Triphenylsilyl-Lithium置于potassium Sodium体系中,化学反应生成乙氧基三苯基硅烷 参考文献:Isomerization Of Some α-Hydroxysilanes To Silyl Ethers. Ii1 标题:Isomerization Of Some α-Hydroxysilanes To Silyl Ethers. Ii1 摘要: Doi:10.1021/ja01513A056
专利号:US-8987493-B2 优先权日:2010-05-20 标题 :Process for synthesis of silane dipeptide analogs 发明人:SIEBURTH SCOTT MCNEILL; BO YINGJIAN 权利人:SIEBURTH SCOTT MCNEILL; BO YINGJIAN; Temple University—Of the Commonwealth System of Higher Education 摘要:The invention provides a method of preparing silane dipeptide analogs, comprising the steps of treating a solution of a substituted 1,2-oxasilolane with lithium metal to form a solution of the dilithium salt of a substituted 3-hydroxypropylsilanol, and reacting the solution of the dilithium salt of the substituted 3-hydroxypropylsilanol with a substituted enamine.
专利号:WO-2017083719-A1 优先权日:2015-11-13 标 题:Transition metal free methods of synthesis of biaryl compounds 发明人:GAO HONGYIN; KURTI LASZLO 权利人:UNIV RICE WILLIAM M 摘要:The present disclosure provides methods of preparing biaryl compounds which do not require transition metal catalysts. In yet another aspect, the present disclosure provides pharmaceutical compositions comprising compounds as described herein and pharmaceutically acceptable carriers.
专利号:US-2013096335-A1 优先权日:2010-05-20 标题 :Process for synthesis of silane dipeptide analogs
专利号:WO-2011146842-A1 优先权日:2010-05-20 标 题:Process for synthesis of silane dipeptide analogs
专利号:CN-109438633-A 优先权日:2018-09-11 标题:A kind of organosilicon toughening agent with anti-drip effect and synthesis method thereof
专利号:CN-105085923-B 优先权日:2015-09-06 标 题:A kind of Vinylphenyl silicon resin and preparation method thereof of solventless method synthesis
参考标题:Highly Selective Hydroxylation And Alkoxylation Of Silanes: One-Pot Silane Oxidation And Reduction Of Aldehydes/ketones 作者:Nianhua Luo,Jianhua Liao,Lu Ouyang,Huiling Wen,Yuhong Zhong,Jitian Liu,Weiping Tang,Renshi Luo |发布日期:2020.1.13 摘要:An Efficient Chemoselective Iridium-Catalyzed Method For The Hydroxylation And Alkoxylation Of Organosilanes To Generate Hydrogen Gas And Silanols Or Silyl Ethers Was Developed. A Variety Of Sterically Hindered Silanes With Alkyl, Aryl, And Ether Groups Were Tolerated. Furthermore, This Atom-Economical Catalytic Protocol Can Be Used For The Synthesis Of Silanediols And Silanetriols. A One-Pot Silane
合成参考文献
参考文献:10.1055/s-0036-1588816 摘要:Kumar P, Guo S, Yuan Y. Metal-Free Ammonium Iodide Catalyzed Oxidative Dehydrocoupling of Silanes with Alcohols. Synlett. 2017 May 17;28(13):1620–3. doi: 10.1055/s-0036-1588816.