iodinepalladiumpalladium(II) bromidepalladium (II) ion({PS,3R,4R,P'S}-3,4-bis{(benzyl)phenylphosphanyl}-1-(tert-butoxycarbonyl)pyrrolidine-P,P')diiodopalladium({PR,3R,4R,P'R}-3,4-bis{(benzyl)phenylphosphanyl}-1-(tert-butoxycarbonyl)pyrrolidine-P,P')diiodopalladium({PR,3R,4R,P'S}-1-(tert-butoxycarbonyl)-3,4-bis{(benzyl)phenylphosphanyl}pyrrolidine-P,P')diiodopalladium({PS,3R,4R,P'S}-1-(tert-butoxycarbonyl)-3,4-bis{(2-methoxybenzyl)phenylphosphanyl}pyrrolidine-P,P')diiodopalladium
专利号:US-7615169-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-7927516-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-9783519-B2 优先权日:2015-06-18 标 题:Palladium/silver co-catalyzed tandem reactions synthesis of phenylacetophenone derivatives by oxabenzonorbornadienes with terminal alkynes and their anti-tumor or anti-cancer activities 发明人:BIAN ZHAOXIANG; LIN CHENGYUAN; MU HUAIXUE; FAN BAOMIN; ZHOU YONGYUN; CHEN JINGCHAO; LU AIPING; CHAN ALBERT SUN-CHI 权利人:UNIV HONG KONG BAPTIST UNIV; UNIV YUNNAN MINZU 摘要:This invention relates to the quick and efficient synthesis of anti-tumor or anti-cancer compounds. More particularly, it relates to the quick and efficient synthesis of anti-tumor or anti-cancer compounds comprising phenylacetophenone derivatives using oxabenzonorbornadienes with terminal alkynes.
专利号:US-8283476-B2 优先权日:2007-06-26 标 题:Transition metal catalyzed synthesis of 2H-indazoles 发明人:HALLAND NIS; NAZARE MARC; LINDENSCHMIDT ANDREAS; ALONSO JORGE; RKYEK OMAR; URMANN MATTHIAS 权利人:HALLAND NIS; NAZARE MARC; LINDENSCHMIDT ANDREAS; ALONSO JORGE; RKYEK OMAR; URMANN MATTHIAS; SANOFI SA 摘要:The present invention relates to a process for the regioselective synthesis of compounds of the formula I, n nwherein R0; R1; R2; R3; R4; R5; A1; A2; A3; A4, Q and J have the meanings indicated in the claims. The present invention provides a direct transition metal catalyzed process to a wide variety of multifunctional 2H-indazoles or 2H-azaindazoles of the formula (I) from 2-halo-phenylacetylenes or (2-sulfonato)phenylacetylenes and monosubstituted hydrazines.
专利号:US-4468523-A 优先权日:1982-06-16 标题 :Synthesis of dialkyl oxalates by the heterogeneously catalyzed oxidative carbonylation of alcohols 发明人:LEONARD JOHN J; SOFRANKO JOHN A 权利人:ATLANTIC RICHFIELD CO 摘要:Synthesis of dialkyl oxalates by the oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with vanadium in the oxide (V 2 O 5 , V 2 O 4 , V 2 O 3 ) form and titanium or a non-hydrolyzable salt thereof, said catalyst being present in a heterogeneous phase.
专利号:US-4451666-A 优先权日:1982-08-06 标题:Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst 发明人:SOFRANKO JOHN A; GAFFNEY ANNE M 权利人:ATLANTIC RICHFIELD CO 摘要:Synthesis of dialkyl oxalates by the heterogeneous catalyzed oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with a crystalline vanadium-phosphorus-manganese containing compound.
参考标题:Synthesis Of Oxalate Esters By The Oxidative Carbonylation Of Amide 摘要:A Process For The Preparation Of Oxalate Esters By The Catalytic Oxidative Carbonylation Of An Amide Acetal Having The Formula ##str1## With Carbon Monoxide And Oxygen Or Oxygen-Containing Gas In The Presence Of A Metal Salt Catalyst, An Amine Base And A Catalytic Amount Of An Alcohol. Preferably A Catalytic Amount Of Particular Oxidizing Metal Salts Is Employed Along With A Catalytic Amount Of An Amine Salt Compound Which May Be Formed In Situ By The Addition Of An Acid. Alternatively Various Counterions And Ligands Of The Metal Salt Catalyst May Be Employed.
合成参考文献
摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 311. 摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 258. 摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2010) 2, 145. 摘要:Kwiecień, H., Science of Synthesis Knowledge Updates, (2018) 3, 15. 摘要:Cheng, B.; Wang, T., Science of Synthesis Knowledge Updates, (2020) 3, 147.