物理性质
- 熔点<25 °C
- 沸点278.7 °C at 760 mmHg
- 闪点118.4 °C
- 密度0.914g/cm3
- PSA:17.07
- LogP:3.7601
- 折射率1.5
- 蒸汽压0.4Pa at 20°C
- 敏感性物化性质有α-、β-、γ-三种异构体,以α-体为主。
- 外观形态液体
- 储存条件贮运及保管马口铁装。贮于阴凉处。
- 产品应用α-鸢尾酮(79-69-6)的用途:GB 2760―1996规定为允许使用的食品用香料.因价格昂贵,应用较少.可代替鸢尾凝脂或其浸膏用于鸢尾,紫罗兰,桂花及高档香精配方,能提调香气,取得甜香.由于味觉为非常有力的甜,适当稀释有浆果样香味,故可用于浆果,果香等食用香精.主要用以配制树莓,草莓等型香精.
- 性质描述α-鸢尾酮(79-69-6)的性状:1.其外观呈无色至淡黄色液体状.2.沸点110~112°C(427Pa).溶于乙醇.3.天然品存在于鸢尾根,草莓等中.4.有紫罗兰,鸢尾,桂花的甜香,是鸢尾油的主要香气.毒性:1.GRAS(FEMA).2.LD50>5g/kg(大鼠,经口).
欧盟法规
REACH注册ECHA物质C&L通报REACH预注册上下游产品
pseudoirone 3,6,7-trimethyl-°Ct-6-en-1-yn-3-ol 5,6-dimethyl-5-hepten-2-one (E)-3,6,7-trimethyl°Cta-2,6-dien-1-oloptically inactive 2,2'-dimethyl-ε,ε-carotene 合成工艺路线路线简述
- 5392-40-5 = 79-69-6 + 79-70-9 + 79-68-5
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Acetone; 4 H,45 °C1.2 Solvents: Acetic Acid; Ph 6 - 72.1 Reagents: Copper,Zinc Solvents: Diethyl Ether,Dichloromethane; 6 H,Rt -> 35 °C3.1 Reagents: Citral Solvents: Dichloromethane; 45 Min,< -70 °C3.2 Reagents: Sodium Bicarbonate
标题:Synthesis Of Irone By Cyclization Reaction
作者:Hu,Tie; Et Al
参考文献:Yingyong Huaxue 日期:2014 卷标:31(11) 页码:1297-1301]
29171-20-8 = 79-69-6 + 599-45-1 + 79-70-9
反应条件:1.1 Reagents: Benzyltriethylammonium Chloride,Sodium Hydroxide2.1 Reagents: Triethylamine,Sodium Solvents: Diethyl Ether3.1 Reagents: P-Toluenesulfonic Acid,Hydroquinone,Propane,2-Methoxy-,Isooctane4.1 Reagents: Sodium Hydroxide Solvents: Methanol5.1 Reagents: Boron Trifluoride Solvents: Toluene
标题:Process For The Preparation Of Irones
参考文献:European Patent Organization]
6754-31-0 = 79-69-6 + 79-70-9 [标题:Reaction Conditions
标题:Synthesis Of Irone
作者:Liu,Xiaogeng; Et Al
参考文献:Xiangliao Xiangjing Huazhuangpin 日期:2001 卷标:(2) 页码:5-7]
= 79-69-6 + 599-45-1 + 79-70-9
反应条件:1.1 Reagents: Boron Trifluoride Solvents: Toluene
标题:Process For The Preparation Of Irones
参考文献:European Patent Organization]
= 79-69-6 + 79-70-9 + 79-68-5
反应条件:1.1 Reagents: Citral Solvents: Dichloromethane; 45 Min,< -70 °C1.2 Reagents: Sodium Bicarbonate
标题:Synthesis Of Irone By Cyclization Reaction
作者:Hu,Tie; Et Al
参考文献:Yingyong Huaxue 日期:2014 卷标:31(11) 页码:1297-1301]
= 79-69-6 + 599-45-1 + 79-70-9
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol2.1 Reagents: Boron Trifluoride Solvents: Toluene
标题:Process For The Preparation Of Irones
参考文献:European Patent Organization]
3548-78-5 = 79-69-6 + 79-70-9 + 79-68-5
反应条件:1.1 Reagents: Copper,Zinc Solvents: Diethyl Ether,Dichloromethane; 6 H,Rt -> 35 °C2.1 Reagents: Citral Solvents: Dichloromethane; 45 Min,< -70 °C2.2 Reagents: Sodium Bicarbonate
标题:Synthesis Of Irone By Cyclization Reaction
作者:Hu,Tie; Et Al
参考文献:Yingyong Huaxue 日期:2014 卷标:31(11) 页码:1297-1301]
= 79-69-6 + 599-45-1 + 79-70-9
反应条件:1.1 Reagents: P-Toluenesulfonic Acid,Hydroquinone,Propane,2-Methoxy-,Isooctane2.1 Reagents: Sodium Hydroxide Solvents: Methanol3.1 Reagents: Boron Trifluoride Solvents: Toluene
标题:Process For The Preparation Of Irones
参考文献:European Patent Organization]
= 79-69-6 + 599-45-1 + 79-70-9
反应条件:1.1 Reagents: Triethylamine,Sodium Solvents: Diethyl Ether2.1 Reagents: P-Toluenesulfonic Acid,Hydroquinone,Propane,2-Methoxy-,Isooctane3.1 Reagents: Sodium Hydroxide Solvents: Methanol4.1 Reagents: Boron Trifluoride Solvents: Toluene
标题:Process For The Preparation Of Irones
参考文献:European Patent Organization
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2912110000-甲醛
2912120000-乙醛 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2024240209-A1
优先权日:2021-04-20
标 题:Synthesis of enantiopure cis-a-irone from a renewable carbon source
发明人:CHEN XIXIAN; ZHANG CONGQIANG; T REHKA; SHUKAL SUDHA; SMITH DEREK; ANDRÉ ISABELLE; JEREMY ESQUE
权利人:AGENCY SCIENCE TECH & RES; INSTITUT NATIONAL DE RECH POUR L AGRICULTURE LALIMENTATION ET LENVIRONMENT; CENTRE NAT RECH SCIENT; INSTITUT NAT DES SCIENCES APPLIQUEES DE TOULOUSE
摘要:Synthesis of enantiopure cis-α-irone from a renewable carbon source Disclosed herein are natural and synthetic enzymes capable of performing a method of producing cis-α-irone. The method comprises providing an enzyme capable of converting psi-ionone to cis-α-irone; and contacting the enzyme and psi-ionone under suitable conditions to produce cis-α-irone. The enzyme may be a methyltransferase from Streptomyces albireticuli (SaMT), a promiscuous bifunctional methyltransferase/cyclase (pMT1) enzyme from Streptomyces, or a modified pMT1 enzyme with at least one substitution. The enzymes allow the in-vivo and in-vitro production of cis-α-irone including the use of glucose as feedstock for the biotransformation into cis-α-irone.
专利号:US-5228910-A
优先权日:1991-09-06
标题 :Mixed metal oxide crystalline powders and method for the synthesis thereof
发明人:JOYCE IVAN H; BLONSKI ROBERT P; MALONEY JOHN J; WELCH JOHN J; PIPOLY RICHARD A; BYRNE CHRISTINE J
权利人:FERRO CORP
摘要:A method for the synthesis of mixed metal oxide crystalline powders comprises the steps of preparing a raw material mixture containing at least two different metal cations; adding a template material to the mixture and blending it therewith; initiating formation of a mixed metal oxide by calcination of the mixture and the template material, whereby particles of the mixed metal oxides are formed; and thereafter recovering the mixed metal oxide particles. Mixed metal oxide crystalline powders comprise a template material; and metal oxides which form pigment classes of material containing the template material, the pigment classes being selected from the group consisting of borate, garnet, olivine, phenacite, phosphate, priderite, pyrochlore, sphene, spinel and zircon, as well as perovskite crystal classes of material containing the template, all of which have a uniform particle morphology and particle size ranging between about 0.2 to 100 mu with minimal comminution.
专利号:WO-9305877-A1
优先权日:1991-09-25
标题 :The sonochemical synthesis of amorphous metals
发明人:SUSLICK KENNETH S; GRINSTAFF MARK E; CICHOWLAS ANDRZEJ A; CHOE SEOK-BURM
权利人:RES CORP TECHNOLOGIES INC
摘要:The present invention relates to novel substantially pure amorphous metals and the sonochemical synthesis thereof comprising irradiating volatile organometallic compounds with high intensity ultrasound. The present invention is further directed to the use of amorphous metals as reactive catalysts for various processes such as the Fischer-Tropsch hydrogenation of carbon monoxide and for the hydrogenolysis and dehydrogenation of saturated hydrocarbons. The present invention further relates to the use of these amorphous metals as soft ferromagnetic materials.
专利号:US-6540971-B2
优先权日:2000-02-10
标题 :Process and reactor for the preparation of ammonia
发明人:GAM ERIK A
权利人:HALDOR TOPSOE AS
摘要:Process and reactor for the preparation of ammonia at elevated pressure and temperature in an ammonia reactor, wherein a process stream of ammonia synthesis gas is successively passed through at least three catalyst beds with intermediate cooling of partially reacted synthesis gas leaving the catalyst beds by heat exchange in heat exchangers arranged between each catalyst bed. The process stream is obtained by combining prior to introduction into a first catalyst bed, a first feed stream of synthesis gas having been preheated through indirect heat exchange during the intermediate cooling of the partially converted synthesis gas and a second feed stream of synthesis gas for adjustment of temperature of the process stream. The first feed stream is passed successively through the interbed heat exchangers for cooling the partially converted synthesis gas and space velocity of the synthesis gas is adjusted to be substantially in the same range in all catalyst beds.
专利号:US-7329767-B2
优先权日:2003-10-03
标 题:Conjugated dienamides, methods of production thereof, compositions containing same and uses thereof
发明人:DEWIS MARK L; JOHN THUMPLASSERIL V; ECKERT MARKUS A; COLSTEE JAN HERMAN; DA COSTA NEIL C; PEI TAO
权利人:INT FLAVORS & FRAGRANCES INC
摘要:Described are mixtures of at least four of the alkadienamides defined according to the structure: n nwherein R represents C 1 -C 2 n-alkyl; R 1 is 2-methyl-1-propyl and R 2 is hydrogen, or R 1 and R 2 taken together is a moiety having the formulan n nwherein n is 4 or 5, or compositions containing substantial concentrations of such mixtures, prepared according to novel processes: (a) extraction of a ground substantially dried fruit of one of the Piper species, Piper longum Linn or Piper peepuloides ; (b) natural product-forming synthesis; or (c) synthetic product-forming synthesis. Also described are uses of the thus-formed products for augmenting, enhancing or imparting an aroma, taste, chemesthetic effect and/or antibacterial effect in or to a consumable material and/or in the oral cavity and/or on the mammalian epidermis.
专利号:US-8007841-B2
优先权日:2003-10-03
标 题 :Conjugated dienamides, methods of production thereof, compositions containing same and uses thereof
发明人:JOHN THUMPLASSERIL V; ECKERT MARKUS A; DEWIS MARK L; COLSTEE JAN HERMAN; DA COSTA NEIL C
权利人:INT FLAVORS & FRAGRANCES INC
摘要:Described are mixtures of at least four of the alkadienamides defined according to the structure: n nwherein R represents C 1 -C 2 n-alkyl; R 1 is 2-methyl-1-propyl and R 2 is hydrogen, or R 1 and R 2 taken together is a moiety having the formula —(CH 2 ) n —, wherein n is 4 or 5, or compositions containing substantial concentrations of such mixtures, prepared according to novel processes: (a) extraction of a ground substantially dried fruit of one of the Piper species, Piper longum Linn or Piper peepuloides ; (b) natural product-forming synthesis; or (c) synthetic product-forming synthesis. Also described are uses of the thus-formed products for augmenting, enhancing or imparting an aroma, taste, chemesthetic effect and/or antibacterial effect in or to a consumable material and/or in the oral cavity and/or on the mammalian epidermis.