CAS: 64249-01-0; Anilofos

该化合物是一种有机磷化合物,主要在农业做法中用作除草剂,其特点是它能够抑制各种杂草的生长,特别是在稻田中.Anilofo通过干扰某些基本植物荷尔蒙的合成,导致目标杂草死亡,发挥功能.该化合物通常以液体形式使用,以其系统性行动而闻名,允许植物吸收该化合物,并将其移到各种组织中.从化学特性来看,Anilofos在正常环境条件下相对稳定,但可以在有强酸或碱的情况下降解.重要的是,必须谨慎地处理Anilofofos,因为它对非目标生物的潜在毒性,包括水生生命和有益的昆虫.在应用过程中应采取安全措施,以尽量减少接触.

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CAS号1066-97-3 O,O'-二甲基二硫代磷酸铵 | CAS号84012-61-3 2-chloro-N-(4-c...

合成工艺路线路线简述

    2-氯-N-(4-氯苯基)-N-(1-甲基乙基)乙酰胺,二甲基二硫代磷酸酯置于四丁基硫酸氢铵,Sodium Carbonate体系中,用 甲苯 作为反应溶剂,45.0~95.0 °C,1.33 Kpa 条件下,以96.1 %的收率获得产物o,O-二甲基-S-[n-(4-氯苯基)-N-异丙基甲酰甲基]二硫代磷酸酯
    参考文献:Cn116199711
    标题:Cn116199711

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    专利信息


    专利号:US-6350878-B1
    优先权日:1998-05-18
    标 题 :Intermediates for the synthesis of epothilones and methods for their preparation
    发明人:ALTMANN KARL-HEINZ; BAUER ARMIN; SCHINZER DIETER
    权利人:NOVARTIS AG
    摘要:The invention relates to a method of synthesis for a compound of formula (I),wherein R is a heterocyclyl moiety and X1, X2, X3 and X4 are, independently of each other, protecting groups, which is appropriate for the synthesis of epothilone B and desoxyepothione B.

    专利号:WO-2015036637-A1
    优先权日:2013-09-13
    标题:Method for the synthesis of kojibiose and the application thereof in the production of food and pharmaceutical compositions
    发明人:DIEZ MUNICIO MARINA; MORENO ANDUJAR FRANCISCO JAVIER; HERRERO CALLEJA MIGUEL; MONTILLA CORREDERA ANTONIA
    权利人:CONSEJO SUPERIOR INVESTIGACION
    摘要:The invention relates to a method for the synthesis of kojibiose, characterised by its simplicity and high yield, using a starting reaction mixture containing, as the main compound thereof, the trisaccharide 2-α-D-glucopyranosyl-lactose, O-β-D-galactopyranosyl-(1→4)-O-[α-D-glucopyranosyl- (1→2)]-β-D-glucopyranose, and leucrose, lactose, fructose, glucose and saccharose, said method comprising steps of fermentation, hydrolysis and purification, allowing the production of a disaccharide with high added value, such as kojibiose, in a cost-effective manner. The invention also relates to the kojibiose produced by means of the method according to the invention, and to the use of same in the production of prebiotic food compositions in order to prevent pathologies relating to the gastrointestinal system, and pharmaceutical compositions for treating viral-type diseases or for delaying the digestion of carbohydrates.

    专利号:WO-03064360-A1
    优先权日:2002-02-01
    标 题:Synthetic tetraethers and synthesis strategies therefor
    发明人:KUEHL CHRISTINE; LITTGER RALF
    权利人:BERNINA BIOSYSTEMS GMBH; KUEHL CHRISTINE; LITTGER RALF
    摘要:The invention relates to novel synthetic tetraethers and a novel method for producing said substances. The inventive tetraethers are characterised in that they can be modified in a simple and targeted manner according to said synthesis method, which enabling the synthesis of the desired model substances. The synthesis concept guarantees high variability with simple individual production.

    专利号:US-9403841-B2
    优先权日:2012-01-25
    标题:Phragamalin limonoids for the treatment of sexual dysfunction
    发明人:WIKBERG JARL; JIRGENSONS AIGARS; LIEPINSH EDVARDS
    权利人:DICOTYLEDON AB
    摘要:The present invention relates to novel chemical compounds, to methods for synthesis of such compounds, and to the use of these novel compounds in the synthesis of other chemical compounds that, inter alia, may be used in the treatment of sexual dysfunction, and for eliciting enhancing effects on sexual behavior. The invention also relates to remarkable biological properties of the novel compounds in their capacity of inducing aggressive behavior.

    专利号:US-2004128713-A1
    优先权日:1997-04-08
    标题 :Soybean plant producing seeds with reduced levels of raffinose saccharides and phytic acid
    发明人:HITZ WILLIAM D; SEBASTIAN SCOTT ANTHONY; GRACE DORMAN JOHN; STREIT LEON GEORGE
    摘要:A soybean enzyme, myo-inositol 1-phosphate synthase, whose manipulation results in the alteration of raffinose saccharide, sucrose, phytic acid and inorganic phosphate content of soybean seeds, thus leading to valuable and useful soybean products, has been identifed. Soybean lines with decreased capacity for the synthesis of myo-inositol 1-phosphate in the tissue of developing seeds in comparison to seeds of other soybean lines, have been developed. As taught herein, reduction of myo-inositol 1-phosphate synthase enzymatic activity by any of several means will result in soybean seeds displaying this desirable phenotype.

    专利号:US-11465129-B2
    优先权日:2017-06-06
    标题:Microwave assisted and low-temperature fabrication of nanowire arrays on scalable 2D and 3D substrates
    发明人:GAO PU-XIAN; LU XINGXU; HOANG SON
    权利人:UNIV CONNECTICUT
    摘要:A method of making a titanium dioxide nanowire array includes contacting a substrate with a solvent comprising a titanium (III) precursor, an acid, and an oxidant while microwave heating the solvent, thereby forming a hydrogen titanate H2Ti2O5.H2O nanowire array. The hydrogen titanate nanowire array is annealed to form a titanium dioxide nanowire array. The substrate is seeded with titanium dioxide before starting the hydrothermal synthesis of the hydrogen titanate nanowire array. The titanium dioxide nanowire array is loaded with a platinum group metal to form an exhaust gas catalyst. The titanium dioxide nanowire array can be used to catalyze oxidation of combustion exhaust.
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    主要参考文献


    1: Singh DP, Khattar JI, Kaur M, Kaur G, Gupta M, Singh Y. Anilofos tolerance and its mineralization by the cyanobacterium Synechocystis sp. strain PUPCCC 64. PLoS One. 2013;8(1):e53445. doi: 10.1371/journal.pone.0053445. Epub 2013 Jan 31.
    2: Bagri P, Kumar V. Assessment of anilofos-induced mutagenicity in bone marrow and germ cells of Swiss albino mice. Toxicol Ind Health. 2020 Feb;36(2):110-118. doi: 10.1177/0748233720913757. 67(5):783-91. doi: 10.1007/s10616-014-9716-1. Epub 2014 May 17.
    4: Akyil D, Konuk M, Eren Y, Liman R, Sağlam E. Mutagenic and genotoxic effects of Anilofos with micronucleus, chromosome aberrations, sister chromatid exchanges and Ames test. Cytotechnology. 2017 Dec;69(6):865-874. doi: 10.1007/s10616-017-0099-y. Epub 2017 Jun 12.

    合成参考文献


    参考文献:10.1016/s0300-483x(01)00411-5
    摘要:Hazarika A, Sarkar SN. Effect of isoproturon pretreatment on the biochemical toxicodynamics of anilofos in male rats. Toxicology. 2001 Aug 28;165(2-3):87–95. doi: 10.1016/s0300-483x(01)00411-5.
    摘要:Tantawy AA. Molluscicidal effect of fenitrothion and anilofos on Lymnaea natalensis and Biomphalaria alexandrina snails and on the free larval stages of Schistosoma mansoni. J Egypt Soc Parasitol. 2006 Aug;36(2):629–42.
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