CAS: 866-23-9; Diethyltrichloromethylphosphonate
该化合物是一种有机磷化合物,其特征是三氯甲基和磷酸酯功能组,这种试剂主要用于有机合成,作为一种多用途中间体,特别是用于制造含有磷的化合物,并用作进一步化学修改的前体,其反应力来自有助于核生殖替代反应的三氯甲基电算组,该化合物在标准处理条件下具有稳定性,在将磷酸盐混合物引入目标分子方面具有效率,并因其在合成农用化学品,药品和特殊化学品方面具有效率而得到重视,建议进行适当的处理和储存,因为它具有水分和强力基的潜在反应.
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: RVAQSYWDOSHWGP-UHFFFAOYSA-N
- InChI=1S/C5H10Cl3O3P/c1-3-10-12(9,11-4-2)5(6,7)8/h3-4H2,1-2H3…
- 计算化学: 氢键受体数3.0氢键供体数0可旋转键数4
相似化合物
3167-63-3物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS07;
注释: Exclamation mark - 危险类别特定目标器官毒性 - 单次接触 类别3
皮肤腐蚀/刺激 类别2
严重眼刺激 类别2
急性毒性 类别4(吸入)
急性毒性 类别4(经皮)
急性毒性 类别4(经口)
严重眼刺激 类别2A - 警示词Warning(警告)
- 危险描述H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害. - 防范说明P264-P280-P302+P352-P362
- 危险等级6.1
- UN编号UN3278
- 危险品标志Xi
- 包装等级III
- 安全声明26-36-60-36/37
- 危险类别码36/37/38-22
- WGK Germany3
欧盟法规
ECHA物质C&L通报上下游产品
tetrachloromethane diphosphorous acid tetraethyl ester 1-adamantyl diethyl phosphite diethylamine(trichloromethyl)phosphonic acid phenyl-hydrazine; salt of trichloromethyl-phosphonic acid monoethyl ester 1,1-dichloro-2,2-diphenylethene ethyl (2-chlor°Cyclohexylidene)acetate合成工艺路线路线简述
- 合成目标产物 Diethyl (Trichloromethyl)Phosphonate 主要起始原料 Carbon Tetrachloride And Triethyl Phosphite
- (文献来源)合成步骤主要原料 Carbon Tetrachloride 和 Triethyl Phosphite
Trichloromethyl-Phosphonic Acid Monoethyl Ester 反应生成 三氯甲基膦酸二乙酯
参考文献:Jakubowitsch; Ginsburg,Zhurnal Obshchei Khimii,1954,Vol. 24,P. 2250,2254; Engl. Ausg. S. 2219,2222
标题:Jakubowitsch; Ginsburg,Zhurnal Obshchei Khimii,1954,Vol. 24,P. 2250,2254; Engl. Ausg. S. 2219,2222
海关参考信息
- 2903130000-三氯甲烷
2903120001-二氯甲烷
2901100000-饱和无环烃
2931399090-其他含磷有机-无机化合物 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2013331427-A1
优先权日:2006-07-28
标题:Methods of stimulating cellular growth, synaptic, remodeling and consolidation of long-term memory
发明人：ALKON DANIEL L
权利人:BRNI NEUROSCIENCES INST; BRNI NEUROSCIENCES INST
摘要:The present invention provides methods of slowing or reversing the loss of memory and learning comprising the steps of contacting an effective amount of a PKC activator with a protein kinase C (PKC) in a subject identified with memory loss slowing or reversing memory loss. The present invention provides methods of stimulating cellular growth, neuronal growth, dendritic growth, dendritic spine formation, dendritic spine density, and the translocation of ELAV to proximal dendrites, and synaptic remodeling. The present invention also provides methods of contacting a protein kinase C (PKC) activator with a PKC activator in a manner sufficient to stimulate the synthesis of proteins sufficient to consolidate long-term memory. The present invention also provides methods of contacting a protein kinase C (PKC) activator with a PKC activator in a manner sufficient to downregulate PKC.
专利号:EP-3004036-A1
优先权日:2013-05-31
标题 :Methods of synthesis of ingenol and intermediates thereof
专利号:CA-2911960-A1
优先权日:2013-05-31
标题 :Methods of synthesis of ingenol and intermediates thereof
专利号:AU-2014273108-A1
优先权日:2013-05-31
标 题:Methods of synthesis of ingenol and intermediates thereof
专利号:US-2016107977-A1
优先权日:2013-05-31
标题 :Methods of synthesis of ingenol and intermediates thereof
专利号:KR-20160016940-A
优先权日:2013-05-31
标题:Methods of synthesis of ingenol and intermediates thereof
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📌 第三方产品分析报告
主要参考文献
参考标题:Mild Synthesis Of Organophosphorus Compounds: Reaction Of Phosphorus-Containing Carbenoids With Organoboranes作者:Monika I. Antczak,Jean-Luc Montchamp |发布日期:2008.3.1
摘要:Organoboranes React With Phosphorus-Containing Carbenoids To Produce A Variety Of Functionalized Organophosphorus Compounds Under Mild Conditions. In Some Cases, Selective Migration Of One Group Attached To Boron Can Be Observed. Phosphonite-Borane Complexes Are Introduced As Novel Synthons For The Synthesis Of Phosphinic Esters.
合成参考文献
摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 388.
摘要:Farmakologiya i Toksikologiya, 10(121), 1975
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