CAS: 1317-38-0; Copper(Ii) Oxide

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CAS号10024-97-2 笑气

专利信息

专利号:US-2009326281-A1
优先权日:2008-06-30
标题:Catalytic system and process for direct synthesis of dimethyl ether from synthesis gas
发明人：APPEL LUCIA GORENSTIN; DE FARIAS ANDREA MARIA DUARTE; ESTEVES ANGELA MARIA LAVOGADE; FRAGA MARCO ANDRE; RAMOS BARBOSA FLAVIA DE SOUZA; BORGES LUIZ EDUARDO PIZZARO; MONTEIRO JOSE LUIZ FONTES; HUERTAS FLORES JHONNY OSWALDO; DA SILVA MARIA ISABEL PAIS; SOUSA AGUIAR EDUARDO FALABELLA
权利人:PETROLEO BRASILEIRO SA; INT INST NAC DE TECNOLOGIA
摘要:A mixed-bed catalytic system and its activation for direct synthesis of dimethyl ether from synthesis gas are described, comprising a catalyst for methanol synthesis and the zeolite ferrierite in its acid form as the methanol dehydrating component, the two being mixed physically in the form of powder of defined granulometry or as pellets. Another object of the present invention is a process for production of the acid form of the zeolite ferrierite. Another object of the present invention is a process for direct synthesis of dimethyl ether from a synthesis gas, using the catalytic system of the present invention.

专利号:US-2015105479-A1
优先权日:2012-04-24
标 题:Catalytically active body for the synthesis of dimethyl ether from synthesis gas
发明人：SCHÄFER ALEXANDER; FEYEN MATHIAS; PARVULESCU ANDREI-NICOLAE; Müller Ulrich; SCHAACK BERND BASTIAN
权利人:BASF SE
摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.

专利号:US-9393555-B2
优先权日:2012-02-15
标题:Catalytically active body for the synthesis of dimethyl ether from synthesis gas
发明人：SCHÄFER ALEXANDER; VON FEHREN THORSTEN; MADON ROSTAM
权利人:BASF SE
摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.

专利号:US-9610568-B2
优先权日:2012-02-15
标题 :Catalytically active body for the synthesis of dimethyl ether from synthesis gas
发明人：SCHÄFER ALEXANDER; VON FEHREN THORSTEN; MADON ROSTAM
权利人:BASF SE
摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.

专利号:US-7652164-B2
优先权日:2005-09-13
标题:Process for the direct synthesis of trialkoxysilane
发明人：LEWIS KENRICK M; MEREIGH ABELLARD T; O'YOUNG CHI-LIN; CAMERON RUDOLPH A
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The Direct Synthesis of trialkoxysilane is carried out by conducting the Direct Synthesis reaction of silicon and alcohol, optionally in solvent, in the presence of a catalytically effective amount of Direct Synthesis catalyst and an effective catalyst-promoting amount of Direct Synthesis catalyst promoter, said promoter being an organic or inorganic compound possessing at least one phosphorus-oxygen bond.

专利号:EP-4353356-A1
优先权日:2022-10-14
标题:Bifunctional catalyst formulation for synthesis of dimethylether (dme) from waste carbon dioxide and hydrogen by one-step and the synthesis method thereof
发明人：SEKER EROL; ZAHIDOVA AYSEL; MUTLU VAHIDE NURAN; DELIISMAIL OZGUN; SARRAFI SAHIN; TUNCER BASAK
权利人:SOCAR TURKEY ARASTIRMA GELISTIRME VE INOVASYON A S; IZMIR YUKSEK TEKNOLOJI ENSTITUSU REKTORLUGU
摘要:This invention relates to bifunctional catalyst formulation for synthesis of dimethyl-ether (DME) from waste carbon dioxide (CO₂) and hydrogen (H₂) and the preparation method of this catalyst formulation. In the preparation method, aluminum oxide-silicon dioxide-copper oxide (Al₂O₃-SiO₂-CuO) catalyst mixture formulation is obtained by using the sol-gel method. The catalysts that are the subject of the invention are bifunctional and perform the synthesis of DME from CO₂ and H₂ in a single-step without forming unwanted byproduct of CH₄, and thus, the synthesis of DME can be done much simply and economically. In addition to this, the sol-gel method in the current invention yields the controlled crystallite size of the active component in the catalysts; thus, the active site loss problem due to uncontrolled growth of crystal sizes that occurs in traditional preparation methods is prevented. The catalyst mixture formulation weight percentages are 10%-90% Al2O₃, 10%-90% SiO₂ and 10%-90% CuO.