112-35-6 = 6976-93-8 + 2358-84-1 + 109-16-0 + 868-77-9 + 2351-42-0 + 2351-43-1 + 24493-59-2 + 629-38-9 + 97-90-5 + 45103-58-0 反应条件:1.1 Catalysts: Phenothiazine,P-Toluenesulfonic Acid Solvents: Toluene; 4 H,120 °C 标题:Side Products Of Methacrylic Acid Esterification With Triethylene Glycol Methyl Ether 作者:Demidova,Yu. V.; Demidov,P. A.; Potekhin,V. V.; Potekhin,V. M. 参考文献:Russian Journal Of General Chemistry 日期:2016 卷标:86(6) 页码:1250-1254
Methoxyethyl 2-Hydroxy-2-Methylpropionate 反应生成 甲基丙烯酸甲氧基乙酯 参考文献:Burns; Jones; Ritchie,Journal Of The Chemical Society,1935,P. 717 标题:Burns; Jones; Ritchie,Journal Of The Chemical Society,1935,P. 717
专利号:WO-2023102600-A1 优先权日:2021-12-06 标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom 发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI 权利人:NEWSOUTH INNOVATIONS PTY LTD 摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.
专利号:US-2013165350-A1 优先权日:2011-12-22 标 题:Surface linkers for array synthesis 发明人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR 权利人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR; AFFYMETRIX INC 摘要:The present invention provide several methods of derivatizing a surface of a support with one or more linkers thus providing a suitable platform for synthesis of a polymer array, particular a nucleic acid array. Some methods derivatize a surface with a self-assembled monolayer (SAM) of a linker. The SAM confers advantages of hydrolytic stability, broad compatibility with synthesis and detection chemistries, and reduced emergence of latent functional groups during polymer array synthesis. Substrates can also be derivatized with multi-layers of SAMs providing greater hydrolytic stability. Substrates can also be derivatized by synthesizing a linker in situ on the substrate by atom transfer radical polymerization of functional and functional monomers. Appropriate selection of monomers reduces emergence of latent functional groups in subsequent array synthesis.
专利号:US-11591418-B2 优先权日:2017-12-28 标 题:POSS-TX nano-photo-initiator synthesis and in situ photochemical Ag nano-particle synthesis with the help of POSS-TX and wrinkled surface formation 发明人:ARSU NERGIS; OCAL Nuket; GUNKARA OMER TAHIR; BATIBAY GONUL SAADET 权利人:UNIV YILDIZ TEKNIK 摘要:The present invention particularly relates to synthesizing photo-initiators having poly-oligo-silsesquioxane (POSS) structure and realizing photo-polymerization by using these photo-initiators and simultaneous and in-situ synthesis of Ag nano-particles in polymer matrix comprising POSS structure and obtaining wrinkled surfaces as a result of self-arranging thereof.
专利号:WO-2025202701-A1 优先权日:2024-08-21 标 题 :Marine antifouling paint based on silyl acrylate copolymer synthesis 发明人:LAHEGHI NEJAD FARHAD 权利人:LAHEGHI NEJAD FARHAD 摘要:This invention involves the production of marine anti-fouling paint using the synthesis of silyl acrylate copolymers. One of the most effective anti-algae or anti-fouling paints was self-polishing paints based on acrylate resins containing tributyl tin, which were banned due to the toxicity of their tin compounds. One of the best-introduced alternatives is self-polishing paints based on silyl acrylate copolymers, but their performance is subpar and they have a shorter lifespan. In this invention, silyl acrylate copolymers in a controlled structure, including at least one soft monomer such as butyl acrylate, ethyl acrylate, etc., at least one hard monomer such as methyl methacrylate, 2-methoxyethyl methacrylate, etc. and at least one functional monomer such as triisopropyl silyl acrylate, triisopropyl silyl methacrylate, tertiary-butyl dimethyl silyl methacrylate, and tri-N-butyl silyl methacrylate were synthesized in which monomers or hard monomers were gradually added to the reactor in 2-6 hours.
专利号:US-9512250-B2 优先权日:2012-02-23 标 题 :Manganese catalyzed photopolymerization of fluorinated monomers 发明人:ASANDEI ALEXANDRU D 权利人:UNIV CONNECTICUT 摘要:The disclosure discloses initiating systems for the radical polymerization of alkenes, and especially fluorine substituted alkenes. The polymerization is catalyzed by a metal carbonyl, preferably manganese carbonyl. The polymerization is initiated directly from alkyl halides at room temperature under visible white light. The polymers also allow the synthesis of block copolymers. The process comprises polymerizing at least one alkene monomer in the presence of a halide radical initiator, carbonyl catalyst and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one alkene monomer to form a polymer. The present disclosure provides a method for living polymerization of alkene monomers which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products. This disclosure also provides a method for activating any halide (Cl, Br, I) chain ends of such polymers for the synthesis of block copolymerizations.
专利号:US-2023212107-A1 优先权日:2021-12-30 标 题:Synthesis of para-alkylated syringyl (meth)acrylate derivatives and photopolymerizable compositions for additive manufacturing in dental applications 发明人:CHOUDHARY UMESH UPENDRA; SU JESSICA KALAY 权利人:ALIGN TECHNOLOGY INC 摘要:The present disclosure provides polymerizable monomers which may be used as reactive diluents in additive manufacturing. The polymerizable monomers may have low vapor pressures and may be compatible with a range of low glass transition temperature oligomers.
[参考文献]: Caroline R Szczepanski, Et Al. Accessing Photo-Based Morphological Control In Phase-Separated, Cross-Linked Networks Through Delayed Gelation. Eur Polym J. 2015 Jun 1:67:314-325.
合成参考文献
参考文献:10.1166/jnn.2011.3595 摘要:Davion B, Delhorbe V, Péralta SP, Goubard F, Vidal F. Dispersion of luminescent nanoparticles in different derivatives of poly(ethyl methacrylate). J Nanosci Nanotechnol. 2011 Apr;11(4):3208–14. doi: 10.1166/jnn.2011.3595.