CAS: 7789-43-7; Cobalt(Ii) Bromide

该化合物是一种无机化合物,其特点是亮红红紫晶晶状,通常是一种水合物(CoBr22H2O),在实验室环境中更常见,在水和极地溶剂中溶解,可溶于钴二溴化物,具有湿性,即它能吸收空气中的湿气.该化合物因其在各种应用中的使用而闻名,包括作为有机合成和制备钴材料的催化剂.就其化学行为而言,钴二溴化物可进行水解,并可使用强酸和强碱作出反应.重要的是,要谨慎地处理这种物质,因为钴化合物有毒,并可能对接触健康造成危害.建议在实验室或工业环境中与钴二溴化物合作时采取适当的安全措施,包括使用个人防护设备.

结构式图片

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20899-99-4

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REACH注册ECHA物质ECHA物质C&L通报REACH预注册

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氢溴酸 Hydrogen Bromide 10035-10-6

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    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-4720573-A
    优先权日:1986-07-31
    标 题:Process for synthesis of glutamic acid from acrylate, amide and synthesis gas
    发明人:LIN JIANG-JEN
    权利人:TEXACO INC
    摘要:A process for the synthesis of glutamic acid intermediate from an acrylate, amide and syngas by reacting them in the presence of a catalyst comprising a cobalt-containing compound, a bis-phosphine ligand and a solvent at a pressure of at least 500 psi and a temperature of at least 50° C. and thereafter extracting the glutamic acid.

    专利号:US-4918222-A
    优先权日:1984-07-27
    标 题 :Process for synthesis of N-acetylglycine
    发明人:LIN JIANG-JEN; KNIFTON JOHN F; YEAKEY ERNEST L
    权利人:TEXACO INC
    摘要:An N-acetylglycine is manufactured by reacting paraformaldehyde with an acetamide and carbon monoxide in the present of a cobalt-containing catalyst promoted by a sulfoxide or dinitride compounds. The presence of sulfoxide or dinitrile ligands are essential for the high yield synthesis of N-acetylglycine and good cobalt recovery.

    专利号:US-5097065-A
    优先权日:1985-04-05
    标题:Process for synthesis of a novel amino acid from styrene, acetamide and syngas
    发明人:LIN JIANG-JEN
    权利人:TEXACO INC
    摘要:A phenyl substituted amino acid derivative is synthesized by reacting styrene, acetamide and synthesis gas with a bimetallic catalyst comprising a rhodium-containing compound and a cobalt-containing compound, optionally in the presence of a solvent at a pressure of at least 500 psi and a temperature of at least 50° C. The novel amino acid contains a carboxylic acid group, an acetamido group at the alpha-position and a phenyl group at the beta-position.

    专利号:US-4892687-A
    优先权日:1986-10-08
    标题:Process for synthesis of amidoacids using a cobalt catalyst and a bidental phosphine ligand
    发明人:LIN JIANG-JEN
    权利人:TEXACO INC
    摘要:A process is disclosed for producing N-acetyl-aminoacid which comprises reacting a feedstock from the group consisting of simple olefins, acetamide and synthesis gas with a catalyst comprising a cobalt-containing compound promoted by a bidental-phosphine ligand in a solvent at a pressure of 500 psi or greater and a temperature of 50 DEG C. or greater. The presence of the ligand increases both reaction rate and cobalt catalyst stability.
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    主要参考文献

    [参考文献]: Yuefan Wang, Et Al. Cobr2-Tmtu-Zinc Catalysed-Pauson-Khand Reaction. Chem Commun (Camb). 2012 Aug 25;48(66):8183-5.
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