CAS: 64491-68-5; (S)-Glycidyl Methyl Ether

相似化合物

64491-70-9 57044-25-4 60456-23-7

上下游产品

CAS号930-37-0 (甲氧基甲基)环氧乙烷 | CAS号57044-25-4 (|R|)-(+)-缩水甘油 | CAS号74-88-4 碘甲烷

(甲氧基甲基)环氧乙烷置于[(1-Rr)-(Dibenzoyl-Lta)] 水体系中,用99%的收率获得产物
参考文献:Wo2008/153280
标题:Wo2008/153280

专利信息

专利号:US-7038062-B2
优先权日:2004-07-01
标题:Synthesis of cyclic trithiocarbonates from epoxides
发明人：PARKER DANE KENTON
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention provides a low cost technique for synthesizing cyclic trithiocarbonates by a simple one step process from epoxides that can be conducted under atmospheric pressure. This synthesis can be depicted as follows: n nwherein R represents a moiety selected from the group consisting of alkyl groups and aryl groups, wherein R′ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, and wherein R″ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, wherein the R moiety and the R′ moiety can be bonded together to form a cyclic structure, with the proviso that R″ represents a hydrogen atom if R′ represents an alkyl group or an aryl group. In this process carbon disulfide and a thiocyanate salt, such as potassium thiocyanate, are reacted with the epoxide in an ionic liquid, such as 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF 6 ) in the presence of water to produce the cyclic trithiocarbonate.

专利号:US-2006004210-A1
优先权日:2004-07-01
标题:Synthesis of cyclic trithiocarbonates from epoxides