专利号:WO-2025202701-A1 优先权日:2024-08-21 标 题 :Marine antifouling paint based on silyl acrylate copolymer synthesis 发明人:LAHEGHI NEJAD FARHAD 权利人:LAHEGHI NEJAD FARHAD 摘要:This invention involves the production of marine anti-fouling paint using the synthesis of silyl acrylate copolymers. One of the most effective anti-algae or anti-fouling paints was self-polishing paints based on acrylate resins containing tributyl tin, which were banned due to the toxicity of their tin compounds. One of the best-introduced alternatives is self-polishing paints based on silyl acrylate copolymers, but their performance is subpar and they have a shorter lifespan. In this invention, silyl acrylate copolymers in a controlled structure, including at least one soft monomer such as butyl acrylate, ethyl acrylate, etc., at least one hard monomer such as methyl methacrylate, 2-methoxyethyl methacrylate, etc. and at least one functional monomer such as triisopropyl silyl acrylate, triisopropyl silyl methacrylate, tertiary-butyl dimethyl silyl methacrylate, and tri-N-butyl silyl methacrylate were synthesized in which monomers or hard monomers were gradually added to the reactor in 2-6 hours.
专利号:US-9540520-B2 优先权日:2011-08-17 标 题 :Synthesis of copper pyrithione from zinc pyrithione and copper compound 发明人:KAPPOCK PAUL S; MARTIN ROBERT J 权利人:KAPPOCK PAUL S; MARTIN ROBERT J; ARCH CHEM INC 摘要:A composition containing unique particles of copper pyrithione wherein greater than 20 wt % to 90 wt % of the particles have a particle size of greater than 10 microns, as determined by laser light scattering using a particle size distribution analyzer, and wherein the particles are flat acicular needle-shaped is described herein. Also described herein is an antifouling paint containing the copper pyrithione and a method of making the composition and antifouling paint.
专利号:US-9156997-B2 优先权日:2010-02-19 标 题:Synthesis of zinc acrylate copolymer from acid functional copolymer, zinc pyrithione, and copper compound 发明人:KAPPOCK PAUL S; TAKAHASHI KAZUNOBU 权利人:ARCH CHEM INC 摘要:Disclosed is a composition containing zinc ester functional polymer and particulate copper pyrithione, wherein the particles have an average aspect ratio within a range of from about 8 to about 15, where the zinc ester functional polymer and the copper pyrithione are obtained by reacting an acid functional polymer with zinc pyrithione and a copper salt or a copper carboxylate. Also disclosed is an antifouling coating containing such a composition.
专利号:BR-102014014775-B1 优先权日:2014-06-16 标 题 :PROCESS OF SYNTHESIS OF A COMPOUND
专利号:US-2011206632-A1 优先权日:2010-02-19 标题:Synthesis of zinc acrylate copolymer from acid functional copolymer, zinc pyrithione, and copper compound
专利号:TW-I535702-B 优先权日:2011-08-17 标 题:Synthesis of copper pyrithione from zinc pyrithione and copper
参考文献:10.3390/molecules26154570 摘要:Li TX, Chen Y, Liu HF, Ma CY, Yang W. Vectorizing Pro-Insecticide: Influence of Linker Length on Insecticidal Activity and Phloem Mobility of New Tralopyril Derivatives. Molecules. 2021 Jul 28;26(15):4570. doi: 10.3390/molecules26154570.