专利号:US-10865116-B2 优先权日:2017-03-24 标 题:Process for the synthesis of IZM-2 zeolite in the presence of a template, 1,6-bis(methylpiperidinium)hexane dihydroxide 发明人:MARTINEZ FRANCO RAQUEL; BATS NICOLAS 权利人:IFP ENERGIES NOW 摘要:A novel process is described for the preparation of a microporous crystalline solid, known as IZM-2 microporous solid or IZM-2 zeolite. This novel process consists of carrying out the synthesis of IZM-2 zeolite by conversion/transformation of a zeolite with structure type FAU in a fluorinated medium under hydrothermal conditions. In particular, said novel process consists of carrying out the synthesis of an IZM-2 zeolite in a fluorinated medium starting from a zeolite with structure type FAU used as the source of silicon and aluminium and a specific organic molecule or template comprising two quaternary ammonium functions, namely 1,6-bis(methylpiperidinium)hexane dihydroxide.
专利号:US-7927516-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-10875778-B2 优先权日:2017-03-24 标 题 :Process for the synthesis of IZM-2 zeolite in the presence of a template, 1,6-bis(methylpiperidinium)hexane dibromide 发明人:MARTINEZ FRANCO RAQUEL; BATS NICOLAS 权利人:IFP ENERGIES NOW 摘要:A novel process is described for the preparation of a microporous crystalline solid, known as IZM-2 microporous solid or IZM-2 zeolite. This novel process consists of carrying out the synthesis of IZM-2 zeolite by conversion/transformation of a zeolite with structure type FAU under hydrothermal conditions. In particular, said novel process consists of carrying out the synthesis of an IZM-2 zeolite starting from a zeolite with structure type FAU used as the source of silicon and aluminium and a specific organic molecule or template comprising two quaternary ammonium functions, namely 1,6-bis(methylpiperidinium)hexane dibromide.
专利号:US-9994508-B2 优先权日:2012-12-11 标 题:Versatile and functionalised intermediates for the synthesis of vitamin D and novel vitamin D derivatives 发明人:LOPEZ PEREZ BORJA; SIGUEIRO PONTE RITA; MAESTRO SAAVEDRA MIGUEL A; MOURINO MOSQUERA ANTONIO 权利人:ENDOTHERM GMBH 摘要:Novel intermediates for the complete synthesis of vitamin D are provided that allow a great versatility of functional groups in the final vitamin derivatives. Vitamin derivatives that are epimeric in position 3 and vitamin derivatives with a wide range of functionalities in position 18, including compounds with isotopic labelling are provided.
专利号:US-6316379-B1 优先权日:1998-06-15 标 题 :ZSM-5 zeolite materials doped with fluorine species for the synthesis of MTBE and other acido-catalyzed reactions 发明人:MAO RAYMOND LE VAN 权利人:UNIV CONCORDIA 摘要:Provided herein is are acidic Z5M-5 zeollte materials which are highly active and selective in the synthesis of methyl tert-butyl ether (MTBE) and similar ethers. The materials are obtained by the preparation method comprising the main steps of: i) impregnation of zeolites with fluorine species using ammonium fluoride as precursor, preferably with a F loading of ca.1.9×10 3 mol.g −1 of zeolite; and ii) stepwise activation in air at preferably 250° C. and then preferably at 300° C. to 500° C., preferably 450° C. The method is preferably applied to desilicated ZSM-5 zeolite and provides conversion rates to MTBE superior to those obtained with prior art commercial AMBERLYSFâ„¢ resin (gas phase reaction at 70-80° C.) is obtained. No by-products, commonly produced by prior art commercial organic resin catalyst, are detected in the product spectrum.
专利号:US-8541571-B2 优先权日:2008-03-03 标题:Homogeneous synthesis of cellulose ethers in ionic liquids 发明人:MOELLMANN EUGEN; HEINZE THOMAS; LIEBERT TIM; KOEHLER SARAH 权利人:MOELLMANN EUGEN; HEINZE THOMAS; LIEBERT TIM; KOEHLER SARAH; SE TYLOSE GMBH & CO KG 摘要:The invention is directed to a simple and new method for the homogeneous synthesis of cellulose ethers. Ionic liquids are not only used as solvent, but also as reaction media for the homogeneous etherification of cellulose. The dissolved cellulose is treated with the etherification agent in the absence of organic and/or inorganic bases and in the absence and/or in the presence of moderate amounts of water. The obtained cellulose ethers show new distributions of substitution on the polymer chain, resulting in new properties and applications.
参考文献:10.1186/1752-153x-5-41 摘要:Shishehbore MR, Afkhami A, Bagheri H. Salicylic acid functionalized silica-coated magnetite nanoparticles for solid phase extraction and preconcentration of some heavy metal ions from various real samples. Chemistry Central Journal. 2011 Jul 15;5(1). doi: 10.1186/1752-153x-5-41. 参考文献:10.1186/1556-276x-6-463 摘要:Li T, Chen Y, Lei W, Zhou X, Luo S, Hu Y, Wang L, Yang T, Wang Z. Effect of growth temperature on the morphology and phonon properties of InAs nanowires on Si substrates. Nanoscale Research Letters. 2011 Jul 21;6(1):463. doi: 10.1186/1556-276x-6-463. 参考文献:10.1186/1556-276x-6-462 摘要:Chen C, Xie Y, Ali G, Yoo SH, Cho SO. Improved conversion efficiency of Ag2S quantum dot-sensitized solar cells based on TiO2 nanotubes with a ZnO recombination barrier layer. Nanoscale Research Letters. 2011 Jul 21;6(1):462. doi: 10.1186/1556-276x-6-462.