盐酸置于ta-Oxyd Hydrate体系中,用 Melt 作为反应溶剂,化学反应生成 五氯化钽 参考文献:Preparation Of The Refractory Metals By Fused Salt Electrolysis 标题:Preparation Of The Refractory Metals By Fused Salt Electrolysis
专利信息
专利号:US-7615169-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-7927516-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-2007074541-A1 优先权日:2003-10-10 标 题:Synthesis of germanium sulphide and related compounds 发明人:BADDING JOHN V; HEWAK DANIEL W; HUANG CHUNG-CHE 权利人:UNIV SOUTHAMPTON 摘要:The invention relates to synthesis of germanium sulphide glasses and optical devices formed therefrom. In a chemical vapour deposition process, germanium tetrachloride is reacted with hydrogen sulphide at temperatures in the range 450-700° C. to form germanium sulphide. Lower temperatures within this range of 450-550° C. directly produce a glass, whereas higher temperatures within the range of 600-700° C. produce a crystalline powder which can then be reduced to a glass by subsequent melting and annealing. The reaction is preferably carried out at atmospheric pressure or slightly higher. Thin films and bulk glasses suitable for optical waveguides can be formed directly in one processing step as can powders and microspheres. The materials synthesised are of a high purity with low oxide impurities and only trace levels of transition metal ions.
专利号:US-9919973-B1 优先权日:2017-03-31 标题 :Synthesis of high temperature ceramic powders 发明人:CHENG ZHE; FOROUGHI PANIZ; BEHRENS ANDRES 权利人:CHENG ZHE; FOROUGHI PANIZ; BEHRENS ANDRES; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES 摘要:The present invention relates to methods and apparatuses for forming high temperature ceramic powders. A method of producing high temperature ceramic powders according to an embodiment of the present invention can include preparing a solution, atomizing the solution, providing a gas and carrying the atomized solution into a furnace via the gas, evaporating the solvent, precipitating and drying the solutes, performing a thermolysis (or pyrolysis) reaction, and performing a carbothermal reduction reaction (CTR) in situ, and collecting product particles after they exit from the furnace.
专利号:US-4171320-A 优先权日:1977-10-19 标题 :Hydrocarbon synthesis from CO and H2 using Ru supported on group VB metal oxides 发明人:TAUSTER SAMUEL J; VANNICE M ALBERT 权利人:EXXON RESEARCH ENGINEERING CO 摘要:An improved method for the synthesis of hydrocarbons with reduced methane formation and for the selective generation of olefinic hydrocarbons, preferably C2-C5 olefins inclusive, which method comprises the steps of passing a CO and H2 synthesis gas stream over a catalyst at a temperature and pressure for a time sufficient to generate the desired olefinic products, wherein the improvement consists in using as a catalyst ruthenium on a support comprising at least one refractory Group VB metal oxide. The weight loading of the ruthenium may range from about 0.01 to about 15 wt. % based on the total catalyst weight. The ruthenium average crystallite size is preferably less than 5 nm (50A). The operating conditions of the instant process are typical for Fischer-Tropsch synthesis.
专利号:US-11713329-B2 优先权日:2018-12-10 标 题 :Intermediates useful in the preparation of halichondrin compounds and methods for preparing the same 发明人:XU WEIPING 权利人:BEIJING TIENYI LUFU PHARMATECH CO LTD 摘要:The invention relates to intermediates useful in the preparation of halichondrin compounds, methods for preparing the same and use thereof, such as halichondrins, eribulin, or their analogs. The intermediates, the methods and use thereof are used for the synthesis of the C20-C26 fragment of halichondrin compounds. The raw materials in the synthetic route of the invention are cheap and easily obtained, the sources and the qualities of the raw materials are reliable. The choice of the methods useful in the synthesis of chiral central structures are based on the structural characteristics of the reactants, thus effectively improving the synthesis efficiency, reducing the difficulties and risks of product quality control, and avoiding the use of highly toxic and expensive organotin catalysts to significantly decrease costs and improve environmental friendliness.
摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1432. 摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1436. 摘要:Roy, K.-M., Science of Synthesis, (2010) 47, 899. 摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 181. 参考文献:10.1007/bf02257271 摘要:Pearce SR, Pich U, Harrison G, Flavell AJ, Heslop-Harrison JS, Schubert I, Kumar A. The Ty1-copia group retrotransposons of Allium cepa are distributed throughout the chromosomes but are enriched in the terminal heterochromatin. Chromosome Res. 1996 Aug;4(5):357–64. doi: 10.1007/bf02257271.