CAS: 4206-67-1; (Iodomethyl)Trimethylsilane

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CAS号2344-80-1 氯甲基三甲基硅烷 | CAS号7681-82-5 碘化钠 | CAS号186581-53-3 重氮甲烷 | CAS号16029-98-4 三甲基碘硅烷 | CAS号75-77-4 三甲基氯硅烷 | CAS号75-47-8 三碘甲烷 | CAS号917-64-6 甲基碘化镁 | CAS号1558-25-4 氯甲基三氯硅烷 | CAS号542-69-8 碘代正丁烷 | CAS号10132-71-5 Ethylfluorodime... | CAS号110481-61-3 ethyl 2-diethox... | CAS号110561-51-8 3,4-dihydro-1H-... | CAS号3739-98-8 三甲基硅基甲基三苯基碘化磷 | CAS号542-69-8 碘代正丁烷 | CAS号18243-41-9 溴乙基三甲基硅烷 | CAS号2344-80-1 氯甲基三甲基硅烷 | CAS号145387-82-2 tert-butyl N-(2... | CAS号14283-35-3 三甲基甲硅烷基异氰酸甲酯 | CAS号18151-32-1 2-氰基乙基三甲基硅烷

氯甲基三甲基硅烷置于sodium Iodide体系中,用 丙酮 作为反应溶剂,以82%的收率获得产物碘甲基三甲基硅烷
参考文献:用强酸裂解烷基硅烷:Iii.(卤甲基)三甲基硅烷与氟磺酸的反应
标题:用强酸裂解烷基硅烷:Iii.(卤甲基)三甲基硅烷与氟磺酸的反应
摘要:利用质子磁共振研究了氟磺酸从(溴甲基)三甲基硅烷和(碘甲基)三甲基硅烷逐步裂解烷基的方法.在两种化合物的第一反应中均观测到了独家的甲基裂解.(溴甲基)二甲基甲硅烷基氟磺酸盐的反应是从硅上裂解甲基和溴甲基而发生的.(碘甲基)二甲基氟硅烷的反应在碘甲基被完全裂解的情况下发生.
DOI:10.1016/s0022-328X(00)87128-4

专利信息

专利号:US-5684195-A
优先权日:1994-07-14
标 题:Method of preparing sulfmonamides from sulfones
发明人：HUANG HORNG-CHIH; HARRING SCOTT R
权利人:SEARLE & CO
摘要:A one-pot synthesis of sulfonamides from sulfones has been developed. Conversion of sulfones to the corresponding sulfinic acid salts is followed by oxidative-amination to give the sulfonamides.

专利号:US-9006231-B2
优先权日:2008-03-03
标 题:Cephalotaxus esters, methods of synthesis, and uses thereof
发明人：GIN DAVID Y; WILMOT JEREMY; DJABALLAH HAKIM
权利人:SLOAN KETTERING INST CANCER
摘要:The present invention provides novel cephalotaxus esters, syntheses thereof, and intermediates thereto. The invention also provides pharmaceutical compositions comprising a compound of the present invention and methods of using said compounds or compositions in the treatment of proliferative diseases (e.g., benign neoplasm, cancer, inflammatory disease, autoimmune disease, diabetic retinopathy) and infectious disease. The invention further provides methods of using said compounds or compositions in the treatment of multidrug resistant cancer.

专利号:US-4139403-A
优先权日:1977-08-19
标题:Dinitroalkyl and fluorodinitroalkyl silicon compounds
发明人：BAUM KURT; LERDAL DUANE A; HORN JERALD S
权利人:US NAVY
摘要:Energetic silicon compounds of the general formulae ##STR1## The gem dinitro compounds are prepared from alkyl bromide silanes by sod nitrite displacement and oxidative nitration. The compounds are then fluorinated. To prepare the polysiloxanes, phenyl blocking groups are used during synthesis of the fluoro dinitro moiety and are then replaced with bromine and the monomer is hydrolyzed.

专利号:US-6812298-B2
优先权日:2001-03-26
标 题 :Hyperbranched polymers by multimonomer polymerization
发明人：DVORNIC PETAR R; HU JIN; MEIER DALE J; NOWAK ROBERT M; PARHAM PAUL L
权利人:MICHIGAN MOLECULAR INST
摘要:Hyperbranched polymers are prepared by a process in which a monomer having the form Ax is reacted with another monomer of the form By, where A and B are functional groups that do not react with themselves, but do react with each other. The process allows synthesis of hyperbranched polymers having a single type of terminal functional group from comonomers, each of which has a single type of functional group. The invention allows greater flexibility in the preparation of a larger variety of different hyperbranched polymers and enables hyperbranched polymers to be prepared at a lower cost as compared with conventional processes using monomers having two types of functional groups that react during polymerization.

专利号:WO-2009148654-A2
优先权日:2008-03-03
标 题:Cephalotaxus esters, methods of synthesis, and uses thereof

专利号:US-2011071097-A1
优先权日:2008-03-03
标题:Cephalotaxus esters, methods of synthesis, and uses thereof