CAS: 22009-37-6; 7-Methyl-3,4-Dihydronaphthalen-1(2H)-One

上下游产品

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3-(4-甲基苯甲酰)丙酸置于三氟甲磺酸,一水合肼,Sodium Hydroxide体系中,化学反应 10.0H,反应生成7-甲基-3,4-二氢-2H-1-萘酮
参考文献:用二乙基氨基三氟化硫和(三氟甲基)三甲基硅烷对甲硅烷基醚和β-萘酚进行亲电三氟甲基硫醇化
标题:用二乙基氨基三氟化硫和(三氟甲基)三甲基硅烷对甲硅烷基醚和β-萘酚进行亲电三氟甲基硫醇化
摘要:利用二乙基氨基三氟化硫(dast)和(三氟甲基)三甲基硅烷(cf 3 Tms)的组合作为合成三α-三氟甲硫基羰基化合物的亲电三氟甲硫基化合物,已经完成了甲硅烷基醚和β-萘酚的高效且通用的三氟甲硫基化反应.β萘酚的收率很高.该方法的重要特征包括宽泛的官能团耐受性和使用现成的dast / Cf 3 Tms.通过α-三氟甲基硫醇化(+)-4-胆甾烯-3-酮和萘醌的合成证明了该方法的潜力.
Doi:10.1002/adsc.201800366

专利信息

专利号:US-9409879-B2
优先权日:2011-03-29
标 题 :Total synthesis of redox-active 1.4-naphthoquinones and their metabolites and their therapeutic use as antimalarial and schistomicidal agents
发明人：DAVIOUD-CHARVET ELISABETH; LANFRANCHI DON ANTOINE; JOHANN LAURE; WILLIAMS DAVID LEE; CESAR RODO ELENA
权利人:DAVIOUD-CHARVET ELISABETH; LANFRANCHI DON ANTOINE; JOHANN LAURE; WILLIAMS DAVID LEE; CESAR RODO ELENA; CENTRE NAT RECH SCIENT
摘要:Naphthoquinones, azanaphthoquinones and benxanthones, their process of synthesis and methods of their use as antimalarial or antischistosomal agents.

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优先权日:2004-02-13
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优先权日:2013-12-05
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专利号:US-2014121238-A1
优先权日:2011-03-29
标 题:Total synthesis of redox-active 1.4-naphthoquinones and their metabolites and their therapeutic use as antimalarial and schistomicidal agents

专利号:WO-2021097139-A1
优先权日:2019-11-15
标 题 :Chiral synthesis of a tertiary alcohol