CAS: 124-19-6; Nonanal

化学文摘社编号为124-19-6的无色液体,其特点是由9个碳原子组成的直链结构,具有纯链状藻类的特征,其分子分子式为C9H18O,在碳链的一端具有独特的正丁二烯功能组(CHO).非氨酸是一种无色液体,在室温下具有强,脂肪和类似于柑橘的味道,使其在香味工业中有用.它略微溶于水,但在有机溶剂中更易溶,反映其疏水性.非氨酸通常存在于各种自然来源中,包括基本油和某些水果,有助于其芳香.从活动角度而言,它可以发生典型的正丁酸反应,例如氧化成非亚酸或减少产生非氨醇.由于其特性,非氨酸用于香味,香水和有机合成的潜在中间体.安全考虑包括其潜在的刺激效应,需要适当的处理和储存规程.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

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CAS号111-66-0 1-辛烯 | CAS号201230-82-2 carbon monoxide | CAS号112-80-1 油酸 | CAS号120-87-6 9,10-二羟基硬脂酸 | CAS号872-05-9 正癸烯 | CAS号143-08-8 1-壬醇 | CAS号112-62-9 油酸甲酯 | CAS号111-67-1 2-辛烯 | CAS号124-38-9 二氧化碳 | CAS号50-00-0 甲醛 | CAS号102998-76-5 1-phenylundec-1... | CAS号104943-23-9 2,5-二氧代吡咯烷-1-基壬酸酯 | CAS号4282-42-2 1-碘壬烷 | CAS号593-45-3 正十八烷 | CAS号506-37-6 神经酸 | CAS号93-55-0 苯丙酮 | CAS号14077-84-0 2,4,6(1H,3H,5H)... | CAS号2243-24-5 N-nonylidenehyd... | CAS号184848-25-7 (4R)-4-benzyl-3...

合成工艺路线路线简述

  • 合成目标产物 1-Nonanal 主要起始原料 Methyl Oleate
  • 143-08-8 = 124-19-6 + 112-05-0 + 87310-12-1
    反应条件:1.1 Reagents: Sodium Bromate Catalysts: Hydrochloric Acid,4-(Benzoylamino)-2,2,6,6-Tetramethyl-1-Piperidinyloxy Solvents: Dimethylformamide,Water; 2 H,Rt
    标题:4-Benzamido-Tempo Catalyzed Oxidation Of A Broad Range Of Alcohols To The Carbonyl Compounds With Nabro3 Under Mild Conditions
    作者:Shen,Jiaxuan; Et Al
    参考文献:Chinese Journal Of Chemistry 日期:2014 卷标:32(5) 页码:405-409]

    143-08-8 = 124-19-6 + 87310-12-1
    反应条件:1.1 Reagents: Pyridine Catalysts: Iodine,4-Acetamido-Tempo Solvents: Dichloromethane,Water; 3 H,20 - 25 °C1.2 Reagents: Sodium Thiosulfate Solvents: Water
    标题:Oxidative Dimerization Of Alcohols In The Presence Of Nitroxyl Radical-Iodine Catalytic System
    作者:Kashparova,V. P.; Et Al
    参考文献:Russian Journal Of General Chemistry 日期:2016 卷标:86(11) 页码:2423-2426]

    143-08-8 = 124-19-6 + 87310-12-1
    反应条件:1.1 Reagents: Oxygen Catalysts: Palladium Solvents: (Trifluoromethyl)Benzene; 24 H,1 Atm,60 °C
    标题:Non-Plasmonic Metal Nanoparticles As Visible Light Photocatalysts For The Selective Oxidation Of Aliphatic Alcohols With Molecular Oxygen At Near Ambient Conditions
    作者:Tana,Tana; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2016 卷标:52(77) 页码:11567-11570]

    143-08-8 = 124-19-6 + 87310-12-1
    反应条件:1.1 Reagents: Sodium Bicarbonate,Iodine Catalysts: 4-Acetamido-Tempo Solvents: Dichloromethane,Water; 20 - 22 °C; 3 H,20 - 22 °C1.2 Reagents: Sodium Thiosulfate Pentahydrate Solvents: Water; 5 Min,20 - 22 °C
    标题:A Tempo-Like Nitroxide Combined With An Alkyl-Substituted Pyridine: An Efficient Catalytic System For The Selective Oxidation Of Alcohols With Iodine
    作者:Kashparova,Vera P.; Et Al
    参考文献:Tetrahedron Letters 日期:2017 卷标:58(36) 页码:3517-3521]

    143-08-8 = 124-19-6 + 1680-36-0 + 112-05-0 + 87310-12-1
    反应条件:1.1 Reagents: Sodium Bicarbonate,Potassium Iodide,4-Acetamido-Tempo Catalysts: 2,6-Lutidine Solvents: Dichloromethane,Water; Ph 8.6,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 5,Rt
    标题:One-Pot Electrochemical Synthesis Of Acid Anhydrides From Alcohols
    作者:Kashparova,V. P.; Et Al
    参考文献:Russian Journal Of General Chemistry 日期:2017 卷标:87(11) 页码:2733-2735
1-壬醇置于aluminum Oxide,Quinolinium Monofluorochromate(Vi)体系中,用 正己烷 用作溶剂,化学反应 6.0H,以61%的收率获得壬醛
参考文献:负载在氧化铝上的氟铬酸喹啉 (Qfc) 作为醇的选择性氧化剂
标题:负载在氧化铝上的氟铬酸喹啉 (Qfc) 作为醇的选择性氧化剂
摘要:摘要 通过新方法制备的氧化铝(中性)负载氟铬酸喹啉(qfc)可选择性地将脂肪族伯醇和仲醇,取代苄醇和脂环醇氧化成相应的羰基化合物,收率非常好.
Doi:10.1080/00397919908086204

海关参考信息

专利信息


专利号:US-2010099894-A1
优先权日:2006-10-09
标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution
发明人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.

专利号:WO-2023102600-A1
优先权日:2021-12-06
标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
权利人:NEWSOUTH INNOVATIONS PTY LTD
摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

专利号:US-6512081-B1
优先权日:1997-07-21
标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

专利号:US-2024076303-A1
优先权日:2022-09-07
标 题:Green Synthesis of Salicylaldehydate-Metal-Organic Frameworks and Applications Thereof
发明人:SHETTY DINESH; MOHAMMED ABDUL KHAYUM
权利人:UNIV KHALIFA SCIENCE & TECHNOLOGY
摘要:Embodiments of the present disclosure generally describe two-dimensional/three-dimensional conjugated salicylaldehydate metal organic framework (2D/3D-c-SA MOF) compositions, method for green synthesis of the two-dimensional/three-dimensional conjugated salicylaldehydate metal organic framework (2D/3D-c-SA MOF) compositions, applications of the said compositions in supercapacitors, lithium-ion batteries, electrocatalytic conversion reactions, photocatalytic reduction of CO 2 and other uses.

专利号:US-11999757-B2
优先权日:2017-11-01
标 题:Synthesis of boronate ester derivatives and uses thereof
发明人:BOYER SERGE HENRI; HECKER SCOTT J; VERZIJL GERARDUS K M; HERMSEN PETRUS J
权利人:MELINTA SUBSIDIARY CORP
摘要:Disclosed herein are methods for the preparation of boronate derivatives in the synthesis of antimicrobial compounds and uses thereof. Disclosed herein includes method of making a compound of Formula (B) by reducing the ketone group of the keto-ester compound of Formula (A), and the reduction can be performed using a Ruthenium based catalyst system or using an alcohol dehydrogenase bioreduction system.

专利号:US-10730904-B2
优先权日:2012-11-14
标 题:Method for liquid-phase synthesis of nucleic acid
发明人:NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO
权利人:TAKEDA PHARMACEUTICALS CO
摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.
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参考文献:10.1007/s10886-010-9746-x
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参考文献:10.1136/thx.2010.156695
摘要:Ibrahim B, Basanta M, Cadden P, Singh D, Douce D, Woodcock A, Fowler SJ. Non-invasive phenotyping using exhaled volatile organic compounds in asthma. Thorax. 2011 Sep;66(9):804–9. doi: 10.1136/thx.2010.156695.
参考文献:10.1016/j.plaphy.2011.06.008
摘要:Lawo NC, Weingart GJF, Schuhmacher R, Forneck A. The volatile metabolome of grapevine roots: First insights into the metabolic response upon phylloxera attack. Plant Physiology and Biochemistry. 2011 Sep;49(9):1059–63. doi: 10.1016/j.plaphy.2011.06.008.
参考文献:10.3389/fncir.2011.00007
摘要:Kuebler LS, Olsson SB, Weniger R, Hansson BS. Neuronal processing of complex mixtures establishes a unique odor representation in the moth antennal lobe. Front Neural Circuits. 2011;5():7.
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