专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-6835849-B2 优先权日:2002-07-15 标题:Synthesis of alkenoate esters from lactones and alcohols 发明人:MANZER LEO ERNEST 权利人:DU PONT 摘要:The invention relates to the synthesis of alkenoate esters from a corresponding lactone and an alcohol in the presence of a basic catalyst. More specifically, this invention relates to the synthesis of methyl-4-pentenoate ester from 5-methyl butyrolactone and methanol.
专利号:US-7229797-B1 优先权日:1999-08-20 标 题:Enzymatic synthesis of deoxyribonucleosides 发明人:TISCHER WILHELM; IHLENFELDT HANS-GEORG; BARZU OCTAVIAN; SAKAMOTO HIROSHI; PISTOTNIK ELISABETH; MARLIERE PHILIPPE; POCHET SYLVIE 权利人:PASTEUR INSTITUT 摘要:The present invention relates to a method for the in vitro enzymatic synthesis of deoxyribonucleosides and enzymes suitable for this method.
专利号:US-11517882-B2 优先权日:2019-12-06 标 题:Ruthenium-based catalyst for ammonia synthesis and preparation method and use thereof 发明人:JIANG LILONG; NI JUN; LIN JIANXIN; HE SHENGBAO; LIN KE; LIN BINGYU; LIN XINGYI 权利人:NATIONAL ENGINEERING RESEARCH CENTER OF CHEMICAL FERTILIZER CATALYST FUZHOU UNIV; PETROCHINA PETROCHEMICAL RES INSTITUTE; BEIJING SANJU ENVIRONMENTAL PROT & NEW MATERIALS CO LTD 摘要:Disclosed is a ruthenium-based catalyst for ammonia synthesis, preparation method and use thereof. The ruthenium-based catalyst comprises Ru—Ba-A core-shell structure which comprises a ruthenium nanoparticle as a core covered with a first shell and a second shell sequentially, wherein the first shell consists of a barium nanoparticle, and the second shell consists of a metal oxide. The Ru—Ba-A core-shell structure can effectively preventing agglomerations of ruthenium nanoparticles during the use of the catalyst and avoiding direct contact between the ruthenium nanoparticles and the metal oxides. In addition, barium nanoparticles have a promoting effect as an electronic promoter, which can effectively improve the stability and catalytic activity of ruthenium-based catalyst for ammonia synthesis, especially in the system for synthesizing ammonia from a coal gas.
专利号:US-2012231327-A1 优先权日:2010-03-10 标题:Positive electrode active material for non-aqueous electrolyte secondary battery, process for production of same, and non-aqueous electrolyte secondary battery produced using same 发明人:HIRATSUKA HIDEKAZU 权利人:HIRATSUKA HIDEKAZU; PANASONIC CORP 摘要:At the time of synthesis of lithium nickelate, by adding a firing aid to material to be fired, crystal growth is promoted at a temperature that is lower than a firing temperature necessary for obtaining desired crystal growth of lithium nickelate, and substitution of elements that contribute to structural stability in crystals is promoted. Furthermore, distortion of crystal or loss of oxygen at the time of synthesis is suppressed. Thus, a lithium ion secondary battery having excellent charge and discharge characteristics and cycling characteristics can be provided.
专利号:US-2025171322-A1 优先权日:2022-03-01 标题:Catalyst support materials for use in ammonia synthesis 发明人:O'HAYRE RYAN P; CADIGAN CHRISTOPHER A; HUANG JAKE D 权利人:OHAYRE RYAN P; CADIGAN CHRISTOPHER A; HUANG JAKE D; COLORADO SCHOOL OF MINES 摘要:Described herein are catalyst support materials for use in synthesizing ammonia (NH 3 ) from nitrogen gas (N 2 ) and hydrogen gas (H 2 ) and methods of making the same. The support material may comprise (MgO) x (BaO) y (Al 2 O 3 ) z and/or (MgO) x (SrO) y (Al 2 O 3 ) z , on which an ammonia synthesis catalyst such as ruthenium is dispersed. When the catalyst support material comprises (MgO) x (BaO) y (Al 2 O 3 ) z , x is from about 0.05 to about 0.7, y is from about 0.05 to about 0.6, and z is from about 0.3 to about 0.5. When the catalyst support material comprises (MgO) x (SrO) y (Al 2 O 3 ) z , x is from about 0.4 to about 0.7, y is from about 0.05 to about 0.5, and z is from about 0.05 to about 0.3.
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