | CAS号141701-93-1 1,3-bis(4-ethox... | CAS号99-93-4 对羟基苯乙酮 | CAS号24430-26-0 1-(4-乙氧基-3-硝基苯基)乙酮 | CAS号23676-09-7 4-乙氧基苯甲酸乙酯 | CAS号62-44-2 非那西丁 | CAS号5459-40-5 4-乙氧基苯乙烯 | CAS号619-86-3 4-乙氧基苯甲酸

合成工艺路线路线简述

    4-乙基苯酚置于吡啶,Dipotassium Peroxodisulfate,氧气,Potassium Carbonate体系中,用 乙腈 用作溶剂,80.0 °C,101.33 Kpa 条件下,反应 16.0H,反应生成4-乙氧基苯乙酮
    参考文献:使用过硫酸钾的苄基sp3 C-h键过渡到羰基的过渡金属和无卤素氧化
    标题:使用过硫酸钾的苄基sp3 C-h键过渡到羰基的过渡金属和无卤素氧化
    摘要:摘要 苯乙酮,二苯甲酮,酰亚胺和苯甲酸等芳基羰基化合物是在温和的条件下,由过硫酸钾作为氧化剂与催化吡啶在乙腈中,由苄基底物制得的.过渡金属和卤素均不参与反应. 苯乙酮,二苯甲酮,酰亚胺和苯甲酸等芳基羰基化合物是在温和的条件下,由过硫酸钾作为氧化剂与催化吡啶在乙腈中,由苄基底物制得的.过渡金属和卤素均不参与反应.
    Doi:10.1055/s-0036-1588429

    海关参考信息

    专利信息


    专利号:US-9969823-B1
    优先权日:2011-09-01
    标题 :Synthesis and polymerization of vinyl triazolium ionic liquids
    发明人:LUEBKE DAVID; NULWALA HUNAID; MATYJASZEWSKI KRZYSZTOF; ADZIMA BRIAN
    权利人:US ENERGY; THE US DEPARTMENT OF ENERGY
    摘要:Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.

    专利号:EP-4428168-A1
    优先权日:2023-03-08
    标 题 :Polyurethane/oligomeric urethane synthesis method by radiation
    发明人:AKBULUT HÜSEYIN; ÇEL KBA SENA; ENADA SEHER; U AKLI MÜGE; DEM RBAY DUYGU
    权利人:CHT TURKEY KIMYA SANAYI VE TICARET A S
    摘要:In particular, the invention relates to the synthesis of radiation-curable polyurethane/oligomeric urethane dispersions of anionic and cationic characters, containing neutralization techniques characterized by the selection of counter ions as monomers and/or agents which can be polymers acting as promoters under radiation, to a radiation polyurethane/oligomeric urethane synthesis method that enables the creation of radiation curable binder systems without using cosolvents, surfactants, emulsifiers, defoamers, stabilizers and additives, wherein all components of the radiation-curable binder systems can be polymerized.

    专利号:US-2023212107-A1
    优先权日:2021-12-30
    标 题:Synthesis of para-alkylated syringyl (meth)acrylate derivatives and photopolymerizable compositions for additive manufacturing in dental applications
    发明人:CHOUDHARY UMESH UPENDRA; SU JESSICA KALAY
    权利人:ALIGN TECHNOLOGY INC
    摘要:The present disclosure provides polymerizable monomers which may be used as reactive diluents in additive manufacturing. The polymerizable monomers may have low vapor pressures and may be compatible with a range of low glass transition temperature oligomers.

    专利号:US-2022145179-A1
    优先权日:2020-11-12
    标题 :Synthesis of aryl 1-(methoxymethyl) vinyl ketones and their use as inhibitors of mild steel corrosion
    发明人:MAZUMDER MOHAMMAD ABU JAFAR; ALI SHAIKH ASROF; ODEWUNMI NURUDEEN; ALHARBI BADER; ALJEABAN NORAH; CHEN TAO; BALHARTH SALEM
    权利人:SAUDI ARABIAN OIL CO; UNIV KING FAHD PET & MINERALS
    摘要:Methods for preparing alkenylphenone corrosion inhibiting compositions may include providing an arylacetone and reacting the arylacetone with formaldehyde in the presence of a strong base catalyst. Corrosion inhibiting compositions may include an alkenylphenone, which may be prepared by a method including providing an arylacetone and reacting the arylacetone with formaldehyde in the presence of a strong base catalyst. Methods of inhibiting corrosion of a steel surface of an oilfield equipment component may include contacting the steel surface with an aqueous solution comprising a corrosion inhibitor. The corrosion inhibitor may include a composition containing an alkenylphenone prepared by reacting an arylacetone with formaldehyde in the presence of a strong base catalyst.

    专利号:US-7250435-B2
    优先权日:1999-10-20
    标 题:Acylsemicarbazides as cyclin dependent kinase inhibitors useful as anti-cancer and anti-proliferative agents
    发明人:NUGIEL DAVID A; CARINI DAVID J; DI MEO SUSAN V; VIDWANS ANUP P; YUE EDDY
    权利人:BRISTOL MYERS SQUIBB PHARMA CO
    摘要:The present invention relates to the synthesis of a new class of indeno[1,2-c]pyrazol-4-ones of formula (I): n nthat are potent inhibitors of the class of enzymes known as cyclin dependent kinases, which relate to the catalytic subunits cdk1-7 and their regulatory subunits know as cyclins A-G.n n This invention also provides a novel method of treating cancer or other proliferative diseases by administering a therapeutically effective amount of one of these compounds or a pharmaceutically acceptable salt form thereof. Alternatively, one can treat cancer or other proliferative diseases by administering a therapeutically effective combination of one of the compounds of the present invention and one or more other known anti-cancer or anti-proliferative agents.

    专利号:US-6407103-B2
    优先权日:1998-04-21
    标 题:Indeno [1,2-c] pyrazol-4-ones and their uses
    发明人:NUGIEL DAVID A; CARINI DAVID J; DI MEO SUSAN V; YUE EDDY W
    权利人:BRISTOL MYERS SQUIBB PHARMA CO
    摘要:The present invention relates to the synthesis of a new class of indeno[1,2-c]pyrazol-4-ones of formula (I):that are potent inhibitors of the class of enzymes known as cyclin dependent kinases, which relate to the catalytic subunits cdk1-9 and their regulatory subunits know as cyclins A-H.This invention also provides a novel method of treating cancer or other proliferative diseases by administering a therapeutically effective amount of one of these compounds or a pharmaceutically acceptable salt form thereof. Alternatively, one can treat cancer or other proliferative diseases by administering a therapeutically effective combination of one of the compounds of the present invention and one or more other known anti-cancer or anti-proliferative agents.
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    主要参考文献

    参考标题:A General Proline‐catalyzed Synthesis Of 4,5‐disubstituted N ‐sulfonyl‐1,2,3‐triazoles From 1,3‐dicarbonyl Compounds And Sulfonyl Azide
    作者:Shanmugam Rajasekar,Pazhamalai Anbarasan |发布日期:2019.12.13
    摘要:An Efficient Proline-Catalyzed Synthesis Of 4,5-Disubstituted-N-Sulfonyl-1,2,3-Triazoles Has Been Accomplished From 1,3-Dicarbonyl Compounds And Sulfonyl Azides. The Developed Reaction Is Suitable For Various Symmetrical And Unsymmetrical 1,3-Dicarbonyl Compounds, Tolerates Various Functional Groups And Affords 4,5-Disubstituted-N-Sulfonyl-1,2,3-Triazoles In Good Yield With Excellent Regioselectivity

    合成参考文献


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    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/Q_schafer832.pdf
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