CAS: 121554-18-5; (4'-Pentyl-[1,1'-Biphenyl]-4-yl)Boronic Acid

相似化合物

153035-56-4 153035-62-2 393870-04-7

上下游产品

4-(4-pentylphenyl)bromobenzene Triisopropyl borate tri-n-propyl borate 4-bromo-1,1'-biphenyl 54H50C54H50 Methyl 2-(4-diethylaminophenyl)-2-phenyl-6-(4'-pentylbiphenyl-4-yl)-2H-naphtho[1,2-b]pyran-5-carboxylate Methyl 6-(4'-pentylbiphenyl-4-yl)-2-phenyl-2-(4-pyrrolidinophenyl)-2H-naphtho[1,2-b]pyran-5-carboxylate 1,4-bis(4''-(pentyl)-1,1',1''-terphenyl-4-yl)-2,3,5,6-tetramethoxybenzene

对溴戊基联苯置于盐酸,正丁基锂体系中,用 乙醚,水 用作溶剂,化学反应 2.0H,反应生成4-戊基联苯硼酸
参考文献:Synthesis Of Cyclic Compounds Consisting Of Face-To-Face P-Oligophenyls
标题:Synthesis Of Cyclic Compounds Consisting Of Face-To-Face P-Oligophenyls
摘要:Facile Synthesis Of Xanthene-Based Pi-Stacked Compounds Consisting Of Face-To-Face P-Oligophenyls Has Been Described. Just By Mixing Xanthene-4,5-Diboronic Acid And P-Oligophenyls Containing A Benzenetetraol Unit Yielded Cyclic Compounds Selectively Due To The Reversibility Of The Boronate Esterification. In The Ground State,Weak Pi-Pi Interactions Between Two P-Oligophenyl Moieties Were Observed,Whereas Their Pi-Pi Interactions Were Clearly Shown In The Excited State. (C) 2014 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tetlet.2014.01.093

专利信息

专利号:US-11225655-B2
优先权日:2010-04-16
标题:Bi-functional complexes and methods for making and using such complexes
发明人：GOULIAEV ALEX HAAHR; FRANCH THOMAS; GODSKESEN MICHAEL ANDERS; JENSEN KIM BIRKEBAEK
权利人:GOULIAEV ALEX HAAHR; FRANCH THOMAS; GODSKESEN MICHAEL ANDERS; JENSEN KIM BIRKEBAEK; NUEVOLUTION AS
摘要:The present invention is directed to a method for the synthesis of a bi-functional complex comprising a molecule part and an identifier oligonucleotide part identifying the molecule part. A part of the synthesis method according to the present invention is preferably conducted in one or more organic solvents when a nascent bi-functional complex comprising an optionally protected tag or oligonucleotide identifier is linked to a solid support, and another part of the synthesis method is preferably conducted under conditions suitable for enzymatic addition of an oligonucleotide tag to a nascent bi-functional complex in solution.