CAS: 54300-32-2; Bis(4-Fluorophenyl)(Phenyl)Phosphine Oxide

上下游产品

bis(4-fluorophenyl)(phenyl)phosphine Bis-(4-fluorphenyl)-phenyl-phosphansulfid sulfuric acid Diphenyliodonium triflate (4-fluorphenyl)(4-nitrophenyl)(phenyl)phosphinoxid Bis(4-nitrophenyl)phenylphosphine oxide di(4-nitrophenyl)(phenyl)phosphin

Bis-(4-Fluorphenyl)-Phenyl-Phosphansulfid置于甲烷磺酸体系中,用96%的收率获得产物二(4-氟苯基)苯基氧化膦
参考文献:Methods For Making Tertiary Phosphine Oxides
标题:Methods For Making Tertiary Phosphine Oxides
摘要:将相应的三级膦磺化物与硫酸和/或有机磺酸在70摄氏度至200摄氏度的温度下反应,制备三级膦氧化物的方法.

专利信息

专利号:US-8981036-B2
优先权日:2012-08-02
标 题:Synthesis of and curing additives for phthalonitriles
发明人：KELLER TEDDY M; LASKOSKI MATTHEW
权利人:KELLER TEDDY M; LASKOSKI MATTHEW; US NAVY
摘要:A composition having a mixture of the below compounds having a mole ratio of at least 1:20. Ar 1 and Ar 2 are independently selected aromatic groups. A composition comprising phthalonitrile compounds that comprise at least 5 mol % of the first compound below. n nA method of: providing a solution of a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; a dihydroxyaromatic compound or anion thereof; an organic transition metal complex or a transition metal salt; an alkaline hydroxide base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form a dimetallic salt of an aromatic ether oligomer. The molar ratio of the dihydroxyaromatic compound to the dichloroaromatic compound is greater than 2:1. Water formed during the heating is concurrently distilled from the solution.

专利号:WO-2015183518-A1
优先权日:2013-03-15
标 题:Synthesis of and curing additives for phthalonitriles
发明人：KELLER TEDDY M; LASKOSKI MATTHEW; SAAB ANDREW
权利人:US GOVERNMENT; KELLER TEDDY M; LASKOSKI MATTHEW; SAAB ANDREW
摘要:A method of: providing a solution of a dichloroaromatic compound having an electron- withdrawing group bound to each aromatic ring containing one of the chloride groups; a dihydroxyaromatic compound or anion thereof; an organic transition metal complex or a transition metal salt; a base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form a dimetallic salt of an aromatic ether oligomer. The molar ratio of the dihydroxyaromatic compound to the dichloroaromatic compound is greater than 2: 1. Water formed during the heating is concurrently distilled from the solution. A composition having a mixture of the below compounds having a mole ratio of at least 1:20. Ar 1 and Ar 2 are independently selected aromatic groups. A composition comprising phthalonitrile compounds that comprise at least 5 mol% of the first compound below.

专利号:US-8735532-B2
优先权日:2012-08-02
标题 :Synthesis of and curing additives for phthalonitriles
发明人：KELLER TEDDY M; LASKOSKI MATTHEW; SAAB ANDREW
权利人:KELLER TEDDY M; LASKOSKI MATTHEW; SAAB ANDREW; US NAVY
摘要:A method of: providing a solution of a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; an excess of a dihydroxyaromatic compound; an organic transition metal complex or a transition metal salt; a base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form an aromatic ether oligomer that is a dihydroxy-terminated compound or a dimetallic salt thereof. Water formed during the heating is concurrently distilled from the solution. A method of curing a phthalonitrile monomer in the presence of an acid and a curing agent to form a phthalonitrile thermoset.

专利号:US-8859712-B2
优先权日:2012-08-02
标 题 :Synthesis of and curing additives for phthalonitriles
发明人：KELLER TEDDY M; LASKOSKI MATTHEW; SAAB ANDREW
权利人:KELLER TEDDY M; LASKOSKI MATTHEW; SAAB ANDREW; US GOVERNMENT
摘要:A method of: providing a solution of a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; a dihydroxyaromatic compound; an organic transition metal complex or a transition metal salt; a base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form a dimetallic salt of an aromatic ether oligomer. The molar ratio of the dihydroxyaromatic compound to the dichloroaromatic compound is greater than 2:1. Water formed during the heating is concurrently distilled from the solution.

专利号:US-6040416-A
优先权日:1999-02-18
标 题:Melt polymer synthesis of poly ether phosphine oxides
发明人：SEKHARIPURAM VENKATESHWARAN N; MECHAM BEVERLY SUE; BHATNAGAR ATUL; MCGRATH JAMES E
权利人:JOHNSON & JOHNSON VISION PROD; VIRGINIA TECH INTELL PROP
摘要:A melt polymerization method for producing poly(arylene ethers phosphine oxide)s suited to optical applications comprising reacting a trimethyl silyl derivative of bisphenol and an activated aromatic dihalide, wherein either reactant is a phosphine oxide, is provided.

专利号:US-2016223559-A1
优先权日:2015-02-02
标题:Tetrazine-containing compounds and synthetic methods thereof
发明人：DEVARAJ NEAL K; WU HAOXING; YANG JUN
权利人:UNIV CALIFORNIA
摘要:Described herein are tetrazine derivatives and efficient synthetic methods of synthesis thereof using elimination-Heck cascade reaction. Provided herein is the synthesis of conjugated tetrazines from the tetrazine derivatives. Also provided herein are methods of use of the conjugated tetrazines as fluorogenic probes for live-cell imaging.