专利号:US-7038062-B2 优先权日:2004-07-01 标题:Synthesis of cyclic trithiocarbonates from epoxides 发明人:PARKER DANE KENTON 权利人:GOODYEAR TIRE & RUBBER 摘要:This invention provides a low cost technique for synthesizing cyclic trithiocarbonates by a simple one step process from epoxides that can be conducted under atmospheric pressure. This synthesis can be depicted as follows: n nwherein R represents a moiety selected from the group consisting of alkyl groups and aryl groups, wherein R′ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, and wherein R″ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, wherein the R moiety and the R′ moiety can be bonded together to form a cyclic structure, with the proviso that R″ represents a hydrogen atom if R′ represents an alkyl group or an aryl group. In this process carbon disulfide and a thiocyanate salt, such as potassium thiocyanate, are reacted with the epoxide in an ionic liquid, such as 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF 6 ) in the presence of water to produce the cyclic trithiocarbonate.
专利号:US-2024010511-A1 优先权日:2019-05-02 标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion 发明人:SAHI SUNIL 权利人:SOLGO INC; SOLGRO INC 摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.
专利号:WO-2024018000-A1 优先权日:2022-07-20 标题 :Modified lignin in the manufacture of organic-inorganic hybrid materials 发明人:VENDAMME RICHARD; RUBENS MAARTEN 权利人:VITO NV 摘要:Organic-inorganic hybrid materials using lignin as the organic phase for the synthesis of thin films are described. These hybrid materials are prepared through the known sol-gel method whereby a metal-oxide precursor and alkoxysilane functionalized lignin are used and subsequently processed to obtain coatings and thin films with a high content in lignin.
专利号:US-7763357-B2 优先权日:2005-01-27 标 题:Polymer composite synthesis in supercritical fluids 发明人:CHARPENTIER PAUL A; LI XINSHENG 权利人:CHARPENTIER PAUL A; LI XINSHENG 摘要:A one step synthetic route of polymeric compositions of a polyolefin and inorganic network consisting of components selected from Si, Zr, Ti, is disclosed. The synthetic route combines parallel reactions of free radical polymerization to form polymer, and hydrolysis of either Si, or Zr, or Ti or both of them precursors. The network consisting of Si, Zr, Ti, is chemically bonded to or within the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules into macromolecular networks. The compositions of the polymeric composites can be easily controlled by adjusting the reactant ratio and reaction rate or conditions such as temperature and pressure, wherein the inorganic compositions disperse in nanoscale within polymeric composites when their concentrations fall below moderate levels. A novel synthesis route for making polymer composites and/or polymer nanocomposites of a polyolefin and an inorganic network consisting of components selected from Si, Zr, Ti, is disclosed. The synthesis route comprises hydrolysis of either Si, or Zr, or Ti alkoxides or mixtures of these precursors within a polymer matrix in supercritical fluids.
专利号:WO-2023196499-A1 优先权日:2022-04-07 标 题:Substrate cleavage for nucleic acid synthesis 发明人:LACKEY JEREMY; DODD DAVID; LANGNER HEERA 权利人:TWIST BIOSCIENCE CORP 摘要:Disclosed herein are methods and compositions for cleavage of nucleic acids from a surface of a solid support. Further described herein are cleavage methods compatible with enzymatic and chemical nucleic acid synthesis methods.
专利号:US-8946466-B2 优先权日:2010-05-18 标 题 :Method for producing polyether carbonate polyols 发明人:Gürtler Christoph; Hofmann Jörg; WOLF AUREL; GRASSER STEFAN 权利人:Gürtler Christoph; Hofmann Jörg; WOLF AUREL; GRASSER STEFAN; BAYER IP GMBH 摘要:The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of at least one double metal cyanide catalyst, wherein the cyanide-free metal salt, the metal cyanide salt or both the mentioned salts used for the preparation of the double metal cyanide catalyst contain(s) from 0.3 to 1.8 mol base equivalents (based on 1 mol of the metal cyanide salt used for the synthesis of the catalyst) of alkaline metal hydroxide, metal carbonate and/or metal oxide.
[参考文献]: Thomas Plénat, Et Al. High-Throughput Single-Molecule Analysis Of Dna-Protein Interactions By Tethered Particle Motion. Nucleic Acids Res. 2012 Jul;40(12):E89.