专利号:US-7429672-B2 优先权日:2006-06-09 标题 :Process for the direct synthesis of trialkoxysilane 发明人:LEWIS KENRICK M; CAMERON RUDOLPH A; RITSCHER LEGAL REPRESENTATIVE KAREN 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:This invention discloses a process to improve reaction stability in the Direct Synthesis of trialkoxysilanes. The process is particularly effective in the Direct Synthesis of triethoxysilane and its higher alkyl cognates providing improved triethoxysilane yields.
专利号:US-9249165-B2 优先权日:2013-08-30 标题 :Slurry phase direct synthesis of organohalosilanes from cyclone fines 发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; MEREIGH ABELLARD T; RAZZANO JOHN; NEELY JOHN DAVID 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The present invention is directed to a process for the synthesis of organohalosilane monomers, comprising the steps of (1) forming a slurry of cyclone fines, ultra fines and/or spent contact mass in a thermally stable solvent and reacting the agitated slurry with an organohalide of the formula R 1 X in the presence of an additive for a time and at a temperature sufficient to produce organohalosilane monomers having the formulae R 1 SiHX 2 , R 1 2 SiHX, R 1 3 SiX, R 1 SiX 3 , and R 1 2 SiX 2 ; wherein R 1 is a saturated or unsaturated aromatic group, a saturated or unsaturated aliphatic group, alkaryl group, or cycloaliphatic hydrocarbyl group, and X is a halogen; and (2) recovering said organohalosilane monomers.
专利号:US-6906214-B2 优先权日:2001-07-04 标题:Preparation of aromatic organozinc compounds and composition therefore 发明人:PERICHON JACQUES; GOSMINI CORINNE; FILLON HYACINTHE 权利人:RHODIA CHIMIE SA 摘要:The invention relates to a technique for preparing aromatic organozinc compounds and to a composition therefore. This composition constitutes a reactant that can be used to carry out the synthesis of organozinc compounds, and comprises a cobalt salt, a zinc salt, a polar aprotic solvent and elemental zinc in divided form, the elemental zinc being in solid form, the other elements being in a form dissolved in the solvent. Application to organic synthesis.
专利号:US-2004024238-A1 优先权日:1999-07-02 标 题:Use of nitriles as polar aprotic solvents 发明人:LAURAIN NATHALIE; ZARD SAMIR 摘要:The invention concerns the use of aliphatic nitriles with relatively high molecular weight, as polar aprotic solvents, in particular in nucleophilic substitution reactions of the aromatic type. Said nitriles have a molecular mass more 79, preferably more than 90. The invention is useful for synthesis of fluorinated aromatic compounds.
专利号:EP-4556461-A1 优先权日:2023-11-16 标 题 :Process for the synthesis of salts with an organic anion useful as ionic conducting materials 发明人:KUNERT ROMAIN; BERNARD LAURENT; PICARD LIONEL 权利人:COMMISSARIAT ENERGIE ATOMIQUE 摘要:The present invention relates to a process for the preparation of a salt comprising an organic anion corresponding to a formula (I) comprising: M + , an alkali metal cation; R 1 , R 2 , R 3 , R 4 , independently, a radical chosen from: chlorine, anionic sulfonamide units of formula (IIa): R a -SO 2 -N - -, and anionic dinitrile units of formula (IIIa): CN-(R b ) - CN, with at least one of the radicals R 1 , R 2 , R 3 , R 4 being other than chlorine; said process comprising at least the step of contacting, in a solvent medium and in the presence of an alkali metal base, chloranil with at least one compound of formula (II) R a -SO 2 -NH 2 or (III) CN-R b -CN to form said salt comprising an organic anion of formula (I).
专利号:US-4219684-A 优先权日:1979-04-02 标 题 :Synthesis of alcohols by hydroformylation with nitrile promoter 发明人:IMAI TAMOTSU 权利人:UOP INC 摘要:Alcohols may be synthesized by reacting an olefinic compound, carbon monoxide and hydrogen in the presence of a Group VIII organometallic complex catalyst at reaction conditions which include a temperature in the range of from about 50° to about 250° C. and a pressure in the range of from about 10 to about 300 atmospheres. In addition, the reaction is also effected in the presence of a promoter compound comprising a nitrile.
摘要:Scott, P. J. H., Science of Synthesis Knowledge Updates, (2013) 4, 248. 摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#03162 摘要:Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz., 19(225), 1969 [] 参考文献:10.1007/s00253-019-09915-8 摘要:Chen Z, Zhao J, Jiang S, Wei D. Recent research advancements on regioselective nitrilase: fundamental and applicative aspects. Applied Microbiology and Biotechnology. 2019 Jun 24;103(16):6393–405. doi: 10.1007/s00253-019-09915-8.