90076-65-6 = 82113-65-3 反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 55 - 60 °C 标题:Syntheses And Lipophilicity Measurement Of Nα/n-Terminus-1,1-Dihydroperfluoroalkylated α-Amino Acids And Small Peptides 作者:Desmarteau,Darryl D.; Et Al 参考文献:Journal Of Fluorine Chemistry 日期:2007 卷标:128(10) 页码:1326-1334]
90076-65-6 = 82113-65-3 反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 70 °C 标题:A One-Pot Synthesis Of A Ternary Nanocomposite Based On Mesoporous Silica,Polyaniline And Silver 作者:Rosa,Ana Claudia De Abreu; Et Al 参考文献:Rsc Advances 日期:2013 卷标:3(48) 页码:26142-26148]
421-85-2 + 335-05-7 = 82113-65-3 反应条件:1.1 -1.2 Reagents: Sodium Methoxide,Hexamethyldisilazane1.3 - 标题:2,6-Difluorophenylxenon(Ii) Bis(Fluorosulfonyl)Amide,-Bis(Trifluoromethylsulfonyl)Amide,-Tris(Fluorosulfonyl)Methanide And -Bis(Trifluoromethylsulfonyl)Methanide As New C-Xe-N And C-Xe-C Compounds 作者:Yagupolskii,Yurii L.; Et Al 参考文献:Journal Of Fluorine Chemistry 日期:2002 卷标:113(2) 页码:143-146]
82113-65-3 = 82113-65-3 反应条件:1.1 Reagents: Neodymium Sesquioxide Solvents: Water; 7 H,90 °C 标题:Complexation Reaction For Ln(Iii)/tbp In Ionic Liquid 作者:Li,Rui-Rui; Et Al 参考文献:Yuanzineng Kexue Jishu 日期:2017 卷标:51(3) 页码:396-403]
90076-65-6 = 82113-65-3 反应条件:1.1 Reagents: Sulfuric Acid; Rt -> 90 °C 标题:Ionic Liquid Silver Salt Complexes For Propene/propane Separation 作者:Agel,Friederike; Et Al 参考文献:Physical Chemistry Chemical Physics 日期:2011 卷标:13(2) 页码:725-731]
91742-21-1 = 82113-65-3 反应条件:1.1 Reagents: Sulfuric Acid 标题:N-Fluorobis(Trifluoromethanesulfonyl)Imide. An Improved Synthesis 作者:Desmarteau,Darryl D.; Et Al 参考文献:Journal Of Fluorine Chemistry 日期:1991 卷标:52(1) 页码:7-12]
91742-21-1 = 82113-65-3 [标题:Reaction Conditions 标题:Tetrahetero-Substituted Methanes With A Carbon-Halogen Bond 作者:Il'Chenko,A. Y. 参考文献:Science Of Synthesis 日期:2005 卷标:18 页码:1135-1201]
82113-65-3 = 82113-65-3 反应条件:1.1 Solvents: Benzene; 24 H,Rt 标题:Isolation Of A Dicationic Platinum Complex With Two Accessible Coordination Sites 作者:Bowring,Miriam A.; Et Al 参考文献:Organometallics 日期:2013 卷标:32(19) 页码:5266-5268]
82113-65-3 = 82113-65-3 反应条件:1.1 Reagents: Titanium Solvents: Water; 2 D,Reflux 标题:Rational Optimization Of Lewis-Acid Catalysts For The Direct Amination Of Alcohols,Part 1 - Activity Descriptors For Metal Triflates And Triflimides 作者:Payard,Pierre-Adrien; Et Al 参考文献:European Journal Of Organic Chemistry 日期:2020 卷标:2020(22) 页码:3219-3224]
335-05-7 = 82113-65-3 [标题:Reaction Conditions 标题:Synthesis And Structures Of Alkaline Earth Metal Salts Of Bis[(Trifluoromethyl)Sulfonyl]Imide 作者:Xue,Lixin; Et Al 参考文献:Solid State Sciences 日期:2005 卷标:7(3) 页码:311-318]
82113-65-3 = 82113-65-3 反应条件:1.1 Reagents: Titanium Solvents: Water; 48 H,Reflux 标题:Rational Optimization Of Lewis-Acid Catalysts For Direct Alcohol Amination,Part 2 - Titanium Triflimide As New Active Catalyst 作者:Payard,Pierre-Adrien; Et Al 参考文献:European Journal Of Organic Chemistry 日期:2020 卷标:2020(22) 页码:3225-3228
专利号:US-11926589-B2 优先权日:2019-07-09 标 题 :Process for the synthesis of non-racemic cyclohexenes 发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND 权利人:BASF CORP; CALIFORNIA INST OF TECHN 摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.
专利号:US-2021053913-A1 优先权日:2019-08-22 标题 :Process for the Synthesis of Fluorinated Conductive Salts for Lithium Ion Batteries 发明人:ZHOU CHANGYUE; DU HONGJUN; WU WENTING 权利人:FUJIAN YONGJING TECH CO LTD 摘要:The invention relates to a new process for the synthesis of fluorinated conductive salts for lithium ion batteries (Li-ion batteries). The said fluorinated conductive lithium ion (Li-ion) battery salts of interest in the framework of the present inventions synthesis process, for example, are Li-ion salts such as LiFSI (lithium bis-(fluoromethanesulfonlyl) imide), LiTFSI (lithium bis-(trifluormethanesulfonlyl) imide), and LiTFSFI (lithium trifluoromethanesulfonylfluorosulfonyl imide), with the formulas as displayed in the Table I herein below. LiFSI, LiTFSI and LiFSTFSI are the most promising conducting salts for Lithium ion batteries and essential for future electromobility.
专利号:US-2022219156-A1 优先权日:2019-04-29 标题:Catalyst for the catalytic synthesis of urea 发明人:GLOTZBACH CHRISTOPH; TENHUMBERG NILS; EL HAWARY TAREK; MAKHYNYA YEVGENY; LEITNER WALTER; KLANKERMAYER JÜRGEN; SCHUMACHER HANNAH 权利人:THYSSENKRUPP IND SOLUTIONS AG; THYSSENKRUPP AG 摘要:A ruthenium-phosphine complex can be used as a catalyst in a method for the catalytic synthesis of urea. The method may comprise more particularly a reaction of formamide or of formamide with ammonia in the presence of the catalyst to form urea and hydrogen. Through the use of the ruthenium-phosphine complex as the catalyst, catalytic preparation of urea from formamide or from formamide with ammonia is provided for the first time. This allows for synthesis under mild conditions and virtually no formation of byproducts. Further, using an acid as a cocatalyst in the catalytic synthesis or the reaction can lead to an improvement in urea yield.
专利号:US-5072040-A 优先权日:1989-04-06 标 题:Process for synthesis of sulfonylimides 发明人:ARMAND MICHEL 权利人:CENTRE NAT RECH SCIENT; HYDRO QUEBEC 摘要:The invention relates to a process for the synthesis of sulfonylimides. n The process for the synthesis of sulfonylimides of the general formula M[RSO 2 ) 2 N] y , in which M represents a metal chosen from alkali metals, alkaline earth metals, rare earths, Al, Sc, Y and Th, R represents a monovalent radical chosen from linear or branched aliphatic radicals having 1 to 8 carbon atoms, alicyclic radicals having 3 to 8 carbon atoms, aryl radicals having 3 to 8 carbon atoms, and y is a number equal to the valence of M, is characterized in that an ionic nitride of the formula M 3 N y , in which M and y have the meaning given above, is reacted with a sulfonyl halide of the formula RSO 2 X, in which R has the meaning given above, and X is chosen from F or Cl, in an aprotic polar solvent.
专利号:US-2014194584-A1 优先权日:2013-01-07 标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process 发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC 权利人:ARKEMA FRANCE 摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.
专利号:US-6399820-B2 优先权日:1998-11-04 标题:Process and reagent useful for the synthesis of sulphanilide which is perhalogenated on the carbon borne by the sulphur atom of the sulphanilide function 发明人:DESMURS JEAN-ROGER; MILLET ANDRE; PEVERE VIRGINIE 权利人:RHODIA CHIMIE SA 摘要:The present invention relates to a process and a reagent useful for the synthesis of sulphanilide which is perhalogenated on the carbon borne by the sulphur atom of the sulphanilide function. This persulphonylation process is characterized in that it comprises a step of placing a nucleophile, whose nucleophilic atom is a nitrogen, in contact with a reagent comprising, for successive or simultaneous addition, a heavy halide of sulphonyl, advantageously sulphonyl chloride, and an organic base comprising a trivalent atom from column V whose lone pair is conjugated directly or indirectly to a bond, and in that the organic part of the said sulphonyl is perhalogenated, advantageously perfluorinated, on the carbon borne by the sulphur. Application to the synthesis of intermediates for organic chemistry.
参考文献:10.1021/jp204148q 摘要:Zhong X, Liu Z, Cao D. Improved classical united-atom force field for imidazolium-based ionic liquids: tetrafluoroborate, hexafluorophosphate, methylsulfate, trifluoromethylsulfonate, acetate, trifluoroacetate, and bis(trifluoromethylsulfonyl)amide. J Phys Chem B. 2011 Aug 25;115(33):10027–40. doi: 10.1021/jp204148q. 参考文献:10.1021/ja203983r 摘要:Yoshida K, Nakamura M, Kazue Y, Tachikawa N, Tsuzuki S, Seki S, Dokko K, Watanabe M. Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes. J Am Chem Soc. 2011 Aug 24;133(33):13121–9. doi: 10.1021/ja203983r.