CAS: 2437-95-8; α-Pinene

该化合物是一种双环单体,是各种锥形树,特别是松树的主要油质的重要组成部分,其特点是其独特的松状芳香,在香味和口味行业中常用.甲苯的分子式为C10H16,其分子重量约为136.24克/摩尔.该化合物在室内温度下是一种无色至黄色的黄色液体,沸点约为155156C.甲苯以其手性特征而著称,存在于两种对应形式的(R)甲-丙烯和(S)甲-丙烯,其(R)形式在性质上更为流行.该物质在有机溶剂中溶解,但水溶性有限.甲苯展示了各种生物活动,包括抗微生物和抗炎特性,还研究其在其他化学化合物合成中的潜力.此外,它还在大气中形成有机气溶质和大气中分解的二次气溶质中发挥作用.

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ECHA物质C&L通报REACH预注册

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    专利信息


    专利号:WO-2024012791-A1
    优先权日:2022-07-11
    标题 :Electrochemical synthesis of pyrazolines and pyrazoles
    发明人:BÄR ROBIN MAXIMILIAN; FORD MARK JAMES; KALDAS SHERIF JAMES; WALDVOGEL SIEGFRIED; HOFMANN SILJA; LINDEN MARTIN
    权利人:BAYER AG
    摘要:The present invention relates to an electrochemical process for the synthesis of pyrazolines and pyrazoles of formula (I). The process can be especially used for the synthesis of the herbicide safener mefenpyr-diethyl.

    专利号:US-11046978-B2
    优先权日:2016-03-16
    标 题:Synthesis of isoprenoids and derivatives
    发明人:GONZALEZ RAMON; CLOMBURG JAMES M; CHEONG SEOKJUNG
    权利人:UNIV RICE WILLIAM M
    摘要:This disclosure generally relates to the use of enzyme combinations or recombinant microbes comprising same to make isoprenoid precursors, isoprenoids and derivatives thereof including prenylated aromatic compounds. Novel metabolic pathways exploiting Claisen, aldol, and acyioin condensations are used instead of the natural mevalonate (MVA) pathway or 1-deoxy-d-xylulose 5-phosphate (DXP) pathways for generating isoprenoid precursors such as isopentenyl pyrophosphate (IPP), dimethylallyl pyrophosphate (DMAPP), and geranyl pyrophosphate (GPP). These pathways have the potential for better carbon and or energy efficiency than native pathways. Both decarboxylative and non-carboxylative condensations are utilized, enabling product synthesis from a number of different starting compounds. These condensation reactions serve as a platform for the synthesis of isoprenoid precursors when utilized in combination with a variety of metabolic pathways and enzymes for carbon rearrangement and the addition/removal of functional groups. Isoprenoid alcohols are key intermediary products for the production of isoprenoid precursors in these novel synthetic metabolic pathways.

    专利号:US-4140708-A
    优先权日:1975-10-16
    标 题 :Asymmetric synthesis of optically active prostaglandins
    发明人:CHADHA NARESH K; PARTRIDGE JR JOHN J; USKOKOVIC MILAN R
    权利人:HOFFMANN LA ROCHE
    摘要:An asymmetric synthesis of optically active prostaglandin F 2 α from cyclopentadiene including intermediates in this synthesis.

    专利号:US-3933892-A
    优先权日:1973-02-12
    标题 :Asymmetric synthesis of optically active prostaglandins
    发明人:CHADHA NARESH KUMAR; PARTRIDGE JR JOHN JOSEPH; USKOKOVIC MILAN RADOJE
    权利人:HOFFMANN LA ROCHE
    摘要:An asymmetric synthesis of optically active prostaglandin F 2 .sub.α from cyclopentadiene including intermediates in this synthesis.

    专利号:US-7429658-B2
    优先权日:2003-09-11
    标题 :Synthesis of protected pyrrolobenzodiazepines
    发明人:HOWARD PHILIP; MASTERSON LUKE
    权利人:SPIROGEN LTD
    摘要:A method of synthesis of a N-10 protected PBD compound of formula (I): n nvia an intermediate of formula (II) or formula (V):

    专利号:US-4727146-A
    优先权日:1980-07-03
    标题 :Synthesis of chiral 1-benzyl-1,2,3,4-tetra-hydroisoquinolines by asymmetric reduction
    发明人:RICE KENNER C
    权利人:US HEALTH
    摘要:In a short total synthesis of morphinan compounds, derivatives of 1-benzyl-1,2,3,4-tetrahydroisoquinoline are produced. Certain of these compounds, although highly aromatic and functionalized, can be optically resolved. The optically active enantiomers can serve as important intermediates for both natural and unnatural opioids. As a special function of this invention, certain of the derivatives, namely 4'-6' and 7'-9', may be hydrogenated to 1'-3' derivative by asymmetric reduction either of the catalytic or chemical type.
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    合成参考文献


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    摘要:Food and Cosmetics Toxicology., 16(853), 1978
    参考文献:10.1016/j.phytochem.2006.04.025
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    参考文献:10.1023/b:joec.0000030269.07833.8f
    摘要:Hwang JY, Kim JH, Yun KW. The Effect of Selected Monoterpenoids on the Cellular Slime Mold, Dictyostelium discoideum NC4. Journal of Chemical Ecology. 2004 Jun;30(6):1153–63. doi: 10.1023/b:joec.0000030269.07833.8f.
    参考文献:10.1142/s0192415x0400193x
    摘要:Lai EY, Chyau CC, Mau JL, Chen CC, Lai YJ, Shih CF, Lin LL. Antimicrobial activity and cytotoxicity of the essential oil of Curcuma zedoaria. Am J Chin Med. 2004;32(2):281–90. doi: 10.1142/s0192415x0400193x.
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