CAS: 101-67-7; Bis(4-Octylphenyl)Amine

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1-bromo-4-°Ctylbenzene 4-°Ctylaniline3-(2-methyl-3-indolyl)-3-[N,N-bis-(4-°Ctylphenyl)amino]phthalide 3-(1-butyl-2-methyl-3-indolyl)-3-[N,N-bis-(4-°Ctylphenyl)-amino]phthalide 3-(1-ethyl-2-methyl-3-indolyl)-3-[N,N-bis-(4-°Ctylphenyl)amino]phthalide 3-[4-(diethylamino)-2-ethoxyphenyl]-3-[N,N-bis-(4-°Ctylphenyl)amino]phthalide

1-(4-溴苯基)辛烷,4-辛基苯胺置于tris-(Dibenzylideneacetone)Dipalladium(0),三叔丁基膦,Sodium T-Butanolate体系中,用 甲苯 用作溶剂,化学反应 1.0H,以78%的收率获得4,4'-二辛基二苯胺
参考文献:供体-受体取代苝衍生物的自组装,动力学和相变动力学
标题:供体-受体取代苝衍生物的自组装,动力学和相变动力学
摘要:通过 X 射线散射,量热法和位点特定的固态 NMR 技术,在一系列二苯胺官能化苝单酰亚胺 (Pmi) 中研究了烷基链取代对相形成和核心动力学的作用.此外,与分子的供体-受体特征相关的强偶极子允许使用介电光谱研究动力学.自组装仅在具有支链烷基链的 Pmi 中显示出有序相.该阶段包括分子扭曲角为 60 度的螺旋状分子堆叠.固态核磁共振的结果进一步指出了分子内氢键在稳定有序相内的柱内填料方面的重要性.而且,正如动态有序参数的值和偶极弛豫强度的降低所揭示的那样,核心动力学被冻结.从各向同性相到有序相的相变动力学通过成核和生长机制进行,并且速率受成核势垒支配.在各向同性相内,核心动力学显示出强烈的温度依赖性,其速率取决于烷基链中亚甲基单元的数量.
Doi:10.1021/ja102150G

专利信息

专利号:US-5734084-A
优先权日:1996-12-17
标 题 :Synthesis of alkylated aromatic amines
发明人：ZHU PING Y
权利人:LUBRIZOL CORP
摘要:An improved method for making alkylated aromatic amines is disclosed. The method includes a new alkylating catalyst system comprising an aromatic amine alkylating catalyst and a non-catalyst solid such as silica. The method results in faster reaction rates and higher yields of alkylated aromatic amines.

专利号:US-4602088-A
优先权日:1984-07-26
标题 :Preparation of enamines from conjugated dienes
发明人：LIN JIANG-JEN
权利人:TEXACO INC
摘要:A method for the preparation of enamines wherein a conjugated diene is reacted with a secondary amine, carbon monoxide and hydrogen (synthesis gas) in solvent solution in the presence of a rhodium catalyst. In accordance with the preferred embodiment, butadiene is reacted with a dialkylamine and synthesis gas in an organic solvent in the presence of a rhodium catalyst to provide the corresponding 1,3-pentadienyl dialkylamine in good yield and with good selectivity. This may be illustrated, for example, by the following equation: H3CCHCHCHCHNR2 + H2O

专利号:US-4310429-A
优先权日:1978-06-19
标 题 :Stabilized polymers, novel stabilizers, and synthesis thereof
发明人：LAI JOHN T
权利人:GOODRICH CO B F
摘要:Novel alpha -aminoacetamides are powerful stabilizers for organic materials subject to oxygen and heat degradation, and particularly for synthetic natural rubber and synthetic ester lubricants. A wide range of substituents on the amine and amide N atoms, and also on the saturated carbon atom, yields an array of stabilizers having a wide range of compatibility in compositions comprising various synthetic resinous compounds to be stabilized. Novel syntheses are provided utilizing at least one amine nucleophilic agent, a dichlorocarbene ion generating agent, and an alkoxide ion generating agent, which together in the presence of aqueous alkali and an onium salt, yield novel alpha -aminoacetamides in which a wide choice of substituents may be introduced. The nucleophilic agent may be a primary or secondary amine, or one of each. The dichlorocarbene ion generating agent is a haloform. The alkoxide ion generating agent may be a ketone, an aldehyde, or a cyanohydrin which reacts with the haloform. An alpha -trihalomethyl alcohol also reacts with the amine nucleophilic agent, without the benefit of a dichlorocarbene ion generating agent. When the alkoxide ion generating agent is an alpha -trihalomethyl alcohol, an alpha -hydrogen may optionally be substituted.

专利号:EP-0253007-A1
优先权日:1986-07-15
标 题 :Stabilized polymers, novel stabilizers, and synthesis thereof
发明人：LAI JOHN TA-YUAN
权利人:GOODRICH CO B F
摘要:Novel α-aminoacetamides are powerful stabilizers for organic materials subject to oxygen and heat degradation, and particularly for synthetic natural rubber, synthetic ester lubricants and synthetic resinous materials. A wide range of substituents on the amine and amide N atoms, at least one of which substituents is an alkylene imine (cyclic), and an even wider range of substituents on the saturated carbon atom, yields an array of stabilizers having a wide range of compatibility in compositions comprising various synthetic resinous compounds to be stabilized. n Novel syntheses are provided utilizing at least one amine nucleophilic agent, a trichloromethide ion generating agent, and an alkoxide ion generating agent, which together in the presence of aqueous alkali and an onium salt, yield novel a-aminoacetamides in which a wide choice of substituents may be introduced. The nucleophilic agent may be a primary or secondary amine, or one of each. The trichloromethide ion generating agent is a haloform. The alkoxide ion generating agent may be a ketone, or an aldehyde which reacts with the haloform. n Cross-reference to related application: This is a continuation-in-part application to Ser.No. 916,639 filed June 19, 1978.

专利号:US-4601839-A
优先权日:1978-06-19
标题:Stabilized polymers, novel stabilizers, and synthesis thereof
发明人：LAI JOHN T
权利人:GOODRICH CO B F
摘要:Novel alpha -aminoacetamides are powerful stabilizers for organic materials subject to oxygen and heat degradation, and particularly for synthetic natural rubber, synthetic ester lubricants and synthetic resinous materials. A wide range of substituents on the amine and amide N atoms, at least one of which substituents is an alkylene imine (cyclic), and an even wider range of substituents on the saturated carbon atom, yields an array of stabilizers having a wide range of compatibility in compositions comprising various synthetic resinous compounds to be stabilized. Novel syntheses are provided utilizing at least one amine nucleophilic agent, a trichloromethide ion generating agent, and an alkoxide ion generating agent, which together in the presence of aqueous alkali and an onium salt, yield novel alpha -aminoacetamides in which a wide choice of substituents may be introduced. The nucleophilic agent may be a primary or secondary amine, or one of each. The trichloromethide ion generating agent is a haloform. The alkoxide ion generating agent may be a ketone, or an aldehyde which reacts with the haloform.

专利号:EP-0849255-A1
优先权日:1996-12-17
标 题 :Improved synthesis of alkylated aromatic amines