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CAS号124-22-1 十二胺 | CAS号64-19-7 冰醋酸 | CAS号22214-02-4 dodecyl(trimeth...

十二烷基伯胺,溶剂黄146 反应生成1-十二烷胺乙酸盐
参考文献:一些高级脂肪胺盐的制备及细菌活性
标题:一些高级脂肪胺盐的制备及细菌活性
摘要:阳离子表面活性剂如季铵化合物早就知道具有防腐性能,并且已经对它们的生理作用进行了非常详细的研究.然而,关于结构相似的高分子量烷基胺及其盐的抗菌活性的信息非常少.对一些高级伯烷基胺对 17 种真菌和 14 种细菌的作用的研究表明,最有效的烷基胺是那些含有 12-15 个碳原子的烷基胺,具体取决于真菌或微生物的类型 [i].对于仲烷基胺~具有 11-13 个亚甲基单元的那些表现出最佳的抗菌活性 [2].烷基多胺的衍生物如 1-烷基-7-苄基二亚乙基三胺 [3,4] 也表现出相当大的细菌效力.二-,三-的混合物,四辛基二亚乙基三胺具有广谱的抗菌活性.此类产品已在国外以相同的 Tego-Diokto 获得专利 [5].大多数烷基胺不溶于水,只能与各种羟乙基化表面活性剂混合使用.含羟基的烷基多胺盐没有这个缺点[6].
Doi:10.1007/bf01150720

专利信息

专利号:US-6599972-B2
优先权日:1996-12-24
标 题 :Latex compositions containing ethylenically unsaturated esters of fatty compounds and applications thereof
发明人：THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; FRUCHEY OLAN STANLEY
权利人:UNIV SOUTHERN MISSISSIPPI
摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from -5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

专利号:US-6897255-B1
优先权日:1996-12-24
标题:Latex compositions containing ethylenically unsaturated esters of long-chain alkenols and applications thereof
发明人：THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; FRUCHEY OLAN STANLEY
权利人:UNIV SOUTHERN MISSISSIPPI
摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable long-chain alkenol ester monomers are disclosed and claimed. Preferred embodiments include latex formed from acrylate or methacrylate esters of long-chain alkenols. A process for the synthesis of the latex composition is also disclosed, which involves (a) esterification of a long-chain alkenol with an ethylenically unsaturated carboxylic acid; (b) polymerization of the ethylenically unsaturated ester in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

专利号:US-6203720-B1
优先权日:1996-12-24
标题 :Low MFT and high Tg , internally plasticizing, and low voc latex compositions
发明人：THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; HARIHARAN RAJAN; WANG ZHIYU
权利人:UNIV SOUTHERN MISSISSIPPI
摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

专利号:US-2011230343-A1
优先权日:2008-10-24
标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance
发明人：SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO
权利人:BASF SE
摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.

专利号:US-6624223-B1
优先权日:1996-12-24
标题 :Internally plasticized and low VOC latex compositions and applications thereof
发明人：THAMES SHELBY FRELAND; WANG ZHIYU; BRISTER ELIZABETH H; HARIHARAN RAJAN; KING COREY L; PANJNANI KAMLESH GOPICHAND
权利人:UNIV SOUTHERN MISSISSIPPI
摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.