CAS: 111296-90-3; 5,7-Dihydroindolo[2,3-B]Carbazole

该化合物是一种多环芳烃化合物,其特点是其引信化的无粉和碳氨基甲醚结构,该化合物具有双环框架,有助于其独特的电子特性,使其对有机电子和医药化学等各个领域感兴趣,典型的是一种平板结构,它增强了其参与欧元堆叠相互作用的能力,这种互动有利于有机半导体和发光装置的应用.惰性与氨基聚醚中的氮原子会影响其再活动性和溶性及其潜在的生物活动.此外,5,7-二氢-Indolo [2,3-b]carbazole可能表现出可被光学应用利用的荧光体.其合成通常涉及多步有机反应,并且可能作为更复杂的衍生物的前体.

结构式图片

相似化合物

109005-10-9 111296-91-4 200339-30-6

欧盟法规

C&L通报

上下游产品

CAS号150758-05-7 1,3-二硝基-4-苯基联苯 | CAS号24239-82-5 1,5-二溴-2,4-二硝基苯 | CAS号108-45-2 间苯二胺

合成工艺路线路线简述

  • 合成目标产物 5,7-Dihydro-Indolo[2,3-B]Carbazole 主要起始原料 Phenylhydrazine Hydrochloride And 1,4-Cyclohexanedione
  • (文献来源)合成步骤主要原料 Phenylhydrazine Hydrochloride 和 1,4-Cyclohexanedione
1,5-二氯-2,4-二硝基苯置于四(三苯基膦)钯,Potassium Carbonate,三苯基膦体系中,用 1,4-二氧六环,水,邻二氯苯,甲苯 用作溶剂,化学反应 72.0H,反应生成5,7-二氢-吲哚并[2,3-B]咔唑
参考文献:Polycyclic Aromatic Compounds And Organic Electroluminescent Devices Using The Same
标题:Polycyclic Aromatic Compounds And Organic Electroluminescent Devices Using The Same
摘要:披露了可以应用于有机电致发光器件的各种有机层中的多环芳香化合物.还披露了包括这些多环芳香化合物的有机电致发光器件.这些有机电致发光器件具有高效率,长寿命并且具有极大改善的发光效率.

海关参考信息

专利信息


专利号:US-8399502-B2
优先权日:2008-09-17
标 题 :Analogs of indole-3-carbinol and their use as agents against infection
发明人:JONG LING; JIANG FAMING; LI GAOQUAN; MORTELMANS KRISTIEN
权利人:JONG LING; JIANG FAMING; LI GAOQUAN; MORTELMANS KRISTIEN; STANFORD RES INST INT
摘要:Compounds useful as antibacterial agents are provided. The compounds are analogs of indole-3-carbinol and have a backbone selected from dihydroindolo[2,3-b]carbazole, 2,2′-diindolylmethane, 2′,3-diindolylmethane, and 3,3′-diindolylmethane. The compounds are useful therapeutic and prophylactic treatment of bacterial infections in mammals. Methods of synthesis of the compounds are provided, as are pharmaceutical compositions containing the compounds.

专利号:US-7666897-B2
优先权日:2002-08-20
标题 :Analogs of indole-3-carbinol metabolites as chemotherapeutic and chemopreventive agents
发明人:JONG LING; CHAO WAN-RU
权利人:STANFORD RES INST INT
摘要:Novel compounds useful as chemotherapeutic and chemopreventive agents are provided. The compounds are analogs of indole-3-carbinol metabolites wherein the structures and substituents of the compounds are selected to enhance the compounds' overall efficacy, particularly with respect to therapeutic activity, oral bioavailability, long-term safety, patient tolerability, and therapeutic window. The compounds are useful not only in treatment of cancer but also in prevention of cancer. One preferred class of the novel compounds has the structure of formula (IV) n nwherein:n R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 5A , R 6A , R 7A , R 8A , R 22 and R 23 are defined herein. Pharmaceutical compositions are provided as well, as are methods of synthesis and use.

专利号:US-3041349-A
优先权日:1959-11-09
标 题 :Synthesis of carbazoles
发明人:BEARSE ARTHUR E; HILLENBRAND JR LOUIS J; GROTTA HENRY M
权利人:MARTIN MARIETTA CORP
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合成参考文献


参考文献:10.1007/s10593-023-03157-3
摘要:Borodkin GI. Carbocation Catalysis in the Synthesis of Heterocyclic Compounds. Chem Heterocycl Comp. 2023 Feb;59(1-2):16–34. doi: 10.1007/s10593-023-03157-3.
参考文献:10.1007/s40843-025-3546-5
摘要:Shi R, Hong W, Zhu S, Cui Z, Li Z, Wu S, Xu W, Gao Z, Liang Y, Jiang H. Organic cocrystals in the NIR window: functional design, controlled synthesis and frontier applications. Sci. China Mater. 2025 Aug 11;68(9):2999–3018. doi: 10.1007/s40843-025-3546-5.
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