CAS: 1576-87-0; Trans-2-Pentenal

该化合物是一个不饱和的藻类,其特点是五碳链和第二和第三碳原子之间的双链,以及甲酰胺功能组,该化合物一般是一种无色的黄色液体,其独特,发光的气味通常被称为青色或果色,在有机溶剂中可溶解,由于水分碳链,水溶性有限.(E)配置表明,双联体两侧最高优先的次级成员在对面,影响其反应和互动.(E)-2-Pentennal被用于各种应用,包括用作调味剂和其他有机化合物合成,还有兴趣研究与甲酰胺和烷有关的化学反应,特别是在有机合成和工业化学方面.在处理该化合物时,应采取安全防范措施,因为它可能刺激皮肤和眼睛.

结构式图片

相似化合物

13991-37-2 1576-95-0 818-59-7

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

1,4-Pentadiene (E)-2-penten-1-ol 1-ethoxy-1,3-pentadiene 1,1,3-triethoxypentane(2E,4E)-hepta-2,4-dienoic acid trans-2-pentenoic acid 2-pentenal 2,4-dinitrophenyl hydrazone Acetic acid 8-(5,5,6,6-tetracyano-4-ethyl-cyclohex-2-enyl)-°Ctyl ester

合成工艺路线路线简述

    1,4-戊二烯置于氧气,Palladium Dichloride体系中,化学反应生成反式-2-戊烯醛
    参考文献:Smidt Et Al.,Angewandte Chemie,1959,Vol. 71,P. 176,180,182
    标题:Smidt Et Al.,Angewandte Chemie,1959,Vol. 71,P. 176,180,182

    海关参考信息

    专利信息


    专利号:US-4190579-A
    优先权日:1977-12-29
    标题:Synthesis of beta-lactams from azetidine carboxylic acid esters
    发明人:LIPSHUTZ BRUCE H; WASSERMAN HARRY H; WU JAMES S
    权利人:RESEARCH CORP
    摘要:Azetidine carboxylic acid esters are converted into enol silyl ethers which, as enamino ketene acetals, undergo ready oxidative cleavage of the ethylenically unsaturated double bond, e.g. by dye-sensitized photo-oxygenation, to form beta-lactams. The beta-lactams and substitution products thereof are useful intermediates in the synthesis of biologically active lactams.

    专利号:US-4288613-A
    优先权日:1979-12-03
    标 题:Cyclopentanone synthesis
    发明人:LAROCK RICHARD C
    权利人:UNIV IOWA STATE RES FOUND INC
    摘要:A method of synthesis of cyclopentanones comprising cyclizing a 4-pentenal, preferably under an ethylene atmosphere, in the presence of a catalytically effective amount of a cyclizing, rhodium(I) para-substituted triarylphosphine catalyst.

    专利号:US-3732214-A
    优先权日:1970-07-16
    标题 :Method for the synthesis of zeaxanthins,xanthophylls,and 3beta-carotene
    发明人:SURMATIS J; WALSER A
    权利人:HOFFMANN LA ROCHE
    摘要:METHOD BY WHICH ZEAXANTHINS, XANTHOPYLLS AND 3-OXO-BCAROTENE CAN BE SYNTHESIZED FROM THE CONDENSATION PRODUCT OF MESITYL OXIDE AND ACETO-ACETIC ESTER AS WELL AS NEW AND NOVEL INTERMEDIATES PRODUCED IN THE SYNTHESIS. ZEAXANTHIN AND XANTHOPHYLL ARE KNOWN COLORING AGENTS FOR FOODSTUFFS, INCLUDING BEVERAGES, PHARMACEUTICAL AND COSMETIC PREPARATIONS. FURTHERMORE, THROUGH THE USE OF THE CONDENSATION PRODUCT OF MESITYL OXIDE AND ACETOACETIC ACID, NEW COMPOUNDS FOR COLORING FOODSTUFFS, INCLUDING BEVERAGES, PHARMACEUTICAL AND COSMETIC PREPARATIONS ARE PRODUCED.

    专利号:US-2005004225-A1
    优先权日:2003-04-16
    标题:Oxidoreductase inhibitors and methods of screening and using thereof
    发明人:BALENDIRAN GANESARATNAM K
    摘要:The present invention relates to 1) the design and synthesis of analogs to glutathione conjugates which bind to or interact with aldose reductase (AR) through unique conformations that are distinctly different from the substrates and inhibitors of AR which are members of sugar metabolism; 2) the screening of the analogs to identify those that interact with or inhibit or enhance the activity of AR; and 3) the use of AR ligands, AR inhibitors (AR antagonsits) or AR enhancer (AR agonists) in the detection of AR activity, the modulation of AR activity, and the treatment of conditions in a subject in need of modulating AR activity. Such conditions include but not limited to cardiovascular disease, diabetes, artheriosclerosis, cancer, neoplasm, obesity, cataract, retinopathy, keratopathy, nephropathy, neurosis, thrombosis, faulty union of corneal injury and neuropathy. Examples of the treatment include the use of fibrates as AR inhibitors to treat these conditions.

    专利号:US-2016068459-A1
    优先权日:2013-04-19
    标题 :Immobilized catalytically active composition for hydroformylation of olefin-containing mixtures
    发明人:DYBALLA KATRIN MARIE; FRANKE ROBERT; HAHN HANNA; BECKER MARC; SCHOENWEIZ ANDREAS; DEBUSCHEWITZ JONAS; WALTER SIMON; WOELFEL RENE; HAUMANN MARCO; WASSERSCHEID PETER; KAFTAN ANDRE; LAURIN MATHIAS; LIBUDA JOERG
    权利人:EVONIK DEGUSSA GMBH
    摘要:A composition and the use of said composition as catalytically active composition in processes for synthesis of chemical compounds, especially the hydroformylation of olefinically unsaturated hydrocarbon mixtures.

    专利号:US-5481040-A
    优先权日:1994-03-31
    标 题:Process for the preparation of phosphonium salts
    发明人:FUKUMOTO TAKEHIKO; HIROKAWA KAZUSHI; OKADA KURAO
    权利人:SHINETSU CHEMICAL CO
    摘要:A process for the preparation of phosphonium salts by the use of chlorides, which is useful in the course of synthesis of olefin compounds by the Wittig reaction, and which comprises reacting a phosphine compound of the general formula R13P wherein R1 is a phenyl group or a straight-chain alkyl group having 2 to 8 carbon atoms, with a primary or secondary chloride of the general formula wherein R2 and R3 are hydrocarbon radicals, in a solvent selected from the group consisting of N,N-dimethylformamide, N,N-dimethylacetamide and N,N-1,3-dimethyl-2-imidazolidinone, and in the presence of an alkali metal salt of the general formula MBr or MI.
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    主要参考文献

    参考标题:Synthesis OfO-(Dimethylamino)Aryl Ketones And Acridones By The Reaction Of 1,1-Dialkylhydrazones And Arynes
    作者:Anton V. Dubrovskiy,Richard C. Larock |发布日期:2011.8.5
    摘要:A Novel, Efficient Route To Biologically And Pharmaceutically Important O-(Dimethylamino)Aryl Ketones And Acridones Has Been Developed Starting From Readily Available 1,1-Dimethylhydrazones Of Aldehydes And O-(Trimethylsilyl)Aryl Triflates. The Reaction Proceeds Under Mild Conditions, Tolerates A Wide Range Of Functional Groups, And Provides The Final Products In Good To Excellent Yields.

    合成参考文献


    摘要:Shimada, K., Science of Synthesis Knowledge Updates, (2010) 1, 435.
    摘要:Kawęcki, R., Science of Synthesis Knowledge Updates, (2018) 4, 327.
    摘要:Hunter, L., Science of Synthesis Knowledge Updates, (2017) 2, 433.
    摘要:Nguyen, B. N.; Hii, K. K.; Szymański, W.; Janssen, D. B., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 638.
    摘要:MacMillan, D. W. C.; Watson, A. J. B., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 385.
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