CAS: 1124-64-7; 1-Butylpyridinium Chloride

该化合物是一种离子液体,其特性是其独特结合的二酸和丁基化合物,配有氯化阴离子;该化合物一般在室温下呈现无色至黄液,具有低挥发性,因此具有吸引传统有机溶剂的替代品;它具有相对较高的热稳定性,可以用于各种化学过程,而不会发生显著降解;丁基锡化合物组的存在助长了其疏水性;而环则具有一定程度的极性,有利于极地溶剂和非极地溶剂中的溶性. 已知1-丁基二烯氯化物具有溶解广泛有机和无机化合物的能力,因此在诸如提取,催化和电化学等应用中有用.此外,它的离子性质具有独特的特性,例如增强的电化学应用中有利于增强的传导性.总的来说,这种化合物在研究和工业环境中都是一种多用途和有价值的物质.

结构式图片

相似化合物

874-80-6 203389-28-0 186088-50-6

欧盟法规

REACH注册C&L通报

上下游产品

pyridine n-Butyl chloride chlorosulfurous acid butyl ester diethyl ether N-butylpyridinium chloroaluminate

合成工艺路线路线简述

  • 合成目标产物 1-Butylpyridinium Chloride 主要起始原料 Pyridine And 1-Chlorobutane
  • (文献来源)合成步骤主要原料 Pyridine 和 1-Chlorobutane
吡啶,氯丁烷 反应 24.0H,以92%的收率获得n-正丁基氯化吡啶
参考文献:[hyetpy]Cl-h2O: An Efficient And Versatile Solvent System For The Dabco-Catalyzed Morita-baylis-hillman Reaction
标题:[hyetpy]Cl-h2O: An Efficient And Versatile Solvent System For The Dabco-Catalyzed Morita-baylis-hillman Reaction
摘要:一个非常高效和多功能的溶剂系统,[hyetpy]Cl-h2O,已经被开发并用于dabco催化的morita-baylis-hillman反应.
Doi:10.1039/c5Ra02102B

海关参考信息

专利信息


专利号:US-2005087449-A1
优先权日:2002-03-04
标题:Electrochemical synthesis of ammonia
发明人:DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-2010191010-A1
优先权日:2007-07-02
标题 :Process for the synthesis of carbamates using co2
发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
权利人:HUNTSMAN INT LLC
摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

专利号:US-6712950-B2
优先权日:2002-03-04
标 题 :Electrochemical synthesis of ammonia
发明人:DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE
权利人:LYNNTECH INC
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-6881308-B2
优先权日:2002-03-04
标 题 :Electrochemical synthesis of ammonia
发明人:DENVIR ADRIAN J; MURPHY OLIVER J; CISAR ALAN J; ROBERTSON PRISCILLA; USELTON KYLE
权利人:LYNNTECH INC
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-8608935-B2
优先权日:2006-03-24
标 题:Apparatus and method for synthesis of alane
发明人:VAJO JOHN J; LIU PING
权利人:VAJO JOHN J; LIU PING; GM GLOBAL TECH OPERATIONS INC
摘要:One embodiment of the invention includes an electrochemical cell and an externally applied electrical potential used to drive a direct synthesis reaction to produce alane.

专利号:US-9512080-B2
优先权日:2012-07-10
标 题:Synthesis of acridinium compounds by N-alkylation of acridans
发明人:NATRAJAN ANAND; WEN DAVID
权利人:SIEMENS HEALTHCARE DIAGNOSTICS INC
摘要:A method is provided for N-alkylation of acridine compounds by reduction of acridines to corresponding acridans to improve the reactivity of the acridine nitrogen, and subsequent N-alkylation of the acridans in ionic liquid solvents to provide the corresponding acridinium compounds in high yield. This inventive process improves chemical conversion, and does not require the use of highly toxic alkylating agents, such as 1,3-propane sultone.
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合成参考文献


摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2010) 2, 12.
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