CAS: 26087-47-8; Iprobenfos

该化合物是制药和化学实验室用于分析和质量控制的高纯度参考材料,是确定和量化各种配方和研究应用中的ibuprofen(IBP)的基准,其特点是其精确的构成,稳定性和可追溯到经认证的参考材料,确保可靠和可复制的结果,其主要优点包括在色谱分析(如HPLC,GC)和遵守国际药典标准(如USP,EP)方面始终如一地进行性能分析(如HPLC,GC)和遵守国际药典标准(如USP,EP),该标准对于方法鉴定,校准和确保药物开发和管制测试的准确性至关重要.

结构式图片

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号691-96-3 亚磷酸异丙酯 | CAS号100-44-7 氯化苄 | CAS号150-60-7 二苄基二硫 | CAS号1809-20-7 亚磷酸二异丙酯 | CAS号51756-06-0 triethylammoniu... | CAS号100-39-0 溴化苄

合成工艺路线路线简述

  • 合成目标产物 Iprobenfos 主要起始原料 Diisopropyl Phosphite And Benzyl Mercaptan
  • (文献来源)合成步骤主要原料 Diisopropyl Phosphite 和 Benzyl Mercaptan
硫代磷酸 O,O'-二异丙基酯置于sulfur体系中,用 Petroleum Ether 用作溶剂,化学反应 0.5H,反应生成异稻瘟净
参考文献:Eliseenkov,V. N.; Shumilina,T. N.,Journal Of General Chemistry Of The Ussr,1982,Vol. 52,# 4,P. 716-720
标题:Eliseenkov,V. N.; Shumilina,T. N.,Journal Of General Chemistry Of The Ussr,1982,Vol. 52,# 4,P. 716-720

海关参考信息

专利信息


专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

专利号:US-2016073631-A1
优先权日:2013-03-04
标 题 :Process for the preparation of dihydropyrrole derivatives
发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

专利号:US-9233920-B2
优先权日:2010-06-11
标题 :Process for the preparation of dihydropyrrole derivatives
发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
权利人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS; SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R 1 is chlorodifluoromethyl or trifluoromethyl; R 2 is optionally substituted aryl or optionally substituted heteroaryl; n is 0 or 1; including the process comprising (a-i) reacting a compound of formula II wherein P, R 1 and R 2 are as defined for the compound of formula I; with nitromethane in the presence a chiral catalyst to give a compound of formula III Wherein P, R 1 and R 2 are as defined for the compound of formula I; and (a-ii) reductively cyclizing the compound of formula III to give the compound of formula I. The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

专利号:US-10906880-B2
优先权日:2016-01-26
标题:Kind of isothiazole oxime ether-containing strobilurin derivatives and its preparation methods and application
发明人:FAN ZHIJIN; CHEN LAI; GUO XIAOFENG; ZHU YUJIE; QIAN XIAOLIN; MA LIUYONG; ZHANG NAILOU; WANG HAIXIA; ZHANG ZHIMING; XU JINGHUA; SONG YINQI
权利人:UNIV NANKAI
摘要:The present invention is that provided a synthesis method of a series of isothiazole oxime ether containing strobilurin derivatives IV. The present invention relates to 3,4-dichloroisothiazolyl oxime ether strobilurin derivatives, and their chemical structural formula is as shown by IV. n n n n n n n n n n The invention discloses the structural formula of the above compound, the synthesis method and the use as an insecticide, a fungicide, an anti-plant virus agent, and an agriculturally acceptable auxiliary or synergist and a commercial insecticide. The use of a fungicide, an anti-plant virus agent and an acaricide in combination for controlling agricultural, forestry, horticultural plant pests, diseases, virus diseases and preparation methods.

专利号:US-9968097-B2
优先权日:2012-05-30
标题:Composition comprising a biological control agent and a fungicide selected from inhibitors of the lipid membrane synthesis, the melanine biosynthesis, the nucleic acid synthesis or the signal transduction
发明人:WACHENDORFF-NEUMANN ULRIKE; ANDERSCH WOLFRAM; STENZEL KLAUS; SPRINGER BERND
权利人:BAYER CROPSCIENCE AG
摘要:The present invention relates to a composition comprising at least one biological control agent. Furthermore, the present invention relates to the use of this composition as well as a method for reducing overall damage of plants and plant parts.

专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.
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主要参考文献


1: Kwon YS, Nguyen VT, Park JG, Gu MB. Detection of iprobenfos and edifenphos using a new multi-aptasensor. Anal Chim Acta. 2015 Apr 8;868:60-6. doi: 10.1016/j.aca.2015.02.020. Epub 2015 Feb 12. Epub 2007 Jan 4. doi: 10.1007/s00244-009-9364-1. Epub 2009 Jul 17. doi: 10.1007/s00128-011-0335-7. Epub 2011 Jun 15. doi: 10.1007/s00216-015-9071-x. Epub 2015 Oct 14. doi: 10.1016/j.cbpc.2008.10.100. Epub 2008 Nov 1. doi: 10.1038/cddis.2013.380.
9: Kim MS, Kim GW, Park TJ. A facile and sensitive detection of organophosphorus chemicals by rapid aggregation of gold nanoparticles using organic compounds. Biosens Bioelectron. 2015 May 15;67:408-12. doi: 10.1016/j.bios.2014.08.073. Epub 2014 Sep 3. doi: 10.5423/PPJ.OA.08.2014.0077. Epub 2014 Dec 15.
11: Tawata S, Taira S, Kobamoto N, Zhu J, Ishihara M, Toyama S. Synthesis and antifungal activity of cinnamic acid esters. Biosci Biotechnol Biochem. 1996 May;60(5):909-10. doi: 10.1016/j.chemosphere.2008.10.046. Epub 2008 Dec 11. doi: 10.1016/j.marenvres.2010.12.007. Epub 2011 Jan 5. Russian. doi: 10.1271/bbb.61.2103. Russian. Russian.

合成参考文献


摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 409.
摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 51(9)(77), 1986
摘要:Pesticide Manual., 9(500), 1991
摘要:Toho Igakkai Zasshi. Journal of Medical Society of Toho University., 29(51), 1982
参考文献:10.1007/s00216-015-9071-x
摘要:Cho HR, Park JS, Kim J, Han SB, Choi YS. Multiresidue method for the quantitation of 20 pesticides in aquatic products. Analytical and Bioanalytical Chemistry. 2015 Oct 14;407(30):9043–52. doi: 10.1007/s00216-015-9071-x.
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