CAS: 1844-01-5; 4,4'-(Diphenylmethylene)Diphenol

该化合物是一种二苯乙烷衍生物,其特征是两个与中央甲烷环环环的副位置相连的氢氧基功能组,该化合物具有高度的热稳定性和僵硬性,适合高性能聚合物,环氧树脂和高级合成材料的应用,其对称结构有助于聚合工艺的连续反应,而氢氧基组则提高了交叉联系效率.该化合物还被用作合成特殊化学品的中间体,包括阻燃剂和粘合剂.其明确界定的分子结构确保了需要精确的异测控制的配方的可预测性能.

结构式图片

欧盟法规

ECHA物质C&L通报

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CAS号615575-22-9 4-hydroxy-4'-me... | CAS号59550-02-6 [diphenoxy(phen... | CAS号14470-28-1 4-甲氧基氯化三苯甲烷 | CAS号108-95-2 苯酚 | CAS号2051-90-3 二氯二苯甲烷 | CAS号71-43-2 苯 | CAS号15658-11-4 (4-羟苯基)二苯基甲醇 | CAS号7647-01-0 盐酸 | CAS号119-61-9 二苯甲酮 | CAS号100-67-4 苯酚钾 | CAS号61675-52-3 4-methyl-N-[4-[...

合成工艺路线路线简述

    二氯二苯甲烷置于盐酸体系中,化学反应生成4,4'-二苯亚甲基双酚
    参考文献:Gomberg; Jickling,Journal Of The American Chemical Society,1915,Vol. 37,P. 2577
    标题:Gomberg; Jickling,Journal Of The American Chemical Society,1915,Vol. 37,P. 2577

    海关参考信息

    专利信息


    专利号:US-6596840-B1
    优先权日:1999-07-19
    标题 :Method for producing modified polycarbonates
    发明人:KRATSCHMER SILKE; HUCKS UWE; BUNZEL LOTHAR
    权利人:BAYER AG
    摘要:A process for the synthesis of polycarbonate is disclosed. The process entails reacting in the presence of at least one phosphonium salt as catalyst, at least one diphenol, at least one carbonic acid diester, and at least one alkyl group-substituted phenol chain terminator. The chain terminator is introduced in free form or as a transesterifiable compound under the conditions of the synthesis. The polycarbonate thus produced is suitable for preparing a variety of molded articles.

    专利号:EP-3169658-A1
    优先权日:2014-07-15
    标题 :Synthesis of bisphenols

    专利号:US-9850345-B2
    优先权日:2012-05-24
    标题:Polycarbonate polyol compositions and methods
    发明人:FARMER JAY J
    权利人:SAUDI ARAMCO TECH CO
    摘要:In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO 2 , wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

    专利号:US-9809678-B2
    优先权日:2008-09-08
    标 题:Polycarbonate polyol compositions and methods
    发明人:ALLEN SCOTT D; COATES GEOFFREY W; CHERIAN ANNA E; SIMONEAU CHRIS A; GRIDNEV ALEXEI A; FARMER JAY J
    权利人:NOVOMER INC; SAUDI ARAMCO TECH CO
    摘要:In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

    专利号:WO-2018191612-A1
    优先权日:2017-04-14
    标 题 :Synthesis of a phosphorous containing monomer and the incorporation in polycarbonate by interfacial polymerization thereof

    专利号:US-3944575-A
    优先权日:1974-05-30
    标题 :Aryl ether compounds and their synthesis
    发明人:VILLAESCUSA FRANK W; BRELAND JOHN G; ARNOLD FRED E
    权利人:US AIR FORCE
    摘要:Tetranitro aryl ether compounds are prepared by aromatic nucleophilic substitution of various aryl diols with 4-fluoro-1,2-dinitrobenzene. By reducing the nitro moieties of the tetranitro compounds, tetraamino aryl ether compounds are obtained. These latter compounds are useful as monomers in preparing thermally stable polymers having good solubility parameters.
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    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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