CAS: 1271-55-2; 1-Ferrocenylethanone

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CAS号102-54-5 二茂铁 | CAS号75-36-5 乙酰氯 | CAS号108-24-7 乙酸酐 | CAS号12093-10-6 二茂铁甲醛 | CAS号75-16-1 甲基溴化镁 | CAS号1271-47-2 二茂铁乙炔 | CAS号1600-27-7 乙酸汞 | CAS号75-34-3 1,1-二氯乙烷标准溶液 | CAS号108-30-5 丁二酸酐 | CAS号1287-16-7 二茂铁乙酸 | CAS号1271-51-8 乙烯基二茂铁 | CAS号1277-49-2 1-二茂铁基乙醇 | CAS号1271-47-2 二茂铁乙炔 | CAS号1271-42-7 二茂铁甲酸 | CAS号12085-68-6 (1-氯-2-甲酰基乙烯基)二茂铁 | CAS号71159-94-9 methyl 1-(3-eth... | CAS号6318-84-9 cyclopenta-1,3-... | CAS号7647-01-0 盐酸

二茂铁置于乙酸酐体系中,化学反应生成乙酰基二茂铁
参考文献:二茂铁,乙酰基-,1,1'-二乙酰基-,苯甲酰基-和 1,1'-二苯甲酰基二茂铁的热容 Dsc
标题:二茂铁,乙酰基-,1,1'-二乙酰基-,苯甲酰基-和 1,1'-二苯甲酰基二茂铁的热容 Dsc
摘要:摘要 通过 Dsc置于20-100oc 温度范围内得到了二茂铁,乙酰基-,1,1'-二乙酰基-,苯甲酰基-和 1,1'-二苯甲酰基二茂铁的热容值和回归线方程在这个温度区间已经计算出来了.二茂铁获得的数据与文献中报道并由 Jons 和 Gjaldbaek 获得的数据一致.报告了对热容量行为的一些观察和相关性.
Doi:10.1016/0040-6031(81)80254-7

专利信息

专利号:US-5214175-A
优先权日:1990-09-27
标 题:Process for the synthesis of monohaloalkylferrocenes and 4-chlorobutylferrocene
发明人：GAUTIER JEAN-CLAUDE; MELIN JEAN-GUY; MONDET JEAN-CLAUDE
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The present invention relates to a process for the synthesis of a monohaloalkylferrocene by reaction of hydrogen with a monohaloalkanoylferrocene in the presence of PtO2 and SnCl2 as catalyst in an acetic acid medium. In this manner, a crude, particularly pure synthetic product is obtained in a high yield, simply and inexpensively. The monohaloalkylferrocenes are especially useful as surfactants or as intermediates for the synthesis of combustion catalysts for propergols. The present invention also relates to a novel monohaloalkylferrocene, namely 4-chlorobutylferrocene.

专利号:US-5550267-A
优先权日:1994-06-14
标 题:Process for the synthesis of haloalkylferrocenes
发明人：GRAINDORGE HERVE; MONDET JEAN-CLAUDE; VINCENT CHARLES-HENRY
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The present invention relates to a process for the synthesis of haloalkylferrocenes, comprising a first stage of reaction, in the presence of AlCl 3 as catalyst and in organic solvent medium, of a carboxylic acid halide or anhydride with ferrocene or an alkylferrocene. n After this stage, without prior isolation of the intermediate compound, a metal hydride is added to the reaction mixture. n The haloalkylferrocenes are particularly useful as intermediates in the synthesis of combustion catalysts for propellants.

专利号:EP-0687683-B1
优先权日:1994-06-14
标 题:Process for the synthesis of haloalkylferrocenes

专利号:EP-0687683-A1
优先权日:1994-06-14
标 题:Process for the synthesis of haloalkylferrocenes

专利号:DE-69515729-T2
优先权日:1994-06-14
标 题 :Process for the synthesis of haloalkylferrocenes

专利号:EP-0478417-A1
优先权日:1990-09-27
标 题:Process for the synthesis of monohalogeno-alkyl-ferrocenes