CAS: 13019-22-2; 9-Decen-1-Ol

相似化合物

25601-41-6 14436-32-9 112-43-6

上下游产品

CAS号25601-41-6 9-Dec烯酸甲酯 | CAS号67233-91-4 ethyl 9-decenoate | CAS号112-47-0 1,10-癸二醇 | CAS号67136-13-4 2-dec-9-enoxyoxane | CAS号39770-05-3 9-癸烯醛 | CAS号100189-71-7 dec-9-enoxymeth... | CAS号53463-68-6 10-溴-1-癸醇 | CAS号3669-80-5 11-羟基十一烷酸 | CAS号1647-16-1 1,9-癸二烯 | CAS号14436-32-9 9-癸烯酸 | CAS号3788-56-5 9-羟基壬酸 | CAS号56683-54-6 顺式-11-十六烯-1-醇 | CAS号50816-18-7 乙酸-9-癸烯基酯 | CAS号142580-79-8 ethyl 4-dec-9-e... | CAS号91717-85-0 1,2,10-癸三醇 | CAS号53463-68-6 10-溴-1-癸醇 | CAS号1275582-65-4 9-bromodecanol | CAS号127102-48-1 1,2-Epoxydecan-10-ol | CAS号17643-36-6 9-癸炔-1-醇 | CAS号19754-58-6 10-(Tetrahydro-...

1,10-癸二醇置于potassium Tert-Butylate,四丁基溴化铵,氢溴酸体系中,用 四氢呋喃,水,甲苯 用作溶剂,化学反应 0.58H,反应生成9-十烯-1-醇
参考文献:艾地苯醌新工艺的合成路线发现和引进优化
标题:艾地苯醌新工艺的合成路线发现和引进优化
摘要:公开了导致艾地苯醌的对环境无害,方便,高产率和成本有效的合成.该合成包括用于制备2-溴-3,4,5-三甲氧基-1-甲基苯的溴化工艺,使用热加热或微波加热进行的heck交叉偶联反应的方案,通过钯催化的氢化作用进行烯烃还原以及以过氧化氢为氧化剂的绿色氧化方案,以实现苯醌构架.总合成由六个步骤组成,可提供20%的总产率,相当于76%的步骤产率.
Doi:10.1021/op200051V

专利信息

专利号:US-8569560-B2
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis
发明人：SCHRODI YANN; PEDERSON RICHARD L; KAIDO HIROKI; TUPY MICHAEL J
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35° C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

专利号:US-6215019-B1
优先权日:1998-09-01
标题 :Synthesis of 5-decenyl acetate and other pheromone components
发明人：PEDERSON RICHARD L; GRUBBS ROBERT H
权利人:TILLIECHEM INC
摘要:The present invention relates to syntheses of 5-decenyl acetate, the major component in Peach Twig Borer pheromone, and other pheromone components. The syntheses entails few reaction steps, use commercially available starting materials, and have relatively short process times. A preferred embodiment of the syntheses involves self-metathesizing 1-hexene in the presence of Grubbs' catalyst, [(PCy3)2Cl2]Ru=CHPh. The resulting 5-decene is then reacted with an alcohol or acetate protected hexene under vacuum to yield 5-decenyl acetate. These syntheses produce good yields without the need for expensive or sophisticated equipment.

专利号:US-7901915-B2
优先权日:2005-09-19
标 题:Biocatalytic manufacturing of (meth) acrylic esters
发明人：SYMES KENNETH CHARLES; COLLIER SIMON ANDREW; ARMITAGE YVONNE CHRISTINE; MISTRY RAJESH; BARANYAI ROBERT
权利人:BASF SE
摘要:The invention relates to a biocatalytic method or process for the synthesis of esters of acrylic acid and/or methacrylic acid free of positively chargeable/charged groups, comprising reacting one or more alcohols (alcohol starting materials) which are free of positively chargeable or charged groups with (meth)acrylyl-CoA, preferably in the presence of a catalyst (inorganic, organic or organometallic, or preferably a biocatalyst) capable of effecting the transfer of an alcohol radical from an alcohol starting material as defined above or below to (meth)acrylyl CoA under removal of the CoA moiety transferase activity, such as an enzyme of the transferase or hydrolase class of enzymes. The (meth)acrylyl-CoA is preferably formed by reaction of (meth)acrylic acid or its salts with coenzyme A in the presence of an energy providing substance and a biocatalyst e.g. with S-acetyl coenzyme A synthetase activity or by reaction of acrylate or methacrylate produced metabolically in the presence of a biocatalyst or metabolically.

专利号:US-12344573-B2
优先权日:2018-07-16
标题:Synthesis of straight-chain lepidopteran pheromones through one- or two-carbon homologation of fatty alkenes
发明人：WAMPLER KEITH M; LEE CHOON WOO; ROZZELL DAVID
权利人:PROVIVI INC
摘要:Methods for the preparation of alkenes including insect pheromones are described. The methods include homologation reactions employing reagents such as 1,3-diesters, epoxides, cyanoacetates, and cyanide salts for elongation of starting materials and intermediates by one or two carbon atoms. The alkenes include insect pheromones useful in a number of agricultural applications.

专利号:US-5753726-A
优先权日:1995-12-20
标 题:Synthesis of modified epoxy resins for cathodic electrodeposition with catalyst deactivation and diol modification
发明人：REUTER HARDY; JOUCK WALTER; OTT GUENTHER
权利人:BASF LACKE & FARBEN
摘要:Epoxy resins for preparing water-dispersible binders for cathodic electrodeposition coating materials, the epoxy resin being preparable by reacting a) polyepoxides having at least one glycidyl group per molecule b) and, optionally, up to 60% by weight, based on the overall epoxy resin reaction product, of aliphatic and/or alicyclic hydroxy compounds having preferably two or on average less than two hydroxyl groups per molecule and a molecular weight of less than 9000 g/mol, c) in the presence of a catalyst consisting of neutral metal salts, such as alkali metal salts and alkaline earth metal salts, zinc salts and nickel salts of tetrafluoroboric, tetrachloroboric, hexafluoro- antimonic,hexachloroantimonic,hexafluorophosphoric, perchlorate and periodic acid, and d) adding a deactivating agent which prevents the epoxy groups reacting further or effectively reduces the rate of such reaction as soon as the phenolic hydroxyl groups have already substantially reacted and at least 0.6% by weight of epoxy groups are still present, based on the overall weight of the epoxy resin reaction product.\\!

专利号:US-4935503-A
优先权日:1988-05-05
标题:Azidochlorination and diazidization of glycals
发明人：NAICKER SELVARAJ; NOUJAIM ANTHONY A
权利人:BIOMIRA INC
摘要:The invention describes a one-pot single step procedure for the azidochlorination or diazidization of glycals, including glycal elements of carbohydrates. Compounds such as 3,4,6-tri-O-benzyl-2-azido-2-deoxy-alpha-D-galactopyranosy chloride, and 3,4,6-tri-O-benzyl-2-azido-2-deoxy-alpha-,beta-D-galactopyranose are prepared from tri-O-benzyl galactal as well as 3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-alpha-galactopyranasol chloride and 3,6-di-O-acetyl-4-O-[2,3,4,6-tetra-O-acetyl-beta-D-galactopyranosyl]-2-azido-2-deoxy-alpha-D-glycopyranosyl chloride from their respective O-acetylated glycal derivatives by the addition of azido chloride which is chemically generated in situ. A method using 3,4,6-tri-O-acetyl-2-azido-2-deoxy-alpha-D-galactopyranosyl chloride for the synthesis of antigenic determinants such as the terminal asialo GM 1 (beta-D-Gal (1->3)-beta-D-GalNAc-OR) has been demonstrated. The conversion of the subject synthon into 3,4,6-tri-O-acetyl-2-azido-2-deoxy-alpha-D-galactopyranosyl bromide and 1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-alpha-D-galactopyranose is also described. A further method for the synthetic generation of the Tn antigen (alpha-D-GalNAc-O-L-serine) is also described.